温度与温标

一、引 言 人类对于冷热的感觉是在很早以前就有的.夏季的炎日,寒冬的冰河,早就作用于他们的感官并逐渐在人们的头脑里形成了概念.但是,使冷热的概念精确化、温度(数值)和温度计的出现,却是近三百年来的事情.1660年酒精温度计的出现是向冷热现象作探讨的重要一步.1714年华伦海脱(Fahrenheit)改良了水银温度计,大体上以当地冬季最冷的气温为0℃,以人的体温约为100°,这样一来,就造成了水的冰点为32°,水沸点为212°的华氏温度计.冰点和水沸点之间的温度划为180个等分,每一等分叫做华氏1°,温度数值的如此表示法,叫做华氏温标.虽然工业和科学…     

金属络合物分子内的电子迁移反应

1.前言金属络合物的电子迁移反应,有外圈型反应(即二个金属离子的内圈配位体之间不发生交换)机制(OS机制)和内圈型反应(即二个金属离子的内圈配位体之间发生了交换)机制     

Theoretical Strength of Face-Centred-Cubic Single Crystal Copper Based on a Continuum Model

The constitutive relation of single crystal copper based on atomistic potential is implemented to capture the nonlinear inter-atomic interactions. Uniaxial loading tests of single crystal copper with inter-atomic potential finite-element model are carried out to determine the corresponding ideal strength using the modified Born stability criteria. Dependence of the ideal strength on the crystallographic orientation is studied, and tension- compression asymmetry in ideal strength is also investigated. The results suggest that asymmetry for yielding strength of nano-materials may result from anisotropic character of crystal instability. Moreover, the results also reveal that the critical resolved shear stress in the direction of slip is not an accurate criterion for the ideal strength since it could not capture the dependence on the loading conditions and hydrostatic stress components for the ideal strength.     

基于CUDA的多GPU加速SART迭代重建算法

为解决SART迭代重建算法计算耗时的问题,在单GPU基础上,利用多块GPU 的并行计算能力,提出了一种多GPU加速迭代重建算法。实验结果表明,与CPU重建相比,在不影响重建图像质量的情况下,采用GPU重建速度有明显提高,且增加GPU数量可以进一步提高重建速度。     

Synthesis and properties of Au-Fe3O4 and Ag-Fe3O4 heterodimeric nanoparticles

Monodisperse Au-Fe 3 O 4 heterodimeric nanoparticles (NPs) were prepared by injecting precursors into a hot reaction solution.The size of Au and Fe 3 O 4 particles can be controlled by changing the injection temperature.UV-Vis spectra show that the surface plasma resonance band of Au-Fe 3 O 4 heterodimeric NPs was evidently red-shifted compared with the resonance band of Au NPs of similar size.The as-prepared heterodimeric Au-Fe 3 O 4 NPs exhibited superparamagnetic properties at room temperature.The Ag-Fe 3 O 4 heterodimeric NPs were also prepared by this synthetic method simply using AgNO 3 as precursor instead of HAuCl 4.It is indicated that the reported method can be readily extended to the synthesis of other noble metal conjugated heterodimeric NPs.     

一类二阶非线性差分方程的全局吸引性

考虑二阶非线性差分方程xn＋1=a＋bxn/A＋xn-1,n=0,1,2,….证明了当条件a,b,A∈（0,∞）成立时方程的唯一正平衡点x^-=（b-A＋√（（b-A）2＋4a））～（1/2））/2是方程的所有正解的一个全局吸引子,所得推论证明了由Kocic和Ladas提出的一个猜想是正确的.     

Numerical Simulation of the Elastic Shrinkage Induced by Portevin-Le Chatelier Effect

A new one-dimensional phenomenological model based on the dynamic strain aging mechanism is developed. In order to account for the elastic shrinkage induced by the Portevin-Le Chatelier effect, elastic deformation is considered under the boundary conditions of the present model. The simulated results are found to be in good agreement with the experimental observations.     

Synthesis and Crystal Structure of a New 2D Honeycomb-like Cadmium(II) Complex with Tripodal Ligand

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Nd2Fe14B/α-Fe双泪永磁合金快淬带的织构与形貌

利用X射线衍射仪和扫描探针显微镜研究了NeFeB系双相永磁合金快淬带的织构与形貌.结果表明,合金快淬带自由面存在择优取向.与三元NdFeB合金相比,复合添加Dy和Ga具有增加合金快淬带织构和细化组织形貌的作用. 关键词：     

流动-差热吸附量热系统 Ⅰ. 装置考察与氢型丝光沸石(HM)-苯体系吸附热的测定

本文介绍了一种差热分析(DTA)与色谱联用的吸附量热系统。经特别设计的柱恒温箱把差热与色谱结合起来, 达到了吸附量热所要求的高灵敏度与低噪声。配置了可变宽度的矩形脉冲进样系统。进样与响应的同步性良好。结合 HM-苯体系吸附热的测定, 给出了量热图谱的解析方法。得出了与文献中吸附微量热计接近的结果。利用本系统还可获得吸附平衡的信息。结果表明, 量热与吸附平衡实验数据之间具有良好的一致性。本系统适用于在接近工业反应的动态条件下研究催化剂的吸附性能。