Structure and analytical potential energy function for the ground state of the BCx (x=0, －1)

In this paper, the electronic states of the ground states and dissociation limits of BC and BC- are correctly determined based on group theory and atomic and molecular reaction statics. The equilibrium geometries, harmonic frequencies and dissociation energies of the ground state of BC and BC- are calculated by using density function theory and quadratic CI method including single and double substitutions. The analytical potential energy functions of these states have been fitted with Murrell-Sorbie potential energy function from our ab initio calculation results. The spectroscopic data （αe, ωe and ωeχe） of each state is calculated via the relation between analytical potential energy function and spectroscopic data. All the calculations are in good agreement with the experimental data.     

Electron Field Emission of CNx Thin Films Prepared by Low Pressure Plasma Enhanced Chemical Vapour Deposition

CNx thin films were prepared using low pressure plasma enhanced chemical vapour deposition,and then bombarded by low-energy N2^ .The compositions before and after N2^ bombardment were compared using x-ray photoelectron spectroscopy.The electron field emission characteristics of CNx thin films before and after N2^ bombardment were studied under the pressure of 10^-6pa.For the samples,the turn-on emission field decreased from 2.5V/μm to 1.2V/μm while the stable current density increased from 0.5mA/cm^2 to a value larger than 1mA/cm^2 before and after the bombardment.Our results illustrate that the field emission characteristics were improved after the bombardment of N2^ .     

可倒陀螺的机理研究与制作

研究了可倒陀螺实现可倒的机理，研制出一种可观察到具有不同“可倒角”的可倒陀螺。     

A Transient-State Simulation of Ionization Effects in a Microwave Tube

A model for studying the ionization effects in a microwave tube has been developed. This model is simulated by a two-dimensional particle-in-cell code with the Mont Carlo collision model for the electron-neutral ionization process. The transient-state process of ion noise and ion focusing effects are observed. A simple theory about ion motion is given for interpreting the phenomenon of the ion moving to the wall of the tube when the beam is not neutralized. The computed result agrees with the experiment and simulation result.     

脉冲激光沉积GaN薄膜的结构和光学特性研究

采用准分子脉冲激光,在Si(111)衬底上生长了带有AlN缓冲层的GaN薄膜, 利用X射线衍射(XRD)、原子力显微镜(AFM)和光致发光光谱(PL)等测试手段研究了不同沉积温度所生长的GaN薄膜结构特征和光学性能.研究表明:沉积温度影响GaN薄膜结构和光学性能,黄带发射峰主要与晶体缺陷有关.在400～700℃沉积范围内随着温度升高,GaN薄膜结构和光学性能提高.     

大小钢球对心碰撞实验

用两个一维单摆进行大小钢球对心完全弹性碰撞的实验,表明碰撞前后两钢球的运动状态是分立的,仅为4个点,碰撞过程是在这4个点间依次跃变的循环过程.     

厚壁压力管道侧向冲击破坏的实验研究

本文报导了三跨连续压力管道侧向受平头、半球头及锥头弹体冲击破坏的实验研究结果,管的外径为45mm,厚度为3mm,内充液体压力分别为0MPa,5MPa,10MPa,15MPa和20MPa五级,获得了不同工况下的临界破坏速度及相应的破坏模式,实验过程中测量并记录了圆管的变形、冲击力时程曲线。实验结果表明,内充介质的存在降低了临界破坏能量,同时临界破坏能量随内充介质压力的增加而减小。     

S波段径向注同轴槽振荡器（英文）

高功率微波器件在雷达、电子对抗等方面具有重要的应用潜力,因此得到广泛的关注。然而,庞大的体积和重量,以及较低的效率和较短的寿命,严重限制了高功率微波的应用范围。提出了一种径向电子注驱动的同轴槽振荡器,该振荡器无需聚焦系统,从而能够大幅度减少体积和耗能。采用由外向内的径向电子注,阴极电流密度低,可以采用热阴极替代爆炸发射阴极,从而提高器件寿命。PIC仿真中,采用460 kV,6 kA径向电子注能够在3.8 GHz产生1.2 GW的输出,对应效率43.5%。     

纳米尺度下气体薄膜润滑理论研究

提出了依赖于逆Knudsen数的纳米尺度影响因子Np，修正了目前应用较为普遍的FK-Boltzmann模型，并给出了其数值计算结果。结果表明：当膜厚小于单个空气分子平均自由程时，由于纳米尺度效应的影响，流量因子有所减小，承载能力略微增加。     

第一性原理研究O2在TiN4掺杂石墨烯上的氢化

作为一种新型高效质子交换膜燃料电池阴极材料, 金属与N共掺杂的石墨烯因其对氧还原反应具有较高的活性而引起了人们的广泛关注. 采用包含色散力校正的密度泛函理论方法系统地研究了O₂在TiN₄掺杂的Graphene上的吸附, 氢化特性. 结果表明: 1) O₂倾向于以side-on模式吸附在Ti顶位, 形成O-Ti-O三元环结构; 2) O₂在TiN₄-Graphene上更倾向于以分子形式直接氢化, 形式OOH结构, 并进一步解离为O+OH, 反应的限速步为O₂的氢化, 对应的反应势垒为0.52 eV.