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Dependence of charge trapping of fluorescent and phosphorescent dopants in organic light-emitting diodes on the dye species and current density
作者姓名:魏斌  廖英杰  刘纪忠  路林  曹进  王军  张建华
作者单位:Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China;Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China;Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China;Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China;Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China;Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China;Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China
基金项目:Project supported by the Key Project of Shanghai Education Committee (Grant No.~08ZZ42), and Science and Technology Commission of Shanghai Municipal (Grant Nos.~08PJ14053, 08DZ1140702 and 08520511200).
摘    要:This paper utilizes multilayer organic light-emitting diodes with a thin layer of dye molecules to study the mechanism of charge trapping under different electric regimes.It demonstrates that the carrier trapping was independent of the current density in devices using fluorescent material as the emitting molecule while this process was exactly opposite when phosphorescent material was used.The triplet-triplet annihilation and dissociation of excitons into free charge carriers was considered to contribute to the decrease in phosphorescent emission under high electric fields.Moreover,the fluorescent dye molecule with a lower energy gap and ionized potential than the host emitter was observed to facilitate the carrier trapping mechanism,and it would produce photon emission.

关 键 词:organic  light-emitting  diodes  excitation  mechanism  charge  trapping  current  density
收稿时间:2009-06-14

Dependence of charge trapping of fluorescent and phosphorescent dopants in organic light-emitting diodes on the dye species and current density
Wei Bin,Liao Ying-Jie,Liu Ji-Zhong,LuLin,Cao Jin,Wang Jun and Zhang Jian-Hua.Dependence of charge trapping of fluorescent and phosphorescent dopants in organic light-emitting diodes on the dye species and current density[J].Chinese Physics B,2010,19(3):37105-037105.
Authors:Wei Bin  Liao Ying-Jie  Liu Ji-Zhong  LuLin  Cao Jin  Wang Jun and Zhang Jian-Hua
Institution:Key Laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai University, Shanghai 200072, China
Abstract:This paper utilizes multilayer organic light-emitting diodes with a thin layer of dye molecules to study the mechanism of charge trapping under different electric regimes. It demonstrates that the carrier trapping was independent of the current density in devices using fluorescent material as the emitting molecule while this process was exactly opposite when phosphorescent material was used. The triplet--triplet annihilation and dissociation of excitons into free charge carriers was considered to contribute to the decrease in phosphorescent emission under high electric fields. Moreover, the fluorescent dye molecule with a lower energy gap and ionized potential than the host emitter was observed to facilitate the carrier trapping mechanism, and it would produce photon emission.
Keywords:organic light-emitting diodes  excitation mechanism  charge trapping  current density
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