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41.
Novel Bi2MoO6 Nanosheets/Vertical TiO2 Nanorods Arrays Heterojunction with Enhanced Photoelectrochemical Performance under Visible Light Irradiation 下载免费PDF全文
Xiang Gao Jia-wei Xue Ying Luo Xiao-di Zhu Song Sun Jun Bao Wen-dong Wang 《化学物理学报(中文版)》2017,30(5):576-580
Novel Bi2MoO6/TiO2 heterojunction was fabricated by growing Bi2MoO6 nanosheets arrays on the vertically aligned TiO2 nanorods arrays via a two-step solvothermal method. The obtained Bi2MoO6/TiO2 hierarchical heterojunction showed excellent visible light photoelectrochemical performance. Compared with the pure TiO2 and Bi2MoO6, the photocurrent density of the heterojunction was increased 57 and 29 times, respectively. Furthermore, the hydrogen generation rate of the Bi2MoO6/TiO2 for photoelectrocatalytic water-splitting was about 6 times higher than that of the pure Bi2MoO6. The improved performance can be attributed to the synergistic effects of enhanced absorption of visible light, increase of migration rate and separation efficiency of photo-induced carriers. 相似文献
42.
Error and stability analysis of numerical solution for the time fractional nonlinear Schrödinger equation on scattered data of general‐shaped domains 下载免费PDF全文
Elyas Shivanian Ahmad Jafarabadi 《Numerical Methods for Partial Differential Equations》2017,33(4):1043-1069
In present work, a kind of spectral meshless radial point interpolation (SMRPI) technique is applied to the time fractional nonlinear Schrödinger equation in regular and irregular domains. The applied approach is based on erudite combination of meshless methods and spectral collocation techniques. The point interpolation method with the help of radial basis functions is used to construct shape functions which play as basis functions in the frame of SMRPI. It is proved the scheme is unconditionally stable with respect to the time variable in and also convergent by the order of convergence , . In the current work, the thin plate spline are used as the basis functions and to eliminate the nonlinearity, a simple predictor‐corrector (P‐C) scheme is performed. It is shown that the SMRPI solution, as a complex function, is suitable one for the time fractional nonlinear Schrödinger equation. The results of numerical experiments are compared to analytical solutions to confirm the reliable treatment of these stable solutions. © 2016 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 33: 1043–1069, 2017 相似文献
43.
Positive ground state of coupled systems of Schrödinger equations in
involving critical exponential growth 下载免费PDF全文
João Marcos do Ó José Carlos de Albuquerque 《Mathematical Methods in the Applied Sciences》2017,40(18):6864-6879
In this paper, we study the existence of a positive ground state solution to the following coupled system of nonlinear Schrödinger equations: where the nonlinearities f1(x,s) and f2(x,s) are superlinear at infinity and have exponential critical growth of the Trudinger‐Moser type. The potentials V1(x) and V2(x) are nonnegative and satisfy a condition involving the coupling term λ(x), namely, λ(x)2<δ2V1(x)V2(x) for some 0<δ<1. For this purpose, we use the minimization technique over the Nehari manifold and strong maximum principle to get a positive ground state solution. Moreover, by using a bootstrap argument and Lq‐estimates, we get regularity and asymptotic behavior. 相似文献
44.
Existence and limit behavior of prescribed L2‐norm solutions for Schrödinger‐Poisson‐Slater systems in
下载免费PDF全文
In this paper, we study constraint minimizers of the following L 2?critical minimization problem: where E (u ) is the Schrödinger‐Poisson‐Slater functional and N denotes the mass of the particles in the Schrödinger‐Poisson‐Slater system. We prove that e (N ) admits minimizers for and, however, no minimizers for N >N ?, where Q (x ) is the unique positive solution of in . Some results on the existence and nonexistence of minimizers for e (N ?) are also established. Further, when e (N ?) does not admit minimizers, the limit behavior of minimizers as N ↗N ? is also analyzed rigorously. 相似文献
45.
Ruchi Ruchi Nurhayat Ispir P. N. Agrawal 《Mathematical Methods in the Applied Sciences》2017,40(16):5687-5706
Ren and Zeng (2013) introduced a new kind of q‐Bernstein–Schurer operators and studied some approximation properties. Acu et al. (2016) defined the Durrmeyer modification of these operators and studied the rate of convergence and statistical approximation. The purpose of this paper is to introduce a Kantorovich modification of these operators by using q‐Riemann integral and investigate the rate of convergence by means of the Lipschitz class and the Peetre's K‐functional. Next, we introduce the bivariate case of q‐Bernstein–Schurer–Kantorovich operators and study the degree of approximation with the aid of the partial modulus continuity, Lipschitz space, and the Peetre's K‐functional. Finally, we define the generalized Boolean sum operators of the q‐Bernstein–Schurer–Kantorovich type and investigate the approximation of the Bögel continuous and Bögel differentiable functions by using the mixed modulus of smoothness. Furthermore, we illustrate the convergence of the operators considered in the paper for the univariate case and the associated generalized Boolean sum operators to certain functions by means of graphics using Maple algorithms. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
46.
In view of the continuously worsening environmental problems, fossil fuels will not be able to support the development of human life in the future. Hence, it is of great importance to work on the efficient utilization of cleaner energy resources. In this case, cheap, reliable, and eco-friendly grid-scale energy storage systems can play a key role in optimizing our energy usage. When compared with lithium-ion and lead-acid batteries, the excellent safety, environmental benignity, and low toxicity of aqueous Zn-based batteries make them competitive in the context of large-scale energy storage. Among the various Zn-based batteries, due to a high open-circuit voltage and excellent rate performance, Zn-Ni batteries have great potential in practical applications. Nevertheless, the intrinsic obstacles associated with the use of Zn anodes in alkaline electrolytes, such as dendrite, shape change, passivation, and corrosion, limit their commercial application. Hence, we have focused our current efforts on inhibiting the corrosion and dissolution of Zn species. Based on a previous study from our research group, the failure of the Zn-Ni battery was caused by the shape change of the Zn anode, which stemmed from the dissolution of Zn and uneven current distribution on the anode. Therefore, for the current study, we selected K3[Fe(CN)6] as an electrolyte additive that would help minimize the corrosion and dissolution of the Zn anode. In the alkaline electrolyte, [Fe(CN)6]3– was reduced to [Fe(CN)6]4– by the metallic Zn present in the Zn-Ni battery. Owing to its low solubility in the electrolyte, K4[Fe(CN)6] adhered to the active Zn anode, thereby inhibiting the aggregation and corrosion of Zn. Ultimately, the shape change of the anode was effectively eliminated, which improved the cycling life of the Zn-Ni battery by more than three times (i.e., from 124 cycles to more than 423 cycles). As for capacity retention, the Zn-Ni battery with the pristine electrolyte only exhibited 40% capacity retention after 85 cycles, while the Zn-Ni battery with the modified electrolyte (i.e., containing K3[Fe(CN)6]) showed 72% capacity retention. Moreover, unlike conventional organic additives that increase electrode polarization, the addition of K3[Fe(CN)6] not only significantly reduced the charge-transfer resistance in a simplified three-electrode system, but also improved the discharge capacity and rate performance of the Zn-Ni battery. Importantly, considering that this strategy was easy to achieve and minimized additional costs, K3[Fe(CN)6], as an electrolyte additive with almost no negative effect, has tremendous potential in commercial Zn-Ni batteries.![]()
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47.
采用熔融酯交换和缩聚两步法,合成了以1,4-丁二醇、4,8-三环[5.2.1.0(2,6)]癸烷二甲醇和碳酸二苯酯为原料的聚(碳酸丁二醇酯-co-三环癸烷二甲醇碳酸酯)(PBTCx, x为进料中TCD占二元醇总量的百分比)。用1H NMR和13C NMR对PBTCs的微观结构和组成进行了表征。采用GPC、 DSC、 XRD、 TG对PBTCs的分子量、玻璃化转变温度(Tg)、热稳定性等进行了研究。结果表明,PBTCs的Mw为10500~124800 g?mol-1, Mn为6300~73000 g?mol-1, PDI为1.59~1.73; PBTCs呈无定形态、Tg为-3.43 ℃~70.90 ℃, PBTCs表现出比PBC更高的热稳定性。薄膜拉伸试验结果表明,PBTC30(拉伸强度为33.54 MPa,断裂伸长率为275.69%)和PBTC40(拉伸强度为32.13 MPa,断裂伸长率为294.63%)具有较高的强度和韧性,在薄膜材料中具有一定的应用潜力。 相似文献
48.
Xiaotong Li Prof. Yuan Yao Chenxi Liu Xin Jia Jiahuang Jian Bao Guo Prof. Songtao Lu Prof. Wei Qin Prof. Qing Wang Prof. Xiaohong Wu 《Angewandte Chemie (International ed. in English)》2023,62(25):e202304667
Aqueous redox flow batteries (ARFBs) are a promising technology for grid-scale energy storage, however, their commercial success relies on redox-active materials (RAM) with high electron storage capacity and cost competitiveness. Herein, a redox-active material lithium ferrocyanide (Li4[Fe(CN)6]) is designed. Li+ ions not only greatly boost the solubility of [Fe(CN)6]4− to 2.32 M at room temperature due to weak intermolecular interactions, but also improves the electrochemical performance of [Fe(CN)6]4−/3−. By coupling with Zn, ZIRFBs were built, and the capacity of the batteries was as high as 61.64 Ah L−1 (pH-neutral) and 56.28 Ah L−1 (alkaline) at a [Fe(CN)6]4− concentration of 2.30 M and 2.10 M. These represent unprecedentedly high [Fe(CN)6]4− concentrations and battery energy densities reported to date. Moreover, benefiting from the low cost of Li4[Fe(CN)6], the overall chemical cost of alkaline ZIRFB is as low as $11 per kWh, which is one-twentieth that of the state-of-the-art VFB ($211.54 per kWh). This work breaks through the limitations of traditional electrolyte composition optimization and will strongly promote the development of economical [Fe(CN)6]4−/3−-based RFBs in the future. 相似文献
49.
Yandong Wu Wei Chen Yimin Jiang Yanzhi Xu Bo Zhou Leitao Xu Chao Xie Ming Yang Mengyi Qiu Dongdong Wang Qie Liu Prof. Qinghua Liu Prof. Shuangyin Wang Prof. Yuqin Zou 《Angewandte Chemie (International ed. in English)》2023,62(30):e202305491
Synthesis of cyclohexanone oxime via the cyclohexanone-hydroxylamine process is widespread in the caprolactam industry, which is an upstream industry for nylon-6 production. However, there are two shortcomings in this process, harsh reaction conditions and the potential danger posed by explosive hydroxylamine. In this study, we presented a direct electrosynthesis of cyclohexanone oxime using nitrogen oxides and cyclohexanone, which eliminated the usage of hydroxylamine and demonstrated a green production of caprolactam. With the Fe electrocatalysts, a production rate of 55.9 g h−1 gcat−1 can be achieved in a flow cell with almost 100 % yield of cyclohexanone oxime. The high efficiency was attributed to their ability of accumulating adsorbed hydroxylamine and cyclohexanone. This study provides a theoretical basis for electrocatalyst design for C−N coupling reactions and illuminates the tantalizing possibility to upgrade the caprolactam industry towards safety and sustainability. 相似文献
50.
Ying Xu Yufan Wang Fu-Sen Liang 《Angewandte Chemie (International ed. in English)》2023,62(43):e202309291
N6-methyladenosine (m6A) on RNAs plays an important role in regulating various biological processes and CRIPSR technology has been employed for programmable m6A editing. However, the bulky size of CRISPR protein and constitutively expressed CRISPR/RNA editing enzymes can interfere with the native function of target RNAs and cells. Herein, we reported a conditional m6A editing platform (FKBP*-dCas13b-ALK) based on a ligand stabilized dCas13 editor. The inducible expression of this m6A editing system was achieved by adding or removing the Shield-1 molecule. We further demonstrated that the targeted recruitment of dCas13b-m6A eraser fusion protein and site-specific m6A erasing were achieved under the control of Shield-1. Moreover, the release and degradation of dCas13b fusion protein occurred faster than the restoration of m6A on the target RNAs after Shield-1 removal, which provides an ideal opportunity to study the m6A function with minimal steric interference from bulky dCas13b fusion protein. 相似文献