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51.
52.
离聚物Surlyn对PBT/PP共混体系的力学性能及形态结构的影响 总被引:2,自引:0,他引:2
用力学性能测试、DMA、SEM等方法研究了离聚物Surlyn对PBT/PP共混体系的力学性能及形态结构的影响。结果表明,在PBT/PP共混体系中引入少量Surlyn可以改善界面的粘接性,从而改善其力学性能。当共混体系中PBT/PP的组份比不变(90/10)且Surlyn的含量为6phr左右时,共混物的冲击强度出现极大值;而弯曲强度在Surlyn含量为1-2phr左右时有最大值。当共混体系中Surlyn的含量不变(6phr)时,其力学性能随PP含量的增加而下降。用玻璃纤维增强共混体系,可显著提高力学性能。 相似文献
53.
Z. Bartczak 《European Polymer Journal》2006,42(8):1819-1829
Blends of isotactic propylene-ran-ethylene (EP) and propylene-ran-(1-butene) (BP) copolymers with various comonomer content (2-3.1 wt.% ethylene, 9.9 wt.% 1-butene), were prepared in Brabender internal mixer at various compositions (25/75, 50/50, 75/25). Static, impact and dynamic mechanical behavior of copolymers and their blends was investigated. The crystalline structure was studied by DSC and SAXS analysis. For all copolymers the lamellar thickness, crystallinity degree and glass transition temperature are lower than those of iPP homopolymer, depending on the comonomer content. It was found that the copolymers exhibit improved impact strength as compared to plain iPP, due to lower crystallinity and higher mobility of chains within amorphous component. Moreover, the elastic modulus as well as the yield behavior of the examined samples resulted to depend primarily on the amount of the crystalline phase and the thickness of the lamellar crystals, respectively. A linear dependence of yield stress on the logarithm of reciprocal lamellar thickness was observed for blends and copolymers, supporting the concept of thermal nucleation of dislocations which control the crystallographic slip processes initiated at the yield point. The blends of BPS with either EPS or EP2 display complete miscibility in the entire range of composition and their mechanical properties are intermediate between those of plain components, changing gradually with the composition. 相似文献
54.
J. P. Dassaud B. Gallot A. Guyot R. Spitz J. P. Beautemps C. Williams C. Bourgaux A. Eisenberg 《先进技术聚合物》1994,5(2):79-89
Polypropylene ionomers have been prepared by sulfonation of copolymers of propene and 7 methyl, 1-6 octadiene, followed by neutralization to cesium salts. Both WAXS and SAXS were used to study the morphology of the samples, while their thermal properties were studied by DSC and their mechanical properties by DMTA. The sulfonation process is shown to cause a further drop in crystallinity in addition to the effect of comonomer incorporation. Ion clustering is observed when the extent of sulfonation is high enough, the limit being dependent on the copolymer composition. The ion pairs which are not incorporated into the cluster cause a small-angle upturn in the WAXS pattern. The mechanical properties are strongly affected by the drop in crystallinity, but may be partly recovered due to ion clustering. No disruption of the ion clusters is observed before thermal decomposition of the polymer. 相似文献
55.
微生物合成的β-羟基丁酸酯与β-羟基已酸酯共聚物/聚乳酸共混材料(PHBHHx/PLA)的力学性能与生物降解性研究 总被引:1,自引:0,他引:1
通过熔融共混法制备了聚乳酸/微生物产β-羟基丁酸酯与β-羟基己酸共聚物的共混物(PLA/PHBHHx).采用拉伸力学试验研究了共混物的力学性能.通过土壤悬浊培养降解法和扫描电子显微镜(SEM)分析对共混材料的生物降解性能进行了研究.实验结果表明,随着PHBHHx含量的增加,共混物的拉伸强度和杨氏模量降低,而生物降解速率却显著提高.但是,在175h之前,重量组成比为20/80的共混物降解速率比纯PHBHHx还要快.综合分析表明,共混材料PLA/PHBHHx的重量比为20/80时,具有优良的力学性能和生物降解性. 相似文献
56.
微生物合成的β-羟基丁酸酯与β-羟基己酸酯共聚物/聚乳酸共混材料(PHBHHx/PLA)的力学性能与生物降解性研究 总被引:1,自引:0,他引:1
WANG Shufang GUO Tianying YANG Chao WANG Hongjian LIU Jing YUAN Xiaoyan ZHENG Junwen ZHANG Banghua SONG Cunjiang Key Laboratory of Functional Polymer Materials for Ministry of Education 《离子交换与吸附》2006,(1)
通过熔融共混法制备了聚乳酸/微生物产β-羟基丁酸酯与β-羟基己酸共聚物的共混物(PLA/PHBHHx)。采用拉伸力学试验研究了共混物的力学性能。通过土壤悬浊培养降解法和扫描电子显微镜(SEM)分析对共混材料的生物降解性能进行了研究。实验结果表明,随着PHBHHx含量的增加,共混物的拉伸强度和杨氏模量降低,而生物降解速率却显著提高。但是,在175h之前,重量组成比为20/80的共混物降解速率比纯PHBHHx还要快。综合分析表明,共混材料PLA/PHBHHx的重量比为20/80时,具有优良的力学性能和生物降解性。 相似文献
57.
The mechanical properties of glass bead filled low density polyethylene (LDPE) composites in tension have been investigated by using an Instron material testing machine. It is found that with increase of the glass bead weight fraction (φ) the tensile modulus (Ec) and the tensile yield stress (σyc) increase as a form of nonlinear function but contrary to the elongation strain at break; the correlation between Ec and φ accords with the logarithmic mixing rule and the relationship between σy and the volume fraction (φf) can be described by means of a second order equation; the effects of the glass bead diameter on the mechanical properties are not large; when φ and the bead size are suitable, the enhanced toughness effect of the filled-systems is more significant; the tensile strength of the glass bead filled system pretreated with a coupling agent are somewhat greater than those of the untreated system. In addition, the morphology of the samples is studied to explain the relationship between the micro-structure and the mechanical properties of the composites. 相似文献
58.
Influence of isotacticity and molecular weight on the properties of metallocenic isotactic polypropylene 总被引:1,自引:0,他引:1
The relationships between structure and properties have been established for isotactic polypropylene, iPP, homopolymers synthesized by metallocene catalyst systems. These iPPs exhibit different isotacticity degrees and molecular weights, and several thermal treatments during their processing have been applied. The most important factor affecting the structure and properties of these polymers is the isotacticity content. The thermal treatment, i.e., the rate of cooling from the melt, is also important and a clear molecular weight effect has been also found for the sample with lowest Mw. These factors affect the thermal properties, the degree of crystallinity and, therefore, the structural parameters and the viscoelastic behavior. A slow cooling from melt favors the formation of the γ phase instead of the α modification. The storage modulus, Young modulus and microhardness values increase as crystallinity does, independently of the origin of this increase: higher isotacticity or application of a slow crystallization from the melt. 相似文献
59.
Ferdous Khan Diana Kwek E. Kronfli S.R. Ahmad 《Polymer Degradation and Stability》2007,92(8):1640-1644
Excimer laser-induced crosslinking of ethylene-propylene-diene elastomer using a trace amount of photoinitiator, 1-hydroxy cyclohexyl phenyl ketone, was evaluated. Gel content measurements on irradiated samples showed that crosslinking was a natural consequence in all, which had undergone exposure to laser radiation. Degree of crosslinking was found to be linear with the laser exposure energy and was found to reach a saturation value of approximately 80% at about 100 J. However, for thicker samples the dependence of gel content i.e. crosslinking was found to be exponential over the range of laser exposure energy in excess of 200 J. As is expected, the tensile strength increased significantly with the increase of crosslinking. The band at 808 cm−1 in the infrared spectra was attributed to the 5-ethylidene-2-norbornene (ENB) content in the polymer. The ENB has a double bond which is considered to be consumed with a high radiochemical yield and thereby contributes to the increase in rate of the formation of intermolecular bridge density. 相似文献
60.
Jennifer S. Forrester Jennifer S. Zobec Erich H. Kisi 《Journal of solid state chemistry》2004,177(10):3553-3559
The pressure-less sintering behavior of PbTiO3 powders synthesized by mechanical alloying TiO2 and PbO was investigated using dilatometry and Rietveld refinements of X-ray diffraction patterns. As-synthesized, the powders are nanocrystalline with a mean particle size of 20 nm. Pressure-less sintering in the range 500-1050°C gives single phase ceramics with densities of 85-90% and crystallite sizes in the range 80-400 nm. Cracking due to the paraelectric-ferroelectric phase transition was not observed in samples sintered below 700°C due to the small crystallite size whereas macroscopic cracks formed in samples sintered above 700°C. Rietveld analysis indicates the formation of Pb vacancies in samples sintered and held for 24 h at intermediate temperatures (600-1000°C) which gives some insight into the mechanism of Pb loss and second phase formation in this system. 相似文献