Facile and efficient synthesis of quinoline-4-carboxylic acids under microwave irradiation

<正>A facile and efficient method for the preparation of 2-non-substituted quinoline-4-carboxylic acids is described via the Pfitzinger reaction of isatins with sodium pyruvate following consequent decarboxylation under microwave irradiation.     

Polypropylene/poly(butyl methacrylate) blends prepared by diffusion and subsequent polymerization of butyl methacrylate in isotactic polypropylene pellets

Polypropylene/poly(butyl methacrylate)(PP/PBMA) blends were prepared by diffusion and subsequent polymerization of butyl methacrylate(BMA) in commercial isotactic polypropylene(iPP) pellets.The diffusion kinetics,diametrical distribution of PBMA in a pellet and phase morphology of a typical PP/PBMA blend were investigated.     

探究支撑课堂智慧滨绎精彩——一道高考试题的剖析与赏析

数学课堂教学呼唤精彩,特别要重视未曾预约的精彩,因为那是“来自上帝的礼物”,是一种转瞬即逝的弥足珍贵的动态生成资源.作为新课程理念下的数学教师,更要具备一双慧眼,拥有一份美丽期待,让更多无法预约的精彩呈现于数学课堂之中.但数学课堂教学的精彩并非可遇而不可求的,让探究支撑数学课堂,将会链接许多意想不到的精彩.本文试图从一道高考试题的课堂探究生成,谈谈如何在课堂中演绎精彩.     

Pincer iridium（Ⅲ）-catalyzed enantioselective C（sp3）-H functionalization via carbenoid C–H insertion of 3-diazooxindoles with 1,4-cyclohexadiene

The asymmetric carbenoid C–H insertion of 3-diazooxindoles into 1,4-cyclohexadiene has been accomplished in the presence of chiral bis(imidazoline) NCN pincer iridium(Ⅲ) complexes as the catalysts. With a catalyst loading of 0.5 mol%, the reactions proceeded smoothly at 0℃ to afford a variety of chiral 3-substituted oxindoles in good yields with moderate to excellent enantioselectivities(up to 99% ee). The protocol exhibits good functional group tolerance with respect to 3-diazooxindoles and is ...     

不同结构的分子筛在1-丁烯中催化裂解性能的研究

我们合成了不同Si含量的SAPO-18,并且利用了XRD、SEM、NH3-TPD进行了表征分析.利用微反固定床反应器评价了代表不同结构的H-ZSM-5(MFI)、H-Beta(* BEA)、SAPO-18 (AEI)系列分子筛的丁烯催化裂解性能.实验结果表明分子筛的结构和酸性对反应结果都有明显影响,分子筛酸量的增加提高了1-丁烯的转化率,但酸量过高会引发氢转移、芳构化副反应,从而降低丙烯的选择性;分子筛孔口大小、孔道结构决定了可以获得的最高丙烯选择性.具有八元环孔口、笼形结构特点的SAPO-18-0.8在线时间20 min时1-丁烯裂解中转化率为60.7％,获得的丙烯选择性达到59.1％.     

Novel chiral multidentate P3N4-type ligand for asymmetric transfer hydrogenation of aromatic ketones

Novel chiral multidentate P₃N₄-type ligand has been synthesized and characterized by NMR and HRMS. Using i-PrOH as solvent and hydrogen source, asymmetric transfer hydrogenation of various ketones was investigated. The catalyst generated in situ from chiral multidentate aminophosphine ligand (R,R,R,R)-3 and IrCl(CO)(PPh₃)₂ exhibited highly catalytic activity and excellent enantioselectivity under mild conditions, achieving the corresponding chiral alcohols with up to 99% yield and 99% ee.     

Achieving UV and visible-light photocatalytic activity enhancement of AgI/BiOIO3 heterostructure:Decomposition for diverse industrial contaminants and high mineralization ability

Heterostructure photocatalyst fabrication is of great significance for promoting the photoreactivity and solar-energy utilization efficiencies. In this work, AgI/BiOIO_3 heterostructure photocatalysts are synthesized by a facile in-situ crystallization of AgI on BiOIO_3. The photocatalytic performance is first surveyed by decomposition of model dye methyl orange(MO) separately with illumination of UV light and visible-light(λ 420 nm). It indicates that AgI/BiOIO_3 shows highly improved photocatalytic activity regardless of the light source, which should be attributed to the matchable band energy levels between AgI and BiOIO_3, benefiting the efficient charge separation. Notably, AgI/BiOIO_3 shows a universal photocatalytic activity for treating diverse antibiotics and phenols, including tetracycline hydrochloride,chlortetracycline hydrochloride, 2,4-dichlorophenol(2,4-DCP), phenol and bisphenol A(BPA), and the strong mineralization ability of AgI/BiOIO_3 was also demonstrated. Additionally, the different mechanisms under UV and visible light irradiation are investigated in detail. This work provides a new reference for design and manipulation of high-performance nonselective heterostructure photocatalyst for environmental purification.     

高中学生数学应用意识培养的策略研究

高中数学中对学生应用意识的培养可简单概括为四个字——学以致用.应用意识的培养就是在教学中以实际情境引入新课,通过自主学习和探究,对新概念、新思想、新方法进行归纳总结,并应用到解题活动和解决实际问题的过程中,同时在解决问题的过程中不断创新、突破、发展,从而形成一种能力.     

“传球”问题纵横谈

<正>对于数学问题,不能仅满足于会做或是用了几种方法解出;对于课堂教学容量也不能只是用“题量”或内容的多少,甚至是交流的多少来体现.课堂教学更重要的是在注重过程的基础上产生了多少有价值的“思维量”,是否进行了或“追根求源”或“横纵拓展”的探究活动.下面通过在教学中对一个数学问题的思考和探究来说明这一点.1 问题呈现问题 甲、乙、丙三人传球,由甲开始发球,并作为第一次传球,经过5次传球后,球仍回到甲手中,则不同的传球方式共有多少种?     

Chiral lateral optical force near plasmonic ring induced by Laguerre-Gaussian beam

Owing to the good adjustability and the strong near-field enhancement, surface plasmons are widely used in optical force trap, thus the optical force trap can achieve excellent performance. Here, we use the Laguerre-Gaussian beam and a plasmonic gold ring to separate enantiomers by the chiral optical force. Along with the radial optical force that traps the particles, there is also a chirality-sign-sensitive lateral force arising from the optical spin angular momentum, which is caused by the interaction between optical orbit angular momentum and gold ring structure. By selecting a specific incident wavelength, the strong angular scattering and non-chiral related azimuthal optical force can be suppressed. Thus the chiral related azimuthal optical force can induce an opposite orbital rotation of the trapped particles with chirality of different sign near the gold ring. This work proposes an effective approach for catchingand separating chiral enantiomers.