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Dynamics of the reaction of O with H2 and its isotopic variants in different rotational excited states 下载免费PDF全文
Scalar properties and vector correlations of the reactions of O+H 2 →OH+H, O+HD→OH+D, O+DH→OD+H, and O+D 2 →OD+D at collision energies of 25 and 34.6 kcal/mole have been studied via the quasi-classical-trajectory (QCT) method based on a BMS1 potential energy surface (PES). The generalized polarization-dependent differential cross section and the distributions of the dihedral angle at the collision energy of 34.6 kacl/mole are presented. The calculated results indicate that both the reagent rotational angular momentum and the mass factor have a significant influence on the scalar properties and vector correlations of the title reactions. 相似文献
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Recovery of single event upset in advanced complementary metal-oxide semiconductor static random access memory cells 下载免费PDF全文
Using computer-aided design three-dimensional (3D) simulation technology,the recovery mechanism of single event upset and the effects of spacing and hit angle on the recovery are studied.It is found that the multi-node charge collection plays a key role in recovery and shielding the charge sharing by adding guard rings.It cannot exhibit the recovery effect.It is also indicated that the upset linear energy transfer (LET) threshold is kept constant while the recovery LET threshold increases as the spacing increases.Additionally,the effect of incident angle on recovery is analysed and it is shown that a larger angle can bring about a stronger charge sharing effect,thus strengthening the recovery ability. 相似文献
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抗坏血酸和尿酸在CPB现场修饰碳糊电极上的电化学行为及其选择性测定应用 总被引:2,自引:0,他引:2
研究了抗坏血酸(AA)和尿酸(UA)在裸碳糊电极(CPE)和溴化十六烷基吡啶(CPB)现场修饰碳糊电极(CPB/CPE)上的电化学行为.研究结果表明,在PBS水溶液中,AA和UA在CPB/CPE上氧化峰电流增加,峰电位负移,CPB/CPE对AA,UA电化学氧化反应产生了催化作用.微分脉冲法研究表明,在AA和UA共存体系中,AA和UA的氧化峰电位相差约220 mV,以此建立了AA和UA的电化学选择性测定方法.AA和UA的微分脉冲伏安氧化峰电流和其相应浓度分别在7.0×10-6~6.0×10-3 mol/L和5.0×10-7~6.0×10-4 mol/L的范围内呈良好的线性关系.在200倍AA共存时UA的检出限为5.0×10-6 mol/L,CPB修饰的碳糊电极直接应用于实际尿样中UA的测定. 相似文献
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本文首次关注时变市场风险度量指标——时变贝塔和单位市场风险收益率度量指标——时变特雷诺比率的周内效应,重点对中国股市行业指数的收益率、时变贝塔、时变特雷诺比率和交易量进行了周效应和周内各交易日效应研究,并比较研究了个股时变贝塔的周内效应。研究发现行业指数的收益率、时变特雷诺比率、交易量有明显的周效应;收益率和时变特雷诺比率有明显的周二和周四效应,但周一和周五效应并不明显,比如行业收益率基本上没有周一效应;上证指数收益率有明显的周四效应;行业指数交易量的各周内交易日效应比较显著;但行业指数的时变贝塔周效应并不显著;此外,个股的时变贝塔表现出不同于行业指数的特点,其周内效应相对比较明显. 相似文献
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Suppressing the hot carrier injection degradation rate in total ionizing dose effect hardened nMOSFETs 下载免费PDF全文
Annular gate nMOSFETs are frequently used in spaceborne integrated circuits due to their intrinsic good capability of resisting total ionizing dose (TID) effect. However, their capability of resisting the hot carrier effect (HCE) has also been proven to be very weak. In this paper, the reason why the annular gate nMOSFETs have good TID but bad HCE resistance is discussed in detail, and an improved design to locate the source contacts only along one side of the annular gate is used to weaken the HCE degradation. The good TID and HCE hardened capability of the design are verified by the experiments for I/O and core nMOSFETs in a 0.18 μm bulk CMOS technology. In addition, the shortcoming of this design is also discussed and the TID and the HCE characteristics of the replacers (the annular source nMOSFETs) are also studied to provide a possible alternative for the designers. 相似文献
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二茂铁甲基季铵盐对异烟肼的电催化氧化及其电分析方法研究 总被引:3,自引:1,他引:2
研究了铂电极上二茂铁甲基季铵盐电催化氧化异烟肼的电化学行为,并且对异烟肼药物的电分析方法进行了研究。实验结果发现,二茂铁甲基季铵盐对异烟肼的电化学氧化具有很好的催化作用。当二茂铁甲基季铵盐浓度一定时,催化氧化峰电流与异烟肼浓度在5×10-5~6×10-4mol/L的浓度范围有良好的线性关系(r=0.9984),运用方波伏安法测定了异烟肼样品含量,与紫外分光光度法所得结果进行比较,相对标准偏差在0.5%以内,标准加入的回收率在98.0%~101.0%之间。 相似文献
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以正硅酸乙酯(TEOS)为硅源,甘油为辅助剂,在水热条件下合成HZSM-5分子筛。考察甘油添加量、晶化时间对HZSM-5分子筛的晶粒尺寸、相对结晶度和酸性等性质及其甲烷无氧芳构化催化性能的影响。利用X射线衍射(XRD)、扫描电镜(SEM)、氨程序升温脱附(NH_3-TPD)等分析手段对不同条件合成的HZSM-5分子筛样品进行表征。结果表明,在添加一定量的甘油辅助剂的条件下,通过调控晶化时间,可以提升HZSM-5分子筛的相对结晶度,在一定程度上抑制无定型SiO_2的产生,增加其酸量。在甲烷无氧芳构化反应中,甘油辅助合成的HZSM-5分子筛催化剂表现出优良的催化性能,与未添加甘油合成的HZSM-5分子筛催化剂相比,甲烷转化率、苯选择性和芳烃选择性均有较大提高,且具有较强的稳定性与容炭能力。 相似文献
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