Efficiency enhancement of InGaN based blue light emitting diodes with InGaN/GaN multilayer barriers

The advantages of InGaN based light-emitting diodes with InGaN/GaN multilayer barriers are studied.It is found that the structure with InGaN/GaN multilayer barriers shows improved light output power,lower current leakage,and less efficiency droop over its conventional InGaN/GaN counterparts.Based on the numerical simulation and analysis,these improvements on the electrical and the optical characteristics are mainly attributed to the alleviation of the electrostatic field in the quantum wells(QWs) when the InGaN/GaN multilayer barriers are used.     

基于液相AFM及干涉频谱法的多孔氧化铝薄膜在线测量系统研究

介绍了多孔氧化铝薄膜(PA)厚度在线测量系统的工作原理、系统结构及独特性能。在白光(宽光谱)照射下,薄膜的上表面和下表面反射的两路光线发生干涉,产生了携带薄膜光学厚度信息的反射光谱。同时,利用液相原子力显微镜(AFM)实时获得的PA膜的表面形貌信息,根据膜系统的Maxwell-Garnette有效介电常数理论,经相干势近似计算得到薄膜的有效折射率,进而得到此时PA膜的物理厚度。使用该系统对PA膜氧化制备过程进行了在线扫描和膜厚测量试验,成功的获得了PA样品的实时表面形貌图像,得到样品的孔隙率和有效折射率。并根据样品反射光谱,利用反射干涉频谱法计算得到氧化150和180 min时,PA膜厚分别为5.35和6.25 μm。本系统具有测量简便、实时性好、无损及测量精确的特点,在实时测量和监控膜厚的同时可获得样品的表面形貌、孔隙率、有效折射率等信息。     

Average Range and Network Synchronizability

The influence of structural properties of a network on the network synchronizability is studied by introducing a new concept of average range of edges. For both small-world and scale-free networks, the effect of average range on the synchronizability of networks with bounded or unbounded synchronization regions is illustrated through numerical simulations. The relations between average range, range distribution, average distance, and maximum betweenness are also explored, revealing the effects of these factors on the network synchronizability of the small-world and scale-free networks, respectively.     

High precision Zernike modal gray map reconstruction for liquid crystal corrector

This paper proposes a new Zernike modal gray map reconstruction algorithm used in the nematic liquid crystal adaptive optics system. Firstly, the new modal algorithm is described. Secondly, a single loop correction experiment was conducted, and it showed that the modal method has a higher precision in gray map reconstruction than the widely used slope method. Finally, the contrast close-loop correction experiment was conducted to correct static aberration in the laboratory. The experimental results showed that the average peak to valley (PV) and root mean square (RMS) of the wavefront corrected by mode method were reduced from 2.501\lambda (\lambda =633~nm) and 0.610\lambda to 0.0334\lambda and 0.00845\lambda , respectively. The corrected PV and RMS were much smaller than those of 0.173\lambda and 0.048\lambda by slope method. The Strehl ratio and modulation transfer function of the system corrected by mode method were much closer to diffraction limit than with slope method. These results indicate that the mode method can take good advantage of the large number of pixels of the liquid crystal corrector to realize high correction precision.     

水热法合成SnO2金红相纳米柱和亚微米晶体

本文采用水热法,以SnCl4·5H2O为前驱物,在180℃,填充度为68;,反应时间8h,强酸环境条件下合成了SnO2纳米金红相晶体,直径约为5～10nm,长30～100nm.加入一定量的NaOH,调节溶液pH值为强碱性(pH=11),同样条件下也合成了SnO2金红相纳米柱晶体,长200nm、直径10～20nm.提高水热反应的温度为430℃,矿化剂为3mol/L NaOH,反应时间24h,合成了亚微米金红相SnO2晶体,最大线度为300nm.     

石墨电极力学性能和界面剥离强度的实验研究

石墨电极已被广泛应用于商业锂离子电池,因而对于石墨电极的力学性能要求也在不断提高。通过表征和研究石墨电极的力学性能和界面剥离强度,能够为石墨电极相关技术的可靠性研究提供必要的数据支持和理论指导,从而使石墨电极得到合理和可靠的使用。本文运用拉伸和180°剥离实验,分别研究了石墨电极原样、电解液浸泡后的电极以及不同充电状态(SOC)下电极的力学性能和界面剥离强度。拉伸实验结果表明,充满电状态下电极材料的断裂形式是脆性断裂,而原样电极、电解液浸泡后电极以及完全放电状态下电极均表现出韧性断裂。180°剥离实验结果表明,电极的活性层与集流体之间界面剥离强度在充满电状态下的值比完全放电后的值大。经过电解液浸泡后的电极活性层与集流体之间界面剥离强度则与原样电极的值相同。经过1000次充放电循环后,石墨电极活性层与集流体之间界面剥离强度则远远低于未经过充放电循环电极的值。     

全自动凝胶净化-浓缩-固相萃取/气相色谱-质谱法测定紫皮石斛中有机磷农药残留

建立了以凝胶渗透色谱(GPC)和固相萃取(SPE)净化、气相色谱-质谱(GC-MS)法同时测定紫皮石斛中10种有机磷农药残留的方法。样品用乙腈超声提取,提取液经GPC去除类脂杂质和大分子物质,后经Envi-Carb/NH2固相萃取柱净化,选择离子(SIM)监测模式检测,外标法定量。在26min内10种农药得到很好的分离,农药残留量在0.02~0.5μg/mL,方法的线性良好,相关系数为0.997 3~0.999 9,农药加标浓度为0.05mg/kg和0.2mg/kg时,加标回收率在70.4%~115.8%,相对标准偏差在2.8%~9.6%,满足国家标准要求,检出限为0.005 2~0.011mg/kg。方法简便、快速、灵敏、准确,能够运用于石斛中多组分有机磷农药残留的定性和定量分析。     

化学实验中洗气瓶的"一物多用"

化学实验中的“一物多用”就是一件实验仪器或一个实验装置能做多个不同性质的化学实验。这是化学实验教学中培养学生想象力和创造力的重要途径,因此,教学中有意识启发学生利用生活用品或废品代替或自制实验用品,并且能“一物多用”,这既能培养学生的改革意识和创新素质,还能激活学生对化学仪器以及实验代用品的使用兴趣,     

熔融石英玻璃飞秒激光微纳加工研究

熔融石英玻璃因具有耐热性高、热膨胀系数低、绝缘性能好等优点,广泛应用于航空航天、微光学元件、军事等领域,并对其加工精度和表面质量提出了更高的要求。由于飞秒激光具有“冷加工”的特点,因此在熔融石英玻璃微纳加工方面展现出独特优势。采用波长为1030nm、重复频率为100kHz、脉宽为290fs的飞秒激光对熔融石英玻璃进行加工,确定了不同物镜下熔融石英玻璃的损伤阈值,研究了不同物镜下的激光功率、扫描速度、离焦量、扫描次数对加工线槽的影响,使用逐层叠加加工的方法在低功率下得到了高深宽比(4∶1)的线槽,并且提高加工线槽的宽度与深度的可控性,可以在较薄熔融石英玻璃(200μm)上进行微纳加工。     

基于光程调制的多差动共聚焦显微技术研究

为解决传统共焦显微系统的分辨力与线性量程不能兼顾的问题,提出了基于变光程技术的多差动共焦显微技术,利用光程的调制在单探测光路中实现轴向响应曲线相对于焦平面的对称相移的方式,仅需要调整单一参数就可获得不同离焦量的响应曲线,实现具有绝对零点、线性度好的多差动光路系统,从而实现在同一系统中对高分辨力与大量程的兼容。该技术减少了元器件性能差异和人为装调误差,结构简单,提高了可靠性。实验表明：系统可兼顾分辨力与线性量程,轴向分辨力可达6.46 nm。为微细结构的测量提供了一种精度高、结构简单、应用场合广泛的技术。