Novel preparation of NaA/carbon nanocomposite thin films with high permeance for CO2/CH4 separation

Novel NaA/carbon nanocomposite thin films were successfully prepared on a porous a-Al2O3 substrate by incorporatingnanosized NaA zeolite into novolak-type phenolic resin.The prepared films were characterized by XRD,SEM and single gaspermeation tests.The NaA zeolite/carbon nanocomposite thin films exhibited that the ideal separation factor of CO2/CH4 was 28.4and the carbon dioxide flux was 3.39*10-7mol/(Pa m2s)at room temperature and under a pressure difference of 100 kPa,whichwas two orders of magnitude higher than that of pure carbon membrane prepared at the same procedures and conditions as those ofcomposite films.From the SEM images,the films were continuous and highly intergrown.Compared with carbon membranes,thethickness of nanocomposite films was drastically decreased,which was helpful to reduce the diffusion resistance and increase theflux of gas permeance.     

Capillary electrophoresis with direct chemiluminescence detection for the analysis of catecholamines in human urine

A rapid and sensitive method for the analysis of three catecholamines by capillary electrophoresis(CE)with directchemiluminescence(CL)detection is described.The detection limits(S/N=3)were 1.3*10-8g/mL for isoprenaline,1.0*10-8g/mL for epinephrine and 2.8*10-8g/mL for dopamine.The proposed method was successfully applied to theanalysis of catecholamines in urine samples of cigarette smokers and nonsmokers.The results showed that there is a close relationbetween the release of dopamine in human body fluids and cigarette smoking/nonsmoking.     

Synthesis and characterization of insulin-5-Fu conjugate,enabling insulin as multi-drug carrier via dendritic approach

To enable insulin as multi-drug carrier, we designed and synthesized dendritic linker molecule bearing three 5-Fluorouracil residues at the branch ends. The new conjugate showed excellent water solubility. The stabilities under different conditions were investigated. The results showed that the conjugate was a potential prodrug to release free 5-Fu.     

Synthesis, Characterization, Spectroscopic Properties of 2-（4-Dimethylaminophenyl）-5-fluoro-6-（morpholin-4-yl）-1H-benzimidazole and its Interaction with Calf Thymus DNA

Benzimidazole compounds have attracted a renewed interest recently owing to theirpotential applications in high-performance composite materials, electronic chemicals,photosensitive materials, and their special potentials in biological and/or medicinalapplication1,2. Typically, aromatic compounds with near planar structures and contain-ing hydrogen-donor groups or groups, which are capable of being protonated, havespecial interactions with DNA via intercalation, hydrogen-bonding, and so on3.Me…     

HL-2A装置电子回旋传输系统

近年来，电子回旋共振加热和驱动在许多装置上得到应用，例如：Tore Supra。JT-60U和Heliotron J，与其它加热和驱动方法相比，它具有以下优点。电子回旋波能以能量集中的高斯模式注入，产生高度集中的功率沉积，能进行理想的MHD不稳定性控制。     

New conversion of Friendlnder reaction of 3-amino-1H-benzo[f]chromene-2-carbonitriles with cyclohexanone

Two different skeletons of heterocyclic compounds,quinoline and quinazolinone analogs could be obtained by a novel one-pot synthesis from substituted 3-amino-1 H-benzo[f]chromene-2-carbonitrile derivatives and cyclohexanone in DMF in the catalyst of anhydrous zinc chloride under reflux.A plausible mechanism was proposed.     

HL-2A装置ECRH系统回旋管超导磁体的调试

为了在HL-2A装置上开展电子回旋共振加热实验研究，我院从俄罗斯GYCOM公司引进了两套4mm回旋管。它们均配有一个超导磁体系统，提供回旋管所需的磁场位形。回旋管中的磁场不仅仅起聚焦作用，更重要的是形成回旋电子束必不可少的，其作用为：（1）电子要产生回旋运动必须要有磁场；（2）回旋电子束要获得足够强的横向能量必须有足够强的绝热压缩量。通过调试测量了磁体磁场分布，确定了磁体工作电流及回旋管工作频率。     

Synthesis,X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru_3~Ⅲ(μ_3-O)(μ-CH_3COO)_6(py)_2Cl with Four Steps One-electron Redox Processes

Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl…     

Structural Study of Inclusion Complex of Andrographolide with β-Cyclodextrin Prepared under Microwave Irradiation

Andrographolide (Andro) (Figure 1) is a diterpene lactone isolated from Andrographis paniculate Nees1. It has showed several biological activities including analgesic, antipyretic and anti-inflammatory effects2. However, its poor water solubility and unstability towards oxygen restrained its application. In pharmaceutics, b-CD is used to increase solubility and stability3. We have prepared the inclusion compound of Andro/b-CD (Figure 2) under microwave irradiation4. It has been found…     

Variable time-period optical switching:a novel OBS implementation

In this paper, we proposed a novel optical switching method based on optical burst switching (OBS), we call it variable time-period optical switching (VTPOS). It can both support circuit services and other immerged packet services. It has better usability of bandwidth, shorter offset and latency time than others of unidirectional transport signaling mechanisms for OBS. It supports deflection switching for improve blocking performance without the need of schedule buffer. It introduces a time pointer and phase indicator that made synchronous more precisely and requires less guard time, it also classifies the different services classes with a relative QoS model.