固相萃取-液相色谱-离子阱二级质谱法同时测定饮用水中多种痕量有机污染物

建立了高效液相色谱-离子阱二级质谱法同时测定饮用水中内分泌干扰物、农药残留和丙烯酰胺等15种痕量有机污染物的方法。250mL水样先用C18固相萃取柱富集,经梯度洗脱液相色谱分离,采用时间分段的方法确定各组分质谱检测条件,利用离子阱二级质谱进行测定。所检测的15种有机污染物定量线性关系良好,相关系数为0.9975～0.9998,检测限在0.2～20ng/L之间。在低、中、高3个不同加标水平下,实际水样的加标回收率为75.1%～99.5%,相对标准偏差为4.6%～12.3%。该方法成功用于5种不同来源饮用水样的检测,获得了满意结果。     

PS-PBA粒子分散系的介电弛豫谱解析——同、反离子对弛豫的影响及表界面电参数的计算

制备了近纳米级的聚苯乙烯-丙烯酸丁酯(PS-PBA)复合微球粒子,并在40Hz～110×106Hz的宽频范围测量了该粒子分散在9种电解质中时的介电弛豫谱,发现了与PS微球粒子分散系不同的特异介电弛豫:低频弛豫对反离子种类具有敏感性而高频弛豫则与电解质种类几乎无关;根据Shilov-Dukhin模型和M-W-O模型分别分析了高、低频率的弛豫机制,并通过对介电谱的Cole-Cole拟合获得了各体系的介电参数.进一步利用Hanai方法由介电参数计算获得了所有体系的相参数;详细分析了体系的内部参数受PS-PBA微球自身结构以及电解质种类影响的原因;讨论了离子扩散系数对介电参数的影响,从而得出了低、高频的弛豫特征时间分别由同离子的扩散系数和反离子的扩散系数所决定之结论.最后,结合Grosse宽频介电理论计算了粒子表面的以及双电层的主要电参数,并分析了电解质种类差异对这些电参数的影响.     

高功率光纤激光器二级抽运技术的理论分析

从理论上分析了高功率光纤激光器直接抽运和二级抽运的斜率效率和热管理问题. 计算结果表明:波长为975 nm的激光直接抽运产生波长为1070 nm的激光时,理论斜率效率为80%,但当抽运光功率为10 kW时,在强制水冷条件下纤芯极值温度也难以降到150 ℃以下;在二级抽运技术中,波长为1018 nm的激光抽运产生波长为1070 nm的激光时,若采用传统的包层抽运技术,其斜率效率不足20%,如果抽运功率填充因子由0.0025提高到0.1,则理论上斜率效率可由18.5%提高到80.9%,从而总斜率效率由15.5 关键词： 二级抽运 功率填充因子 斜率效率 热管理     

扩散模型中扩散系数的非参数组合估计

为了提高扩散系数估计的准确度, 我们利用动态组合时间域与状态域信息提出一个新的组合估计量. 我们发现所提组合估计量能有效估计扩散模型的扩散系数, 正如在本文中模拟所示. 在一定的条件下, 建立了估计量的渐进正态性, 并证明了时间域估计量与状态域估计量是渐进独立的. 大量的模拟展示了所提组合估计量优于单域估计量, 也优于本文所提估计量.     

布朗扩散系数对胶体聚集粒子簇大小动态标度影响的MonteC …

通过对胶体扩散控制聚集机理的ＭｏｎｔｅＣａｒｌｏ模拟，表明粒子簇的布朗扩散系数与其大小和形状有关，粒子簇的大小分布可被标度、在微观或介观的层次上，揭示了表征粒子簇结构的几何形状因子在扩散控制聚集过程中对动态标度和粒子簇分布的影响。     

The carbon impurity ohmic discharges on particle transport in the HT-7 tokamak

The line-integrated optical measurement of impurity radiation profiles for the study of light impurity transport is performed in the HT-7 tokamak. The carbon impurity line emissivity is obtained by Abel inversion. The radial transport behaviours of carbon impurities at different central line averaged electron densities ne are investigated in ohmic discharges. The diffusion coefficient Dk（r）, the convection velocity Wk（r） and the total flux of the impurity ions Fk decrease with the increase of ne, which shows a reduction in the impurity particle transport at higher electron densities.     

Universal Scaling Law for Atomic Diffusion and Viscosity in Liquid Metals

The recently proposed scaling law relating the diffusion coefficient and the excess entropy of liquid [Samanta A et al. 2004 Phys. Reu. Lett. 92 145901; Dzugutov M 1996 Nature 381 137], and a quasi-universal relationship between the transport coefficients and excess entropy of dense fluids [Rosenfeld Y 1977 Phys. Rev. A 15 2545],are tested for diverse liquid metals using molecular dynamics simulations. Interatomic potentials derived from the glue potential and second-moment approximation of tight-binding scheme are used to study liquid metals.Our simulation results give sound support to the above-mentioned universal scaling laws. Following Dzugutov,we have also reached a new universal scaling relationship between the viscosity coefficient and excess entropy.The simulation results suggest that the reduced transport coefficients can be expressed approximately in terms of the corresponding packing density.     

液体扩散时的折射率分布和扩散系数的测定

本实验提供一种测量透明度或半透明度液体的折射率和扩散系数的方法。此方法可用于食品工业、日用化学工业、石油工业及制药工业部门。     

A NEW MODEL FOR ESTIMATION OF DIFFUSION COEFFICIENT OF PHENOL DESORPTION WITHIN POLYMERIC RESIN UNDER ULTRASOUND

4 new model, phase equilibrium-kinetics model (PEKM), for estimation of diffusioncoefficient was proposed in this paper. Kinetic experiments of phenol desorption on NKAII resin inthe presence and the absence of ultrasound were separately conducted, and diffusion coefficients ofphenol within an adsorbent particle were estimated by means of proposed PEKM and classicsimplified model. Results show that the use of ultrasound not only changes the phase equilibriumstate of NKAll resin/phenol/water system which had been equilibrium at normal condition, but alsoenhances diffusion of phenol within the resin. The diffusion coefficient of phenol in the resin in thefield of ultrasound increases in an order of magnitude in comparison with the diffusion coefficientdetermined under no ultrasound Experimental results also indicated that the diffusion coefficientsestimated by PEKM were more accurate than that estimated by the classic simplified model.     

用逐步二级分辨数学模型预测农业害虫种群动态

文章应用基本Ｆｉｓｈｅｒ准则下逐步二级分辨原理，对山东省临沂市１９６５～１９８６年（１９８０年除外）共２１年的第二代玉米螟虫株率的历史观测数据进行了数量分析，建立了３个逐步二级分辨数学模型。经对历史资料的回报验证，其历史符合率分别为９５．２４％、９２．３１％、１００％。将１９８７年、１９８８年观测数据作为独立样本进行试报，其预报结果与实际一致。