Characterization of silicone oil emulsions stabilized by TiO2 suspensions pre-adsorbed SDS

To study the effects of pre-adsorbed emulsifier on Pickering emulsion stability, the preparation of silicone oil emulsions by TiO₂ suspensions pre-adsorbed sodium dodecyl sulfate (SDS) at the fixed TiO₂ concentration of 0.15 g was carried out below a fiftieth of critical micelle concentration (cmc) of SDS, where all added amounts of SDS are adsorbed on the TiO₂ particles. The stability of the Pickering emulsions incorporating TiO₂ suspensions pre-adsorbed SDS was investigated by measuring the volume fraction of emulsified silicone oil, adsorbed amounts of TiO₂ suspensions pre-adsorbed SDS, oil droplet size, and some rheological responses such as the stress-strain sweep curve and strain and frequency dependences of dynamic viscoelastic moduli. The silicone oil was almost emulsified by TiO₂ suspensions pre-adsorbed SDS above cmc/10³. Increasing in the adsorbed amount of SDS on the TiO₂ particles leads to an increase in the adsorbed amounts of TiO₂ suspensions pre-adsorbed SDS. Such silicone oil emulsions for the first time showed two yield stresses in the stress-strain sweep curve as well as the oscillatory stress-strain curve. The respective yield stresses also increase with an increase in the adsorbed amounts of TiO₂ suspensions pre-adsorbed SDS. From such characteristic rheological properties and a partial sedimentation of some TiO₂ particles remained in the dispersion medium, we proposed the formation of a three dimensional network of the flocculated TiO₂ particles pre-adsorbed SDS on the silicone oil droplets.     

1.09万m^3蛋形壳体结构无粘结预应力张拉分析

本文通过对杭州市四堡污水处理石蛋形消化池无粘结预应力张拉对混凝土结构影响的试验研究,测定了张拉应力的影响范围,分析了预应力张拉工艺,比较了规范与施工相近有关系数的取值,提出了供设计、施工参考采用的控制张拉力和张拉工艺等。     

The elastic anisotropy of nematic elastomers

We examine the robustness of order in nematic elastomers under mechanical strains imposed along and perpendicularly to the director when director rotation is prohibited. In contrast to electric and magnetic fields applied to conventional nematics, mechanical fields are shown theoretically and experimentally to greatly affect the degree of nematic order and related quantities. Unlike in liquid nematics, one can impose fields perpendicular to the director, thereby inducing biaxial order which should be susceptible to experimental detection. Nematic elastomers with unchanging director and degree of order should theoretically have the same elastic moduli for longitudinal and transverse extensions. This is violated when nematic order is permitted to relax in response to strains. Near the transition we predict the longitudinal modulus to be smaller than the transverse modulus; at lower temperatures the converse is true, with a crossover a few degrees below the transition. The differences are ascribed to the different temperature dependence of the stiffness of uniaxial and biaxial order. We synthesised side chain single-crystal nematic polymer networks, performed DSC, X-ray, birefringence, and thermo-mechanical characterisations, and then obtained linear moduli from stress-strain measurements. Received 29 September 2000     

基于迟滞应力应变关系的非线性声学检测理论与方法研究

本文将传统PM(Preisach-Mayergoyz)模型由一维介质拓展到二维介质,引入迟滞细观弹性单元概念,得到迟滞变化的应力应变关系.并采用一阶有限差分方程进行了声场计算和分析,发现空间声场中含有明显的高阶奇次谐波成分.对接收到的全波信号进行滤波、放大、时间反转后加载到接收换能器对应阵元上再进行发射,观察到高次谐波在微损伤区域实现聚焦.这为利用非线性高次谐波检测微损伤提供了可能的途径,也为疲劳损伤等缺陷的早期检测提供了理论和方法依据.     

本征磁性拓扑绝缘体MnBi2Te4电子结构的压力应变调控

由于MnBi2Te4电子结构具有对晶格常数的改变相当敏感的特性,本文采用基于密度泛函理论的第一性原理方法对MnBi2Te4反铁磁块体的电子结构施加等体积应变调控.研究发现体系能带结构在材料等体积拉伸和压缩作用下变化灵敏,体系出现绝缘体-金属相变.特别地,当施加特定应变后导带和价带在Γ处出现交叉,体系呈零带隙状态.在此应变下仍可观察到能带反转的现象,具有非平庸的能带拓扑性质.根据不同应变下的电荷密度图,发现等体积应变会影响体系七倍层层间距,其中等体积压缩和拉伸应变可分别增大和减小Te原子层间距,表明等体积压缩有利于降低反铁磁层间耦合.通过等体积压力应变调控,掌握了MnBi2Te4的电子结构的变化规律,这对本征磁性拓扑绝缘体MnBi2Te4的物性研究和实验制备具有重要的指导意义.     

射电偏振仪PПy—1的结构及其工作原理

本文介绍了射电偏振仪ＰПｙ—１的结构及其工作原理。该仪器是利用发射偏振的超高频无线电磁波透射复合材料构件，对接收到的信号进行分析来确定构件在工作状态下的应力应变值。本文还通过测试实例说明了仪器的使用及各种参数的确定方法。     

Equibiaxial deformation of poly(4-methyl-1-pentene) by a forging process

Poly(4-methyl-1-pentene) (PMP) has been uniaxially compressed by a forging (equibiaxial) process. The rheology of the process has been examined for this semicrystalline polyolefin, melting point about 235°C. The yield energy, area under the compressive stress-strain curve up to the yield point, as a function of temperature was found to consist of two linear components of different slope. These two linear relations arise from the glassy and crystalline phases of PMP. The intercept temperature (T_i) at zero yield energy for the glassy phase has been evaluated. The attainable maximum compression ratio without sample rupture (CR_max) increased steadily on increasing forging temperature above T_i, and below T_m. In this range, the crystalline relaxation temperature (T_c), evaluated from an Arrhenius plot of yield stress was 160°C. Above T_c, a CR_max of 240 was reached. This value is five times higher than that attained for isotactic polypropylene (i-PP). However, the draw efficiency evaluated by elastic recovery in the plane direction of PMP (0.76) is lower than for i-PP (0.97). Differential scanning calorimetry analyses showed that the melting peak became a complex doublet on increasing compression ratio ( > 100). The drawing and stress-strain behavior of PMP are compared with i-PP. © 1994 John Wiley & Sons, Inc.     

国产航空有机玻璃(PMMA)的压缩应力-应变行为研究——Ⅱ.力学性能特征参数分析

讨论从加卸载循环的应力-应变表征曲线提取得到的各材料力学性能,尤其是关于屈服和塑性变形的特征参数。包括加卸载弹性模量E_L~T,E_u~T;屈服点的表征参数:屈服应力σ_s~T,屈服应变ε_s~N,屈服应变能U_s;热激活塑性变形的表征参数:活化体积V_τ和活化能ΔH。讨论这些参数对温度和应变率的依赖关系,寻求由这些特征参数作表述,或是存在于这些参数之间的经验关系或规律。     

Effect of dentin tubules to the mechanical properties of dentin. Part II: Experimental study

To verify the theoretical models of varying transversely isotropic stress-strain relations of dentin established in the preceding work (Part I), we perform a set of experiments. Because of the very fine tooth size, it usually seems to be difficult to directly measure the inhomogeneous and anisotropic parameters of dentin. In this paper, by the digital speckle correlation method, tensile experiments are made on the small dentin samples either parallel or perpendicular to the dentin tubules. With the theoretically predicted elastic stress-strain relations, an optimization method is proposed to fit the strain curve adapted to the experimental data. The results show that the theoretical elastic stress-strain relations coincides very well with the experimental observations. The determined Young's modulus and Poisson's ratio of dentin matrix are 29.5 GPa and 0.44, respectively, in the optimization sense. The project supported by the National Natural Science Foundation of China (19525207)     

δ-Al2O3短纤维增强Al合金复合材料的拉伸力学行为研究

利用宏观、微观实验和三维弹塑性有限元分析方法（FEM,对δ－Al_2O_3短纤维增强Al合金复合材料的弹性模具和应力-应变曲线进行预测,同时讨论该类材料的断裂特征．研究了纤维位向的变化并引入了实测的短纤维位向分布规律．研究表明,本文对该类复合材料的弹性模量和应力-应变曲线的预测是较为准确的．