含有吲哚并咔唑基团的热激发延迟荧光双极性主体材料的设计、合成及应用

设计合成了一种含吲哚并咔唑基团的有机电致发光主体材料10-苯基-10-(4-(7-苯基吲[2,3-b]咔唑-5(7H)-基)苯基)蒽-9-(10H)-酮(DphAn-5PhIdCz).通过核磁氢谱对其结构进行了表征,测试了它的紫外-可见吸收波长、荧光发射波长、荧光量子产率和瞬态荧光寿命等光物理性能,该材料具有双极性和热延迟荧光特性.通过将DphAn-5PhIdCz作为绿色发光体(ppy)2Iracac的主体,制备了高效低滚降的磷光有机电致发光器件(PhOLED),其最大发光效率达到56.12 cd·A-1,外量子效率15.70%,最大功率效率71.3lm·W-1.这些数据表明Dph An-5Ph IdCz作为Ph OLED主体材料在有机发光二极管(OLED)显示和照明具有较大的潜在应用价值.     

具有陷波电路结构的P波段低温低噪声放大器

该文的工作是设计和制作了一种具有陷波电路结构的P波段低温低噪声放大器。在低温75K环境下,工作频段为250-350MHz的范围内,该低温低噪声放大器具有优异的性能,噪声系数小于0.4dB,增益为14.4dB,增益平坦度小于0.05dB,输入反射损耗S11<-20dB,输出反射损耗S22<-20dB。同时在工作频段外的高温超导滤波器寄生通带内,该低温低噪声放大器成功实现了传输陷波响应,加强了系统对前端高温超导滤波器产生的寄生通带的衰减和抑制。     

Compact superconducting single-and dual-band filter design using multimode stepped-impedance resonator

This study presents two multimode stepped-impedance structures to design single-and dual-band filters. Transmission zeroes are introduced for the single-band filter by using dual-mode stepped-impedance resonators. The single-band filter with high selectivity is centered at 6.02 GHz and has a fractional bandwidth(FBW) of 25.6%. Four stubs(two low frequency and two high frequency ones) are connected to the rectangular patch in the center to construct a quadruplemode resonator. The independent conditions of the center frequencies of the high and low bands of the resonator are analyzed. A dual-band filter, which operates at 1.53 GHz and 2.44 GHz with FWBs of 12.1% and 14.1%, respectively is designed. The single-and dual-band filters are both fabricated with double-sided YBCO films and they can be used in mobile and satellite communications.     

Dependence of charge trapping of fluorescent and phosphorescent dopants in organic light-emitting diodes on the dye species and current density

This paper utilizes multilayer organic light-emitting diodes with a thin layer of dye molecules to study the mechanism of charge trapping under different electric regimes. It demonstrates that the carrier trapping was independent of the current density in devices using fluorescent material as the emitting molecule while this process was exactly opposite when phosphorescent material was used. The triplet--triplet annihilation and dissociation of excitons into free charge carriers was considered to contribute to the decrease in phosphorescent emission under high electric fields. Moreover, the fluorescent dye molecule with a lower energy gap and ionized potential than the host emitter was observed to facilitate the carrier trapping mechanism, and it would produce photon emission.     

独立寻址的色温可调白光有机电致发光二极管

提出了一种利用Ag/Al电极作为叠层结构的连接层,有效调控白色有机电致发光器件(WOLEDs)的发射光谱和提高器件的发光效率的新方法。当连接层厚度从9nm降到5nm,白光区域内的色坐标从(0.27,0.29)变化到(0.38,0.31)。此外,通过调控任意色度的互补色(蓝黄)WOLEDs,成功地制备了色温从8009K到4539K的可以独立寻址的器件。最后,论文讨论了基于独立寻址实现色温可控的红绿蓝三基色WOLEDs的光电性能。     

微型SMES用超导储能磁体试验研究

超导储能磁体是超导储能系统(SMES)的关键部件,因此有必要在SMES系统运行前对超导储能磁体进行系统试验研究.本文以第二代高温超导(YBCO)线材设计制作的超导储能磁体为试验对象,通过降温试验、临界电流测试、储能量测试和对地绝缘测试等试验测试并分析了超导储能磁体的电气和低温绝缘性能.试验结果表明:超导储能磁体基本性能...     

介质谐振器法测量高温超导薄膜微波表面电阻的误差分析

用微扰法研究了两端接地型蓝宝石介质谐振器测量高温超导薄膜微波表面电阻R_S的误差与几何结构和工作频率的关系.结果表明,介质柱直径与高度之比2a/L,金属屏蔽腔内半径与介质柱半径之比b/a以及工作频率f对测量误差和最小可测表面电阻R_smin有很大影响.所得到的曲线可用于蓝宝石介质谐振器的设计中.结果还表明,适当选取2a/L,b/a与f可使测量误差接近于1%,最小可测表面电阻R_smin可达到微欧姆的数量级.这对于高温超导薄膜的检测和微波器件应用说 关键词： 介质谐振器 高温超导薄膜 微波表面电阻 误差分析     

Pure blue and white light electroluminescence in a multilayer organic light-emitting diode using a new blue emitter

We characterized the 6,12-bis{[N-（3,4-dimethylphenyl）-N-（2,4,5-trimethylphenyl）]amino} chrysene （BmPAC）, which has been proven to be a blue fluorescent emission with high EL efficiency. The blue fluorescent device exhibits good performance with an external quantum efficiency of 5.8% and current efficiency of 8.9 cd/A, respectively. Using BmPAC, we also demonstrate a hybrid phosphorescence/fluorescence white organic light-emitting device （WOLED） with high efficiency of 36.3 cd/A. In order to improve the relative intensity of blue light, we plus a blue light-emitting layer （BEML） in front of the orange light emitting layer （YEML） to take advantage of the excess singlet excitons. With the new emitting layer of BEML/YEML/BEML, we demonstrate the fluorescence/phosphorescence/fluorescence WOLED exhibits good performance with a current efficiency of 47 cd/A and an enhanced relative intensity of blue light.     

基于深蓝光激基复合物构筑的OLED植物照明光源

为了得到可应用于植物照明且具有红蓝光谱的有机发光二极管（OLED）,采用两种典型的载流子传输材料,N,N′-二（1-萘基）-N,N′-二苯基-（1,1′-联苯）-4,4′-二胺（NPB）和1,3,5-三（1-苯基-1 H-苯并[d]咪唑-2-基）苯基（TPBi）以界面接触或掺杂的方式形成深蓝光激基复合物,并将其与红色磷光材料Ir（DMP-IQ）₂（acac）结合,制备得到符合植物光合作用光谱需求的OLED器件。通过改变器件结构中深蓝光激基复合物和红光发光层之间的间隔层厚度,可调节电致光谱中的蓝/红光强度比例。在以掺杂的方式形成激基复合物的结构基础上,将主体材料（mCP）掺入NPB···TPBi膜中构成三元体系,减少膜中由载流子堆积引起的激子淬灭,在NPB···TPBi···mCP掺杂比例为1···1···3的实验条件下得到2.8 V的开启电压,4528 cd/m²的亮度,3.09 cd/A的电流效率和6.96%的外量子效率。     

CDMA移动通信用高温超导滤波器的研制

本文提出了一种新型H型环带谐振器,具有结构紧凑,尺寸小,Q值高,非相邻耦合弱等优点.该谐振器在一侧设置了一个开口,改变开口位置,可以在较大范围内改变谐振器谐振频率,并且能够改变基频和二倍谐频之间的频率间隔.对于直连型馈线引入方式,H型环带谐振器容易实现外部Q值的匹配,同时对输入/输出端谐振器的谐振频率影响很小.本文还基于H型环带谐振器,采用2英寸双面YBCO高温超导薄膜设计并制作了用于CDMA移动通信系统的12节高温超导滤波器.该滤波器的中心频率为832MHz,相对带宽为1.6%.在70K温度下的测试结果显示滤波器的带内插入损耗低于0.28dB,反射损耗优于-15.5dB,带外抑制约为75dB,通带低频端带边陡峭度超过30dB/MHz,高频端带边陡峭度超过20dB/MHz.