酸-碱交替沉淀法铜基甲醇合成催化剂的优化制备与表征

采用酸-碱交替沉淀法制备了Cu基甲醇合成催化剂放大样(500 g), 并用X射线衍射、低温N2吸附和扫描电子显微镜等对催化剂进行了表征,系统考察了制备条件(搅拌速度、溶液滴加速度、盐和碱溶液浓度等)对催化剂性能的影响. 结果表明,采用酸-碱交替沉淀法制备的Cu基甲醇合成催化剂中, Cu和Zn组分以无定形的CuO-ZnO固溶体存在,使得CuO和ZnO的晶粒减小,导致催化剂的晶粒度较小,粒径尺寸分布较均匀,结晶度相对较低,有利于提高催化剂的比表面积. 采用酸-碱交替沉淀法制备的Cu基甲醇合成催化剂具有较高的Cu分散度和较大的Cu比表面积. 在优化条件下制备的催化剂的活性和耐热性均比国内外工业催化剂高.     

直线感应加速器组元的双脉冲改造

 对用于单脉冲直线感应加速器的加速组元进行了双脉冲改造的初步尝试：利用传输线延时获得了双脉冲馈入；用铁氧体作为磁芯材料，在感应腔上得到了双脉冲腔压波形。结果表明，现有组元功率系统经过简单的改造，可以获得两个甚至多个脉冲输出；在伏秒值允许的范围内，铁氧体磁芯的感应腔可以感应出双脉冲波形。为以后多脉冲直线感应加速器的改造和设计提供了一个方向，也提出了一些有待解决的问题。     

烟酸诺氟沙星和乳酸诺氟沙星的荧光特性及应用

研究了烟酸诺氟沙星和乳酸诺氟沙星在不同介质中的荧光特性。采用荧光分光光度法测定了烟酸诺氟沙星和乳酸诺氟沙星的含量。烟酸诺氟沙星和乳酸诺氟沙星分别在0.025—2.5μg/mL和0.01—2μg/mL范围内,其荧光强度与浓度线性关系良好。     

甲醇合成Cu/Zno催化剂前驱体的物相转变

采用共沉淀法制备Cu/ZnO合成甲醇催化剂,重点考察了Cu/Zn母料老化期间pH值的变化情况,并结合X射线衍射(XRD)、红外光谱、微分热重分析、程序升温脱附和扫描电镜等表征于段研究了不同老化时间前驱体物相的变化.结果表明,老化前,前驱体主要以无定形碱式碳酸盐的形式存在;老化过程中,物相由无定形向晶体转变,铜锌开始掺入相应的碱式碳酸盐,此时母液pH值下降,溶液由蓝色变成蓝绿色.随着老化时间的增加,铜锌掺入量增加,晶粒逐渐长大,最终形成大量能生成高活件催化剂的前驱体物相(Cu,Zn)2(CO3)(OH)2和(Cu,Zn)5(CO3)2(OH)6.XRD结果表明,老化时间对催化剂的CuO晶粒大小影响很大.     

Algorithm Study on Reconstruction of Refractive Angles in Fan Beam Diffraction Enhanced Computed Tomography

Based on the 360° computing method of refractive angle for parallel beam diffraction enhanced imaging computed tomography （DE-CT） technique, a new algorithm used to calculate the refractive angle for fan-beam DE-CT technique is developed. The refractive index gradient can be obtained by using the new algorithm with projection data of an object in the range of 0 - 360°, and the new algorithm only needs to set the analyser at half slope position of the rocking curve.     

超声波在液体中的传播速度与温度的关系

根据超声光栅的原理,在分光计上测出了超声波在不同温度下的纯净水中的传播速度.通过最小二乘法进行数据拟合,得到了传播速度与温度的近似公式.     

Barrier Enhancement Effect of Postannealing in Oxygen Ambient on Ni/AIGaN Schottky Contacts

Al0.2 Ga0.8N/GaN samples are grown by metalorganic chemical vapour deposition （MOCVD） method on （0001） sapphire substrates. A 10nm-thick Ni layer is deposited on AlGaN as the transparent Schottky contact. The effect of postannealing in oxygen ambient on the electrical properties of Ni/AlGaN is studied by current-voltage- temperature （I-V-T） measurement. The annealing at a relatively low temperature of 300℃ for 90 s results in a decrease of the ideality factor from 2.03 to 1.30 and an increase of the Schottky barrier height from 0.77eV to 0.954 e V. The I-V-T analysis confirms the improvement originated from the formation of NiO, a layer with higher resistance, which could passivate the surface states of AlGaN and suppress the tunnelling current. Furthermore, the annealing also leads to an increase of the transmittance of the contacts from 57.5% to 78.2%, which would be favourable for A1GaN-based photodetectors.     

Simultaneous wireless information and power transfer transmitting architecture based on asynchronous space-time-coding digital metasurface

Simultaneous wireless information and power transfer(SWIPT) architecture is commonly applied in wireless sensors or Internet of Things(IoT) devices, providing both wireless power sources and communication channels. However, the traditional SWIPT transmitter usually suffers from cross-talk distortion caused by the high peak-to-average power ratio of the input signal and the reduction of power amplifier efficiency. This paper proposes a SWIPT transmitting architecture based on an asynchronous spac...     

用于固态照明的自由曲面微透镜设计

针对LED照明应用中,现有二次光学设计过程对LED初始光强空间角分布的依赖性,讨论了用于LED照明的自由曲面微透镜器件的设计方法.根据斯涅尔定律和边缘光学理论,研究了自由曲面微透镜的面形构造算法,建立了自由曲面微透镜器件的光学模型,并用光学模拟软件对其照明性能进行了模拟实验.结果显示,该微透镜器件能够在目标面上获得满足预期要求的照度分布,照明均匀度在92%以上,且其结构有效解决了LED初始光强空间角分布复杂化的现状和现有二次光学设计对光源初始光强空间角分布依赖性的矛盾.