非离子聚(N-乙烯基-2-吡咯烷酮)凝胶在线型聚(丙烯酸)溶液中的溶胀特性

研究了在线型聚 (丙烯酸 ) (PAA)溶液中链长、pH、离子强度和水 /二甲亚砜混合溶剂组成对非离子聚 (N-乙烯基 - 2 -吡咯烷酮 ) (PVP)水凝胶溶胀特性的影响 .发现聚酸浓度的变化引起凝胶显著的体积相变 ,这是因为凝胶和聚合物通过氢键形成了大分子间凝胶 -聚合物复合物 .凝胶的溶胀特性取决于聚酸的链长而不是离子强度 .随着pH值和水 /二甲亚砜混合溶剂组成的变化 ,凝胶的溶胀率 (SR)发生变化     

Optimized design of quasi-optical source-array of solid state source power combiner at frequency 100 GHz

It is determined for the structure of the source-array located in inner surface of input quasi-optical resonator operating at frequency 100GHz using Type WT5731 GaAs Gunn diodes made in P.R. China (fundamental frequency 50 GHz). An adaptable phase coupling has been achieved and RF output power exceeded the sum of the individual diode outputs by from three to seven times.     

Two millimeter solid-state source global optimum for quasi-optics power combiner

A global optimization method for discussing quasi-optical power combiner of solid-state millimeter-wave source is provided. The device we use operate at about 150 GHz and GaAs Gunn diodes are chosen here as active sources arranged in a planar matrix of N×N (N-3,5,..., 2k+1, where h is positive integer). The best array and the location of the active elements in the source-array plane which is the surface of one reflector we will discribe later can be given by global optimization, where the radio frequency power can reach sixfold to ninefold larger than the total sum of the individual diode power.Work suported by natural science fund of China.     

稀土络合催化聚合的顺-聚丁二烯的双峰分子量分布

用渗透压、粘度和尺寸排斥色谱方法研究了稀土络合催化聚合的顺丁橡胶在聚合过程中分子量和分子量分布的变化。络合催化剂中不同结构的烷基铝组分在聚合过程中起着不同的作用。对实验数据所作的分析指出,使用烷基铝和氢化烷基铝混合物组成的络合催化剂,聚合至高转化率时的聚丁二烯将出现双峰分布。烷基铝和氢化烷基铝的相反行为指示,聚合机理互有差异,而且不能简单地以链转移常数的不同来解释。     

磺化丁基橡胶离聚体及其共混物的动态力学性质

<正> 含10％摩尔以下的离子且主链为柔性的离聚体是一种热塑性弹性体。在动态力学性质方面呈现特殊的行为,表现在贮能模量(1gE′)与温度的关系中有橡胶态平台出现。最早Otocka等指出,(丁二烯-甲基丙烯酸)共聚物无橡胶态平台,经金属离子中和后产生橡胶态平台,且E′增加。Agarwal,Makowski等则报道磺化乙丙胶离聚体的橡胶态平台随离子含量提高而加宽,随硬脂酸锌的加入而缩短。Fitzgerald及Weisst结合X-射线小角散射研究了甘油及邻苯二甲酸二辛酯对磺化聚苯乙烯离聚体的动态力学性质的影响。     

Multiple Diodes Quasi-Optical Oscillater

This paper presents quasi-optics techniques, millimeter techniques and a global optimization method etc techniques. It is a structure of quasi-optics power combiner, that includes a spherical reflection, that the radius of the curvature is R and another one is a hybrid reflector that is called input reflector. The space of the both reflectors is LL. The monolithic source-array is made up of 25 Gunn diodes that are mounted of parallel brass bars that have low thermal resistance. And the bars are fixed on the inner plane surface of the hybrid reflector. The hybrid reflector made up of a plane and a spherical, that the radius of the curvature are R. It is designed that higher fundamental mode power, larger fractional power of fundamental mode power and more combining efficiency of the quasi-optics power combiner.This paper describes an algorithm, which can determine the global optima of the power combiner of solid-state millimeter wave resonator. The global optimization method can determine a neighborhood of the global optima of an objective function and an estimation of the global optima. In the quasi-optical resonator, the objective functions are the fundamental mode power, the fractional power of fundamental mode and the combining efficiency respectively.     

ICP-AES测定硅锰中的磷

采用电感耦合等离子体-原子发射光谱法(ICP-AES)研究了硅锰合金中磷的测定,考察了试样的分解、分析谱线的选择、干扰元素的影响及精密度和准确度等影响的有关因素,其测定结果与国家标准方法一致.磷的分析谱线采用214.914 nm的测定结果最好;该方法的检出限为0.003％,回收率为96.9％～101.6 ％.     

极端波动、跳跃和尾部风险——基于已实现波动率的股票市场风险动态预测

本文基于跳跃扩散波动理论,利用非参数方法估计波动中跳跃成份,研究我国股市波动中跳跃的动态演变特征,将跳跃作为股市波动的重要因素纳入模型,建立我国股指收益率的非齐次自回归已实现波动率模型,利用条件极值方法对我国股市的波动风险进行动态预测.统计结果表明:在股市大波动时期跳跃发生更为频繁,而且和连续成份相比较,跳跃对股指波动的贡献占据主要地位。和传统的EGARCH模型相比,包含跳跃的已实现波动率模型对股指波动风险预测性能明显优于EGARCH模型风险预测,跳跃对股指波动风险预测具有显著的解释力.对股市历史数据的分析和预测表明,跳跃对于股指日收益率尾部行为具有重要的影响,大跳跃的发生导致尾部风险显著增大。本文研究结果对于政府监管部门监控股市和制定有效的调控措施加强股市风险管理具有重要的参考价值。