Bifurcation trees of period-3 motions to chaos in a time-delayed Duffing oscillator

Nonlinear Dynamics - In this paper, bifurcation trees of period-3 motions to chaos in a periodically forced, time-delayed, hardening Duffing oscillator are investigated by a semi-analytical method....     

一类三对角矩阵的特征值和特征向量的研究

讨论了一种三对角矩阵的特征值和特征向量.按矩阵右下角对角元素的参数分为两类,得出特征值和特征向量的结论或数值算法.举例说明了算法的有效性.     

Enantioselective total synthesis of a natural hydrocarbazolone alkaloid,identification of its stereochemistry,and revision of its spectroscopic data

The natural hydrocarbazolone alkaloid (1R,2R,3R)-3-hydroxy-1,2-dimethyl-1,2,3,9-tetrahydro-4H-carbazol-4-one has been synthesized in a catalytic and enantioselective manner. A key hydrocarbazole derivative was constructed by the holmium-catalyzed Diels-Alder reaction of (silyloxyvinyl)indole as the diene. Total synthesis of the natural product clarified the ambiguity in the spectroscopic data reported for natural products.     

和厚朴酚的电化学行为及反应机理研究

和顾朴酚在０．１ｍｏｌ／Ｌ ＮＨ３－ＮＨ４Ｃｌ缓冲溶液（ＰＨ９．４）中,用线必 安法得到两个还原峰Ｐ１和Ｐ２。峰电位分别为ＥＰ１＝－０．２３Ｖ和ＥＰ２＝－１．１８Ｖ（ｖｓ,Ａｇ／ＡｇＣｌ）。用线性扫描与循环伏安法、脉冲极谱法和恒电位库仑法等手段研究体系的电化学行为及其反应机理。实验表明,Ｐ１和Ｐ２均为不可逆波。Ｐ１和Ｐ２的电子转移数均为２。和厚朴酚在汞电极上的吸附具有中性分子吸附的特征,吸附符合Ｆ     

基于Elman神经网络的252Cf源核系统随机中子脉冲信号识别方法

 针对²⁵²Cf自发裂变中子源构成的核信息系统,以实际所测随机中子脉冲数据的自相关函数为研究对象,借助仿真实验, 利用Elman神经网络对不同质量核材料进行识别。在实测数据的基础上,通过叠加随机抖动,模拟产生了不同质量核材料的相关函数样本,并将其用于神经网络的训练与测试,实验结果表明,训练过的Elman神经网络能够较好地识别相关函数的特征,分辨不同质量的核材料,平均识别率达到85%,综合平均误差为0.04,且具有较高的鲁棒性。     

Pre-activation and Defects Introduced via Citric Acid to Mitigate Capacity and Voltage Fading in Li-rich Cathode

The application of Li-rich and Mn-based layered cathode materials is impeded by the discharge voltage decay and capacity fading upon cycling, despite their high specific capacity. Here, we combine pre-activation and nanoscale defects modification of lithium rich and manganese based layered materials to mitigate the above two serious problems through improved anionic redox activity and Li⁺ conductivity. The optimum constructed nanoscale defects rich cathode material delivers a reduced voltage fading rate of 1.27 mV per cycle compared to 3.7 mV per cycle for the pristine material after 200 cycles at 1 C rate. Moreover, the nanoscale defects rich material delivers a high specific discharge capacity of 173.1 mAh · g^–1 with a high capacity retention of 99.5 % after 200 cycles at 1 C rate superior than the pristine material (89.3 mAh · g^–1 and 53.4 %, respectively). This study highlights the reversibility of oxygen redox in electrochemical stability and effectiveness of nanoscale defects in stabilize voltage.     

Yttria-stabilized-zirconia hollow spheres prepared by atmospheric plasma spray

Yttria-stabilized-zirconia （YSZ） hollow spheres are widely utilized for their novel physical and chemical properties. However, developing a simple and low-cost method for preparing such hollow spheres still remains a great challenge. In this paper, an atmospheric plasma spray （APS） method is introduced, and the formation mechanism of hollow 7YSZ （ZrO2-7wt%Y2O3） spheres is presented. The hollow sphere morphology was observed by scanning electron microscopy （SEM） when agglomerated and sintered 7YSZ powders were used. Additionally, additive composition changes, phase transformations, and the thermal behavior of 7YSZ powders were analyzed by energy dispersive spectroscopy （EDS）, X-ray diffractometry （XRD）, thermogravimetric analysis （TG） and differential scanning calorimeter analysis （DSC）. Furthermore, the phase transformations of agglomerated and sintered 7YSZ powders, 7YSZ hollow spheres that annealed at various temperatures for different times are analyzed.     

幂函数形式连续变截面梁振动的弯曲固有频率分析*

本文使用微分方程解析法求解变截面梁固有频率。首先,建立变截面梁模型,其中截面面积和惯性矩均按幂次函数变化。得到变截面梁自由振动时挠度的解析表达式,并获得不同边界条件下梁弯曲振动的固有频率方程。其中惯性矩所对应幂指数与截面面积的幂指数的差值为4时,可得自振频率方程的精确形式;而幂指数差值不等于4时,给出近似解法。其次,对4种具体的变截面梁求解不同边界下的自振频率,并与瑞利-里兹法所得的自振频率解比较。验证精确解法结果的正确性,并发现近似解法结果的相对偏差在5%以内。该解析方法较瑞利-里兹法具有能快速求解的特点,且易于分析截面参数对梁固有频率的影响。由算例可得,边界和其他参数不变时,梁的同阶次无量纲自振频率随着幂次指数的增加而增加。几何参数中仅截面形状参数改变时,随着形状参数的增加,梁的同阶次无量纲自振频率随之减小,但固定-自由梁的第一阶自振频率除外。     

Synthesis,characterization and cytotoxicity of Pt(II), Pd(II), Cu(II) and Zn(II) complexes with 4’‐substituted terpyridine

Eight novel Pt(II), Pd(II), Cu(II) and Zn(II) complexes with 4’‐substituted terpyridine were synthesized and characterized by elemental analysis, UV, IR, NMR, electron paramagnetic resonance, high‐resolution mass spectrometry and molar conductivity measurements. The cytotoxicity of these complexes against HL‐60, BGC‐823, KB and Bel‐7402 cell lines was evaluated by MTT assay. All the complexes displayed cytotoxicity with low IC₅₀ values (<20 μm ) and showed selectivity. Complexes 3 , 5 , 7 and 8 exerted 9‐, 5‐, 12‐ and 7‐fold higher cytotoxicity than cisplatin against Bel‐7402 cell line. The cytotoxicity of complexes 3 , 5 , 6 , 7 and 8 was higher than that of cisplatin against BGC‐823 cell line. Complexes 3 , 7 and 8 showed similar cytotoxicity to cisplatin against KB cell line. Complex 7 exhibited higher cytotoxicity than cisplatin against HL‐60 cell line. Among these complexes, complex 7 demonstrated the highest in vitro cytotoxicity, with IC₅₀ values of 1.62, 3.59, 2.28 and 0.63 μm against HL‐60, BGC‐823, Bel‐7402 and KB cells lines, respectively. The results suggest that the cytotoxicity of these complexes is related to the nature of the terminal group of the ligand, the metal center and the leaving groups. Copyright © 2013 John Wiley & Sons, Ltd.