QuEChERS/气相色谱法测定水果中31种有机磷农药残留

建立了QuEChERS/气相色谱测定水果中31种有机磷农药残留的快速分析方法,并对Qu ECh ERS前处理方法进行优化。样品以乙腈提取、氯化钠盐析后,经C18填料和无水硫酸镁分散固相萃取净化,气相色谱FPD检测器检测,基质匹配标准曲线校正,外标法定量。结果表明,该方法的线性相关系数为0.990 3~0.999 9;不同加标水平下31种有机磷农药的回收率为81.7%~120.7%,相对标准偏差为0.4%~14.7%,方法的检出限为0.4~6μg·kg~(-1)。方法简便快速、准确灵敏,且节省样品和有机溶剂,可满足水果中此31种有机磷农药残留同时快速检测的实际需要。     

TI图形计算器探究"杨辉三角"

本文是一个将信息技术与高中数学知识整合的教学实例,指导学生借助图形计算器学习合情推理的方法,探究杨辉三角中的数学规律.学生使用图形计算器研究数学问题过程中某些繁琐的计算、推导完全可以由机器完成,使学生把学习的重心放到观察、猜想中去,进一步培养学生研究性学习的能     

Thermal Rate Constants of the N（^4S）＋O2（X^3∑g^-） → NO（X^2Ⅱ） ＋O（^3P） Reaction on the ^2A′ Potential Energy Surface

A quasiclassical trajectory study with the sixth-order explicit symplectic algorithm for the N（^4S）＋O2（X^3∑g^-） → NO（X^2Ⅱ） ＋O（^3P） reaction has been reported by employing a new ground potential energy surface. We have discussed the influence of the relative translational energy, the vibrational and rotational levels of O2 molecules on the total reaction cross section. Thermal rate constants at temperatures 300, 600, and 1000 K determined in this work for the reaction are 4.4 × 10^7, 1.8 × 10^10, and 3.1 × 10^11 cm^3mol^-1s^-1, respectively. It is found that they are in better agreement with the experimental data than previous theoretical values.     

High Power One- and Two-Order Cascaded Raman Lasers Based on Home-Made Phosphosilicate Fibre

One- and two-order cascaded Raman fibre lasers are demonstrated by using home-made P-doped Raman fibres.An output power of 2.8 W at 1245 nm with a slope efficiency of 33.4% and an output power of 2.0 W at 1495 nm with a slope efficiency of 23.5% are obtained with the pump source at 1069. 7nm.     

考虑多阶段决策信息集结的新算法及其应用

针对多阶段区间信息集结与决策问题,提出一种考虑最小化集结矩阵与阶段区间矩阵之间距离的新方法,寻求更趋近帕累托最优的集结结果,使最终评价值更符合多阶段评价的目标。 首先,根据多阶段专家评价值将区间信息转化为二维坐标点,并将其映射到二维坐标系中。然后,构建区间信息离差最小化集结模型,并基于植物模拟生长算法(PGSA）进行群体判断信息的集结,再通过合成各方案的属性评价值,给出各决策方案的综合评价值并进行排序,进而给出最优决策方案。最后,以物流服务商的多阶段绩效评价为例,验证了该方法的合理性和有效性。     

伏安法测定叶绿素铜-钠盐中微量铅

在酸性溶液中以抗坏血酸还原Cu(Ⅱ)为Cu(Ⅰ),以KCNS分离大量铜,在抗坏血酸-葡萄糖-柠檬酸铵底液中,采用阳极溶出伏安法分析了叶绿素铜-钠盐中的微量铅,Cu:pb高达9000:1时仍可进行铅的准确测定。     

Evaluation of Optical Properties of Self-Frequency-Doubling Crystal Yb：GdYAl3（BO3）4 for Laser Applications

Yb：GdYAl3 （B03）4 （Yb：GdYAB） is investigated as a new laser crystal for potential applications in self-frequency doubling. The emission and absorption properties of Yb：GdYAB crystal are studied, and the emission decay times of the upper laser level are measured. The emission cross sections are evaluated using the absorption cross section and principle of reciprocity. The other laser performance parameters, such as the minimum inversion fraction βmin, pump saturation intensity Isat and minimum pump intensity 1rain, are also calculated. The results are discussed in the framework of requirements for an effective diode-pumped Yb^3＋ laser system. Yb：GdYAB is expected to exhibit the most useful laser properties and to be superior to Yb：YAB crystal that has been excellent self-frequency-doubling crystal at present in many key spectroscopic parameter values.     

用面阵CCD模拟测定星光漂移的方案研究

在LAMOST焦面光纤定位系统预研中 ,在焦面板上采用面阵CCD跟踪测量亮星的位置及其漂移 ,以对焦面板进行定位。在实验室条件下 ,用光纤出射光斑代替星光 ,即在光纤一端耦合进光 ,并在另一端用面阵CCD接收光斑 ,以模拟实际中接收星光情况。并利用重心法和图像迭加技术对采集的光斑信号进行处理。结果表明 :用面阵CCD测量星光位置及其漂移具有重复精度高 ,稳定性好的特点 ,且通过图像迭加处理 ,可提高星光信号的信噪比。     

超定方程组最小二乘解行处理法C语言程序实现

用C语言实现文[1-2]所给出的一个求解超定方程组最小二乘解的保证收敛的迭代解法。