Experimental research on application of Hartmann micro-lens array in coherent beam combination of two-dimensional laser array

We demonstrate experimentally the application of a phase error detection method in the coherent beam combination (CBC) of a laser array. The method is based on the Hartmann micro-lens array. Both the piston and tilt errors can be detected and corrected simultaneously by combining this method with adaptive optics-correcting technology. The far-field intensity pattern of the combined beam has high energy concentration and good beam quality. The power encircled in the main lobe of the far-field pattern is 41.3%, and the contrast of the pattern reaches 81.8%. Experimental results show the great potential of the Hartmann phasing method for use in the CBC of a large number of laser beams.     

利用遗传算法优化误差扩散核参数的条纹二值编码方法研究

二值条纹投影图像在高速、高精度的三维面形测量领域应用广泛,而提高二值编码条纹的正弦性对于提高三维面形的测量精度具有积极意义.传统及改进的误差扩散核多采用普适的扩散核对条纹图像进行二值编码,较少考虑图像特征与投影离焦程度对相位提取精度的影响.首先利用遗传算法的思想来寻求更佳的误差扩散核系数,然后通过线性拟合来构建与离焦程度以及正弦条纹周期相关的优化目标函数,最后得到优化二值编码条纹正弦性的误差扩散核.仿真和实验分析结果表明,在不同尺寸的窗口下,不同周期有最小相位误差的误差扩散核且它们各不相同,证实扩散核对图像的二值编码质量与图像特征有关.实验进一步证明,大中小三种离焦程度下,所提算法的相位误差较普适的Floyd-Steinberg扩散法可分别减小43.86％、64.37％和50.10％,所提算法的相位误差较改进的Floyd-Steinberg扩散法可分别减小13.51％、18.48％和17.65％.     

芳亚甲基硝基缩氨基胍类化合物的合成及杀虫活性

依据活性亚结构拼接原理, 以硝基胍为原料, 合成了一系列具有新烟碱类和缩氨基脲类杀虫剂共同结构特征的芳亚甲基硝基缩氨基胍类化合物, 其结构通过¹H NMR、 IR和元素分析等方法进行了确证. 杀虫活性测定结果表明, 在600 μg/mL浓度下, 目标化合物对桃蚜[Myzuspersicae(Sulzer)]具有较优异的活性, 其中化合物4-2, 4-8, 4-10, 4-16, 4-27, 4-31和4-34的校正死亡率均在90%以上. 进一步以桃蚜、 棉蚜(Aphis gossypii)和桃粉蚜(Hyalopterusamygdali blanchard)为对象, 测定了化合物4-2, 4-8和4-34的精密毒力. 结果表明, 它们在低浓度下仍然具有很高的活性, 其中化合物4-8对棉蚜的活性甚至优于对照药剂吡虫啉, 在3.13 μg/mL浓度下致死率仍高达95.7%(吡虫啉为79.4%), 具有进一步研究开发的价值.     

根据远场光班确定夏克-哈特曼传感器采样率的一种方法

提出了一种利用夏克-哈特曼波前传感器测量未知波前时确定其子孔径数目的新方法.首先将被测波前相位用傅里叶级数展开表示,然后对展开表达式的复振幅进行贝塞尔展开,并对它进行傅里叶变换计算出其远场光斑分布.分析表明,波前相位频谱分量与远场光斑形态存在某种相互对应的关系.可根据采样定理通过远场光斑的分布界限确定出夏克-哈特曼波前传感器的采样率.该方法为夏克-哈特曼传感器对未知波前进行测量时其子合理孔径数目的确定提供了理论依据.有效避免了夏克-哈特曼传感器由于采样率不足而造成精度下降的问题,结束了在确定夏克-哈特曼波前传感器的子孔径数目时只依靠经验的状态.     

Synthesis and properties of MoO3/ZrO2 solid acid catalysts for the preparation of polydimethylsiloxane (PDMS) via octamethylcyclotetrasiloxane (D4) ring-opening

A series of MoO₃/ZrO₂ catalysts were prepared by impregnation method, and characterized by X-ray diffraction (XRD), specific surface area (BET) and temperature-programmed desorption of NH₃ (NH₃-TPD). The polydimethylsiloxane (PDMS) was prepared by ring-opening polymerization from D₄ and MM with MoO₃/ZrO₂ catalysts. The effects of MoO₃/ZrO₂ catalysts preparation conditions on PDMS molecular weight and reaction conversion rate were discussed. Moreover, the effects of reaction conditions on the ring-opening polymerization were also studied. During the preparation of PDMS, the molecular weight of the product can be controlled by adjusting the mass ratio of D₄:MM. The MoO₃/ZrO₂ catalyst was compared with other catalysts during the ring-opening process, and the repeated times of MoO₃/ZrO₂ catalysts were also studied. The results showed that MoO₃/ZrO₂ catalyst had more excellent catalytic performance, for ring-opening process, and when the repeated times was more than 5, the catalytic activity decreased significantly. In addition, the kinetics of D₄ ring-opening polymerization with the MoO₃/ZrO₂ catalyst was investigated.     

子种绿A与锡反应分光光度法测定痕量锡

探讨了在氨性介质中子种绿Ａ（Ｃ３７Ｈ３５Ｎ２Ｏ６Ｓ２Ｎａ） 染料与锡（ＩＶ） 反应形成离子缔合物的最佳条件,建立了测定痕量锡的新方法。子种绿Ａ—Ｓｎ（ＩＶ） 缔合物的最大吸收波长位于６３０ ｎｍ ,表观摩尔吸光系数ε６３０ ＝ １．７×１０６ Ｌ／（ｍｏｌ·ｃｍ）,锡浓度在０～８０ ｕｇ／Ｌ 范围内遵守比耳定律。用于水样与罐头食品分析,结果令人满意。     

大气湍流波前低阶模式的时间功率谱分析

引入规格化的相位谱,推导了大气湍流波前低阶模式（Ｚ－倾斜和Ｇ－倾斜、离焦、像散以及彗差）的时间功率谱,并就水平大气传输、星体目标观测、空间目标监测等几种情况作了实际的数值计算及分析,此外还给出实验结果,分析结果表明：对于水平大气传输模式,倾斜功率谱曲线的低频阶段的指数下降因子为４／３－６β／１１（β为相位谱空间频率的指数下降因子）,离焦、像散和彗差项的功率谱低频段指数下降因子为０;水平大气传输工作     

新西佛碱3．5－二溴水杨醛缩氨基硫脲的合成及其在荧光滴定中的应用

本文研究了新西佛碱３．５－二溴水杨醛缩氨基硫脲（简称３．５－ＤＢＳＴＳ）的合成，及其作为一种新型荧光滴定指示剂，应用于有色溶液中酸碱滴定的条件，建立了一种简便、准确、快速测定有色溶液中酸碱浓度的新方法，用于有色饮料中殴含量的测定，结果满意，指示剂发荧光的ｐＨ突跃范围为７．４８～９．７２，λ＿（ｅｘ）＝３８５ｎｍ，λ＿（ｅｍ）＝５００ｎｍ。     

Novel CuS nanofibers using organogel as a template: controlled by binding sites

A new cholesterol organogelator 1 was synthesized, which was confirmed as an effective gelator for various organic solvents and could self-assemble into network fibers in some organic solvents. Moreover, gelator 1 could act as templates for the synthesis of various CuS nanofibers with different helical pitches. For example, when H(2)S was used as the sulfur source, straight and bending helical CuS nanofibers with a pitch of 100-200 nm could be fabricated in butyl acetate and benzene-butanol gel systems, respectively, while bending CuS nanofibers with a similar helical pitch (ca. 50 nm) could be obtained when thioacetamide was used as the sulfur source in both gel systems. It was first found that the morphologies of inorganic nanofibers could be controlled by the binding sites between the inorganic precursor and the organogel.     

Kinetics-driven growth of orthogonally branched single-crystalline magnesium oxide nanostructures

Orthogonally branched single-crystalline magnesium oxide nanostructures were synthesized through a simple chemical vapor transport and condensation process in a flowing Ar/O(2) atmosphere. Other morphologies, such as cubes and nanowires, can also be obtained under different controlled conditions. The formation of different types of nanostructures can be tuned by modifying oxygen partial pressure during the synthesis. All the nanostructures are cubic single-crystalline enclosed by low-index {100} facets. Growth mechanisms for the nanostructures are discussed in detail: different supersaturation ratios, relatively high substrate temperatures, and surface defects in certain crystallographic planes cooperatively take important effects on determining the product morphologies. Structural defect-related blue light emission of the three types of MgO nanostructures was investigated. The MgO nanostructures with abundant morphologies may find applications in various nanodevices, and the kinetics-driven methodology might be exploited to synthesize similar nanostructures of other functional oxide materials.