全文获取类型
收费全文 | 9198篇 |
免费 | 735篇 |
国内免费 | 1563篇 |
专业分类
化学 | 6872篇 |
晶体学 | 67篇 |
力学 | 103篇 |
综合类 | 73篇 |
数学 | 2043篇 |
物理学 | 2338篇 |
出版年
2024年 | 24篇 |
2023年 | 108篇 |
2022年 | 204篇 |
2021年 | 302篇 |
2020年 | 280篇 |
2019年 | 269篇 |
2018年 | 257篇 |
2017年 | 256篇 |
2016年 | 301篇 |
2015年 | 263篇 |
2014年 | 284篇 |
2013年 | 716篇 |
2012年 | 444篇 |
2011年 | 635篇 |
2010年 | 518篇 |
2009年 | 788篇 |
2008年 | 732篇 |
2007年 | 681篇 |
2006年 | 673篇 |
2005年 | 541篇 |
2004年 | 398篇 |
2003年 | 320篇 |
2002年 | 385篇 |
2001年 | 304篇 |
2000年 | 302篇 |
1999年 | 241篇 |
1998年 | 217篇 |
1997年 | 161篇 |
1996年 | 172篇 |
1995年 | 128篇 |
1994年 | 104篇 |
1993年 | 87篇 |
1992年 | 77篇 |
1991年 | 52篇 |
1990年 | 29篇 |
1989年 | 22篇 |
1988年 | 36篇 |
1987年 | 21篇 |
1986年 | 25篇 |
1985年 | 27篇 |
1984年 | 19篇 |
1983年 | 10篇 |
1982年 | 11篇 |
1981年 | 18篇 |
1980年 | 14篇 |
1979年 | 15篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1974年 | 3篇 |
1973年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Deák L. Bottyán L. Major M. Nagy D. L. Spiering H. Szilágyi E. Tanczikó F. 《Hyperfine Interactions》2002,144(1-4):45-52
Hyperfine Interactions - Synchrotron Mössbauer Reflectometry (SMR), the grazing incidence nuclear resonant scattering of synchrotron radiation, can be applied to perform depth-selective phase... 相似文献
42.
本文报道了用吸附溶出伏安法测定毗喳酮.以悬汞电极为工作电极,在Na}B,O,-NaOH介质(pH=10)中,毗喳酮产生一尖锐的吸附还原峰,E,二一1. 29V (vs. SCE ),峰电流与毗喳酮浓度在2. 0 X 10-'-8. 0 X 10-smol " L-’范围内呈良好的线性关系.检测限为2. 0 X 10-0mol " L-'(富集90s).本文对毗喳酮在悬汞电极上的电化学行为进行了探讨,对测定毗喳酮的最佳条件进行了详细的选择,利用本法测定了片剂中毗喳酮含量,结果满意. 相似文献
43.
Keka Chakraborty S K Paranjpe V Siruguri O D Jayakumar S K Kulshreshtha 《Pramana》1997,48(6):1115-1122
Neutron diffraction and M?ssbauer measurements have been carried out on the cubic Laves phase intermetallic TbMnFe. The magnetic
moment on the transition metal atom is found to be low, 0.2μ
B, at room temperature. This moment is temperature independent down to 10 K. Magnetic moment on the rare earth atom varies
from 2.5μ
B at 296 K to 7.27μ
B at 10 K. M?ssbauer spectra recorded at 298 K and 78 K have magnetic character but there is a large distribution of hyperfine
field values. Both these features arise due to magnetic frustration created in the sample due to the competing ferro and antiferromagnetic
interactions between the transition metal atoms. 相似文献
44.
45.
The adsorption behavior (capacity, density distribution and packing density) and the isosteric heat versus loading in a slit pore whose walls contain defective graphene layers are investigated in this paper. The defective wall is characterized by the extent and size of the defect. Simulation results obtained with the Grand Canonical Monte Carlo method reveal complex patterns of isosteric heat, and this complex behavior is a result of the interplay between three factors: (i) the surface heterogeneity (solid-fluid interaction, sites with varying degree of affinity), (ii) fluid-fluid interaction and (iii) the overlapping of potentials exerted by the two defective walls. We illustrate this with argon adsorption in pores of various sizes, and results obtained from the simulation agree qualitatively with the experimental data at 77 K on Saran microporous S600H and micro-mesoporous S84 charcoals of Beebe et al. [R.A. Beebe, B. Millard, J. Cynarski, J. Am. Chem. Soc. 75 (1953) 839]. The S600H was found to contain pores predominantly in the neighborhood of 7 Å with 30% of defect and a defective size of 2.84 Å. This is consistent with the argument made by Beebe et al. that this sample is a microporous solid and most pores can accommodate only one layer. The other sample, S84, has larger pores than S600H, and it is found that it has a wider pore size distribution and the pore width is centered at about 12 Å. 相似文献
46.
Jesús de la Cal Javier Cárcamo 《Journal of Mathematical Analysis and Applications》2007,334(2):1106-1115
As a consequence of Jensen's inequality, centered operators of probabilistic type (also called Bernstein-type operators) approximate convex functions from above. Starting from this fact, we consider several pairs of classical operators and determine, in each case, which one is better to approximate convex functions. In almost all the discussed examples, the conclusion follows from a simple argument concerning composition of operators. However, when comparing Szász-Mirakyan operators with Bernstein operators over the positive semi-axis, the result is derived from the convex ordering of the involved probability distributions. Analogous results for non-centered operators are also considered. 相似文献
47.
An energy-dependent partitioning scheme is explored for extracting a small number of eigenvalues of a real symmetric matrix with the help of genetic algorithm. The proposed method is tested with matrices of different sizes (30 × 30 to 1000 × 1000). Comparison is made with Löwdin’s strategy for solving the problem. The relative advantages and disadvantages of the GA-based method are analyzed 相似文献
48.
G. K. Shenoy 《Hyperfine Interactions》2006,170(1-3):5-13
Stanley L. Ruby (1924–2004) made major contributions to Mössbauer spectroscopy and was the first to suggest the feasibility of observing the Mössbauer effect using synchrotron radiation. In this article we recall his scientific legacy that have inspired his scientific colleagues. 相似文献
49.
Fe–Al alloys around the concentration of 30 at. % Al present re-entrant spin-glass behaviour at low temperatures. This behaviour is not completely understood and Mössbauer spectroscopy, combined with other experimental techniques, is useful to describe and explain this behaviour. Results show that the Mössbauer spectra coincide with the magnetic behaviour showed in literature and they can be explained as a magnetic cluster system whose magnetic clusters are getting smaller when the temperature is decreasing. When the temperature is reaching to the spin-glass transition at 92 K the spins in the paramagnetic matrix are moving slower and below this transition the spins are completely frozen. 相似文献
50.