机载腔增强吸收光谱系统应用于大气NO_2空间高时间分辨率测量

介绍了一套用于机载平台测量的非相干宽带腔增强吸收光谱(IBBCEAS)系统,并应用于实际大气NO_2空间分布的高时间分辨率观测.为满足机载测量中对时间分辨率的需求,系统采用离轴抛物面镜代替消色差透镜提高光学耦合效率;并运用Allan方差,对系统性能进行了分析.通过腔增强吸收光谱系统与长光程吸收光谱系统对实际大气NO_2的对比测试,两者线性相关系数R~2达到0.86.将IBBCEAS系统应用于机载平台,在时间分辨率为2 s的情况下,探测限达到95 ppt(1σ).通过机载观测,获得了华北地区石家庄等地上空对流层大气NO_2的廓线信息.     

Supercontinuum generation in seven-core photonic crystal fiber pumped by a broadband picosecond pulsed fiber amplifier

We report a supercontinuum source generated in seven-core photonic crystal fibers(PCFs) pumped by a self-made all-fiber picosecond pulsed broadband fiber amplifier. The amplifier's output average power is 60 W at 1150 nm with spectral width of 260 nm, and its repetition rate is 8.47 MHz with pulse width of 221 ps. With two different lengths of seven-core PCF, different output powers and spectra are obtained. When a 10 m long seven-core PCF is chosen, the output supercontinuum covers the wavelength range from 620 nm to 1700 nm, with the output power of 11.7 W. With only 2 m long seven-core PCF used in the same experiment, the wavelength of the supercontinuum spans from 680 nm to 1700 nm,with the output power of 20.4 W. The results show that the pulse width is 385 ps in the 10 m long seven-core PCF and 255 ps in the 2 m long one, respectively, due to the normal dispersion of the PCF.     

基于层间相似性的时序网络节点重要性研究

时序网络可以更加准确地描述节点之间的交互顺序和交互关系.结合多层耦合网络分析法,本文提出了基于节点层间相似性的超邻接矩阵时序网络节点重要性识别方法,与经典的认为所有层间关系为常数不同,层间关系用节点的邻居拓扑重叠系数进行度量.Workspace和Enrons数据集上的结果显示:相比经典的方法,使用该方法得到的Kendall’sτ值在各时间层上的平均提高,最高为17.72%和12.44%,结果表明层间相似性的度量对于时序网络的节点重要性度量具有十分重要的意义.     

Highly-sensitive NO,NO_2,and NH_3 measurements with an open-multipass cell based on mid-infrared wavelength modulation spectroscopy

A compact prototype based on mid-infrared wavelength modulation spectroscopy(WMS)is developed for the simul-taneous monitoring of NO,NO_2,and NH_3 in the urban area.Three quantum cascade lasers(QCLs)with central frequencies around 1900.0 cm~(-1),1600.0 cm~(-1),and 1103.4 cm~(-1)are used for NO,NO_2,and NH3detections,respectively,by timedivision multiplex.An open-path multi-pass cell of 60-m optical path length is applied to the instrument for high sensitivity and reducing the response time to less than 1 s.The prototype achieves a sub-ppb detection limit for all the three target gases with an average time of about 100 s.The instrument is installed in the Jiangsu environmental monitoring center to conduct performance tests on ambient air.Continuous 24-hour measurements show good agreement with the results of a reference instrument based on the chemiluminescence technique.     

112 Gbit/s transmitter optical subassembly based on hybrid integrated directly modulated lasers

Based on the hybrid integration technology, an ultra-compact and low cost transmitter optical subassembly module is proposed. Four directly modulated lasers are combined with a coarse wavelength division multiplexer operated at the O-band. The bandwidth for all channels is measured to be approximately 3 GHz. The 112 Gb∕s transmission is experimentally demonstrated for a 10 km standard single mode fiber(SSMF), in which an optical isolator is used for avoiding the back-reflected and scattered light to improve the bit error rate(BER) performance. A low BER and clear eye opening are achieved for 10 km transmission.     

负载的Ni催化剂上植物油脂加氢脱氧制备第二代生物柴油

在半连续反应器中,以棕榈酸甲酯为植物油脂模型化合物,进行了加氢脱氧制取高品质生物柴油燃料的研究。采用浸渍法制备了HY、SiO₂、γ-Al₂O₃及SAPO-11四种载体负载的Ni催化剂,采用XRD、NH₃-TPD、H₂-TPR、BET、SEM等技术进行催化剂表征。结果表明,Ni/SAPO-11催化剂由于SAPO-11表面呈现的弱酸和中强酸性质,在保持较高的加氢脱氧反应性的同时,抑制了裂解反应的发生,具有较好的催化性能。进一步对SAPO-11上不同的Ni负载量、反应温度、反应压力等进行了研究,发现当Ni负载量为7%,反应温度为220℃,压力为2MPa时,催化剂具有较高的催化性能,棕榈酸甲酯的转化率达到了99.8%,C_9~16烷烃的总选择性为92.71%。     

库仑-称重法测量金属镀层厚度的研究

用库仑法溶解镀层,阳极溶解曲线判断溶解终点,天平确定镀层厚度,建立了库仑-称重法。在电镀锡板上的试验,取得了满意的结果,SD小于0．04g／m^2,RSD不超过0．36%。     

氙灯泵浦钕玻璃放大器储能效率研究北大核心CSCD

按照激光放大器能量传输和转化过程,利用激光速率方程和氙灯辐射方程、光线追迹软件等理论方法和分析计算工具,对氙灯泵浦钕玻璃激光放大器进行储能效率和能量转换环节的理论分析以及定量、半定量计算,系统分析各种能量转化与损耗因素对放大器储能效率的影响。理论研究的成果与放大器实验考核的结果相一致。     

基于微分法精确测量气溶胶飞行时间的新方法

利用飞行时间气溶胶粒子束光谱技术对大气气溶胶牲子粒谱分布进行监测是精确测量大气气溶胶粒子粒径大小及浓度的典型方法.而精确测量气溶胶粒子飞行时间是实现粒径谱精确监测的关键.利用微分法对门限电平比较法进行优化改进,利用信号微分后的零点对应信号最大值的特点,将飞行时间提取中变化的门限电平的比较转换成零电平的比较,设计了一种精确测量气溶胶粒子飞行时间的方法.该方法不但可以忽略因气溶胶粒子大小而引起的散射光强弱变化,而且,即使散射光双峰信号并非理想的对称信号,该方法也能精确地测得飞行时间.     

空间激光通信中光强起伏尺度特征的数值分析

利用数值模拟的方法,定量地计算分析了空间激光通信中光强起伏问题,得到了准直光束与聚焦光束光强起伏相关距离（不均匀元半径）随大气相十长度变化的结果;进而分别从接收效率和性价比等不同的角度对激光通信系统接收孔径选取的参考因素进行了探讨。根据现代光通信对误码率的最低要求定义最佳接收孔径,计算分析了聚焦光束空间激光通信系统最佳接收孔径随大气相干长度r0的变化关系。结果表明,最佳接收孔径随大气相干长度的减小而迅速增大。对于聚集光束空间激光通信而言,在大气相干长度ro约为4cm的强湍流效应情况下,通信系统的接收孔径接近5倍艾里斑直径,才能满足国际电信联盟-电信标准部对光通信的最低要求。