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61.
The enantioselective ring-opening reactions of azabicyclic alkenes with primary and secondary aromatic amine nucleophiles are reported using an iridium catalyst generated in situ from 1.5 mol % of [Ir(COD)Cl](2) and 3 mol % of (S)-BINAP. The reaction affords the corresponding trans-1,2-diamine derivatives in moderate to good yields with moderate to high enantioselectivities (up to 97% ee). The trans-configuration of the 1,2-diamino product 2g was confirmed by X-ray crystallography. 相似文献
62.
Peng Lingling Wang Yuhua Wang Zhaofeng Dong Qizheng 《Applied Physics A: Materials Science & Processing》2011,102(2):387-392
MgO:Eu3+ nanocrystals with average diameter around 15 nm were prepared via a facile combustion method under a weak reductive atmosphere
at temperature as low as 300°C. The photoluminescence spectra showed that the MgO:Eu3+ nanocrystals emit white light, the hypersensitive transition (5
D
0→7
F
j
of Eu3+) emission was prominent in the emission spectra resulting from the noinversion symmetry local site at which Eu3+ ions were located. Two kinds of luminescence sites of Eu3+ are identified by means of the fluorescence decay and site-selective spectroscopy. The excitation and absorption spectra
indicated that the absorption of surface state decreased with the increase of Eu3+ concentration, meaning that the surface defect decreased through Eu3+ doping for some of them located at the disordered sites near the surface or absorbed at the surface of MgO host. Meanwhile,
absorptivity and CIE chromaticity coordinates of all samples were measured; the results were in accordance with the excitation
and absorption spectra and photoluminescence spectra, respectively. 相似文献
63.
64.
65.
Wei Liu Yuhua Shi Tongshun Shi Guofa Liu Yongxin Liu Ce Wang Wangjin Zhang 《Liquid crystals》2003,30(11):1255-1257
5,10,15,20-Tetrakis(4-n-alkanoyloxyphenyl)porphyrins and their Zinc complexes exhibit hexagonal columnar phases with low phase transition temperatures and wide mesophase ranges. 相似文献
66.
Fuyi Li Zhanping Liang Qi Zhang Yuhua Li 《Journal of Mathematical Analysis and Applications》2007,327(2):1010-1028
In this paper, the existence of sign-changing solutions for nonlinear operator equations is discussed by using the topological degree and fixed point index theory. The main theorems are some new three-solution theorems which are different from the famous Amann's and Leggett-Williams' three-solution theorems as well as the results in [F. Li, G. Han, Generalization for Amann's and Leggett-Williams' three-solution theorems and applications, J. Math. Anal. Appl. 298 (2004) 638-654]. These three solutions are all nonzero. One of them is positive, another is negative, and the third one is a sign-changing solution. Furthermore, the theoretical results are successfully applied to both integral and differential equations. 相似文献
67.
Yongbing Song Run Jiang Zheng Wang Lang Wang Yuhua Yin Baohui Li An‐Chang Shi 《Macromolecular theory and simulations》2016,25(6):559-570
The self‐assembled morphologies of cyclic amphiphiles, which are composed of a long hydrophobic block and a short hydrophilic block, in selective solutions are studied by using a simulated annealing method. The morphological dependence of the aggregates on solvent quality is investigated. The topology effects are studied by comparing results from linear counterparts of the amphiphiles. It is observed that, in addition to spherical micelles, cylindrical micelles, disklike micelles, vesicles, and large compound micelles, muticompartment vesicles with several fluidic cores can be formed by the cyclic systems. The morphologies are regulated by the interaction parameter εAS between the hydrophobic block and solvents. Furthermore, it is revealed that the differences of characteristics of the self‐assembled aggregates originate from the difference in architectural constraint. The wide region of forming multicompartment vesicles suggests that cyclic amphiphilic macromolecules could be a suitable candidate for applications to deliver multiple functional components by compartmentalizing different components in different confined space of vesicles. 相似文献
68.
69.
Cuprous chloride was coordinated by diazabutadiene (DAB‐R) ligands to form Cu(I)‐(DAB‐R) complexes, most of which have a 1:1 ratio of Cu to DAB‐R as reported. In the case of a special DAB‐iPP, N,N′‐bis(2,6‐diisopropylphenyl)‐1,4‐diaza‐1,3‐butadiene, an unexpected composition of complex was found with the formula Cu(I)Cl(DAB)2. When employed as catalyst for triarylamine synthesis from the coupling of aryl halides with primary and secondary arylamines, the new Cu(I)‐(DAB‐iPP) complex displayed high efficiency. 相似文献
70.
本文采用应力波特征线方法详细分析了刚体撞击固支的弹性长杆的撞击过程,指出当撞块质量和长杆质量的比值满足一定条件时,在第一次撞击过程结束后会发生第二次撞击。 相似文献