Low Threshold Current Density Operation of Strain-Compensated Quantum Cascade Laser

We report the low threshold current density operation of strain-compensated In0.64 Ga0.36As/In0.3sAl0.62As quantum cascade lasers emitting near 4.94 μm. By employing an enlarged strain-compensated structure and optimizing the injector doping density, a rather low threshold current density of 0.57kA/cm^2 at 80 K is achieved/or an uncoated 20-μm-wide and 2.5-mm-long laser.     

Plastic Deformation of Fine-Grained Al-Cu-Fe-（B） Icosahedral Poly-Quasicrystals at Elevated Temperature

Fine-grained Al-Cu-Fe-（B） icosahedral poly-quasicrystals （1QCs） as the main materials and fine-grained Al- Pd-Mn IQCs as the supplements, both prepared by powder metallurgy, are uniaxially deformed at vaNous temperatures and strain rates. The systematic study shows the dependences of curves of the true stress versus true strain on several parameters, such as temperature, strain rate and grain size. For Al-Cu-Fe IQCs with grain sizes of about 10-30μm, QC-specific intra-granular softening drop appears in the deformation curves at lower temperatures and/or faster strain rates, but disappears in those curves at higher temperatures and/or slower strain rates, which suggests that the inter-granular effects such as grain-boundary sliding should be taken into account to interpret the continuous hardening, similarly to conventional poly-crystals. For Al-Cu-Fe-B IQCs with smaller grain sizes of about 1 μm and fine-grained AI-Pd-Mn IQCs with grain sizes of about 10μm, QC- specific intra-granular softening drop is absent for all the deformation curves at the possible lowest temperature and fastest strain rate. This implies that the sma/ler the grain size, the more the inter-granular contribution. At the same time, due to the rapid recovery caused by intense diffusion in small-sized grains, the intra-granular quasicrystal lattice reorders rapidly from disordering, which also inhibits the intra-granular softening drop to some extent.     

内开槽矩形波导栅慢波电路高频特性的数值分析

 介绍了用德国CST公司提供的MWS 4.2软件模拟计算色散特性和耦合阻抗的理论方法，对内开槽矩形波导栅结构的高频特性进行了数值模拟。结果表明：在传统矩形波导栅结构的基础上，开槽后的矩形波导栅结构比开槽前的相速更低，用作行波管的慢波结构时，可降低工作电压，工艺上容易实现，而且耦合阻抗均在45 W以上，满足毫米波行波管的要求；在内开槽宽度一定的前提下，槽深、栅间距和栅周期的增大对降低系统相速有利。     

Toeplitz矩阵,Hankel矩阵求逆的固有复杂度

对于一类问题P,如果能找到一个算法(对串行计算而言)其计算复杂性为f_1(u),则称f_1(n)为问题P固有复杂度的上界,若问题P的所有算法(对串行计算而言)其计算复杂性不小于f_2(n),则称f_2(u)为问题P固有复杂度下界.问题P的固有复杂度介于上     

FeN_4掺杂对富勒烯催化特性调制的第一性原理研究

因其较好的稳定性和催化活性,非金属N与金属共掺杂的富勒烯(C60)作为新型氧化还原反应(ORR)催化剂受到了人们的广泛关注.采用基于密度泛函理论的第一性原理方法系统地研究了Fe N4掺杂对C60催化特性的调制规律,揭示了O_2在Fe N4掺杂的C60上的吸附和氢化特性.结果表明:(1)O_2倾向于以side-on模式吸附在Fe的顶位上,O-O键平行于C60的球切面,与Fe形成O-Fe-O三元环结构,对应的吸附能为1.48 e V.(2)O_2的氢化反应路径可以分为两条:(i)O_2先解离为O+O,然后氢化为O+OH.O_2的解离为反应的速控步,势垒为2.82 e V.(ii)O_2先氢化形成OOH结构,然后解离.氢化为反应的速控步,势垒为2.83 e V.     

金属片镶嵌微缝薄膜结构的吸声特性分析*

为了使声波在低声压级、低频带达到理想的吸收效果,本文提出了金属片镶嵌微缝薄膜结构理论模型,并分析了该模型的吸声机理。首先将该结构的力学模型看作多自由度系统,构建振动微分方程,得到了金属片镶嵌薄膜的分布位置与每段薄膜弹性系数之间的关系。并在此基础上分析了激励频率与固有频率之间的关系,得出基频对该结构吸声效果的影响。然后利用有限元软件对该结构的模态振型和声阻抗进行了分析,得到了镶嵌在微缝薄膜上的金属片与声波的耦合形式。最后通过试验对该结构的吸声特性进行了验证,结果表明:吸收峰值受镶嵌位置影响较小,平均吸声系数变化不大,一阶固有频率会受镶嵌位置的改变而改变。     

毛细管胶束电动色谱在扁桃酸合成中的应用

扁桃酸是药物中间体,可以苯甲醛为原料在相转移催化剂作用下合成制得.为了选择最佳合成条件,提高扁桃酸的转化率,需要对合成过程中各组分的含量进行快速测定,及时指导最优合成条件的选择.产品扁桃酸中可能含有未反应的苯甲醛和副产品苯甲酸、苯甲醇等杂质.以往采用非水溶剂酸碱滴定分析法测定产品中扁桃酸的含量,但当产品中有苯甲酸等酸性物质存在时,会使测定结果偏高.由于待测样品中组分扁桃酸、苯甲酸酸性使沸点较高,     

富氧条件下甲烷还原NOxCo—ZSM—5催化剂的性能和表征

利用不同浓度和不同ＰＨ值的交换溶液，制得一系列Ｃｏ－ＺＳＭ－５催化剂，对富氧条件下催化剂甲烷选择性还原ＮＯＸ的活性进行了测定，由实验结果得知，富氧时，催化剂上氧化氮还原活性和甲烷的选择性随反应温度的变化２，分别在４４０℃和４１０℃有一极大值，应用ＩＲ、ＴＰＲ、ＸＰＳ和ＴＰＤ－ＭＳ等技术对催化剂进行了表征，观察到Ｃｏ＾２＿在ＺＳＭ－５分子筛上有两种不同落位，在Ｃｏ＾２＋离子与ＺＳＭ－５分子筛中的Ｎａ