Fe3O4@SiO2-NH2纳米粒子制备及其对Pb2+吸附性能影响

采用共沉淀法合成Fe3 O4纳米粒子,并在其表面依次包覆SiO2和γ-氨丙基三乙氧基硅烷,溶胶凝胶一步法合成氨基化磁性纳米粒子Fe3 O4@SiO2-NH2.并通过SEM、FTIR和VSM等测试方法,对该磁性纳米粒子的颗粒形貌、表面性质及磁强度进行了表征;考察了介质pH值对该磁性纳米粒子吸附Pb2+的平衡吸附容量的影响,并研究了吸附动力学、等温吸附线及吸附热力学.结果表明:Fe3 O4@SiO2-NH2粒径大小平均为80 nm,饱和磁化强度为79.52 emu/g,其对Pb2+吸附过程是吸热过程和熵增过程;吸附行为符合Lagergren准二级动力学模型,化学吸附占主导;符合Langmuir模型,是单分子层吸附.在介质pH值为6、温度为313 K时吸附效果最优,最大吸附容量可达到179.5 mg/g.     

Bidirectional highly-efficient quantum routing in a T-bulge-shaped waveguide

Quantum routing in a T-bulge-shaped waveguide system coupled with a driven cyclic three-level atom and a twolevel atom is investigated theoretically.By employing the discrete-coordinate scattering method,exact expressions of the transport coefficients along three ports of the waveguide channels are derived.Our results show that bidirectional high transfer-rate single-photon routing between two channels can be effectively implemented,with the help of the effective potential generated by two atoms and the external driving.Moreover,multiple band zero-transmission emerges in the scattering spectra,arising from the quantum interferences among photons scattered by the boundary and the bulged resonators.The proposed system may suggest an efficient duplex router with filtering functions.     

绒线团状Bi_2WO_6光催化降解亮绿SF淡黄的研究

本文以Na2WO4·2H2O和Bi(NO3)3·5H2O为原料,采用水热法合成Bi2WO6光催化剂,利用XRD、SEM对Bi2WO6光催化剂的形貌及晶型进行了表征,结果表明,180℃/6h条件下合成的Bi2WO6光催化剂的结晶度良好,具有Bi2WO6特征峰,为规则层状多孔疏松绒线团状Bi2WO6,平均晶粒尺寸为0.283nm。以亮绿SF淡黄为目标降解染料,考察绒线团状Bi2WO6光催化剂光催化性能,研究绒线团状Bi2WO6光催化剂吸附和光催化降解染料的动力学规律,并探讨绒线团状Bi2WO6光催化剂投加量、不同光源、染料溶液的初始浓度、反应时间等因素对亮绿SF淡黄吸附和光催化降解的影响。实验结果表明:在298K,pH=7,绒线团状Bi2WO6用量为2g/L,亮绿SF淡黄的初始浓度为5mg·L-1,以氙灯(300W)为光源,搅拌2h,亮绿SF淡黄降解率达90.2%。绒线团状Bi2WO6可见光降解亮绿SF淡黄符合一级反应速率动力学方程。     

谐振式光子带隙光纤陀螺一体化方案

实现了使用光子带隙光纤的一体化谐振式光纤陀螺方案,设计并制作了谐振腔中基于微光学结构的耦合器。实验测得制作的谐振腔清晰度为3.7。搭建了基于该谐振腔的陀螺系统,并对其主、次偏振态的谐振曲线进行了实际测量。实验结果测得该系统60 s零漂为2.45 ()/s,及1 h长期稳定性为7.11 ()/s。同时,实现了对应陀螺输出50 ()/s（积分时间10 s）及100 ()/s（积分时间10 s）的模拟转速实验,验证了该陀螺系统的Sagnac效应。分析得到耦合损耗是影响该陀螺系统性能的主要因素。验证了该谐振腔结构具有应用于陀螺系统的可行性,为谐振式光纤陀螺性能进一步提高提供了参考。     

谐振式光子带隙光纤陀螺一体化方案（英文）

实现了使用光子带隙光纤的一体化谐振式光纤陀螺方案,设计并制作了谐振腔中基于微光学结构的耦合器。实验测得制作的谐振腔清晰度为3.7。搭建了基于该谐振腔的陀螺系统,并对其主、次偏振态的谐振曲线进行了实际测量。实验结果测得该系统60s零漂为2.45(°)/s,及1h长期稳定性为7.11(°)/s。同时,实现了对应陀螺输出±50(°)/s(积分时间10s)及±100(°)/s(积分时间10s)的模拟转速实验,验证了该陀螺系统的Sagnac效应。分析得到耦合损耗是影响该陀螺系统性能的主要因素。验证了该谐振腔结构具有应用于陀螺系统的可行性,为谐振式光纤陀螺性能进一步提高提供了参考。     

Ni／聚氨酯纳米复合涂层的制备及其摩擦学性能研究

用超声化学方法制备了纳米Ni微粒，并在此基础上制备了Ni／聚氨酯纳米复合涂层，用X射线衍射仪和透射电子显微镜表征了纳米Ni微粒的结构和形貌以及纳米复合涂层中Ni微粒的分布；用球—盘摩擦磨损试验机评价了Ni／聚氨酯纳米复合涂层的摩擦磨损性能．结果表明：纳米Ni微粒平均品粒尺寸为10nm；纳米Ni微粒均匀分布在Ni／聚氨酯纳米复合涂层中，其颗粒尺寸约为50nm；Ni／聚氨酯纳米复合涂层的摩擦学性能明显优于聚氨酯涂层．     

多氢键反应-纳米金共振散射光谱法测定三聚氰胺

在pH 7.0的磷酸盐缓冲溶液中,氯金酸被3,5-二羟基苯甲酸(DBA)还原生成的金纳米粒子在610nm处产生一个较强的共振散射峰;当有三聚氰胺(MA)存在时,DBA与MA形成多氢键化合物而不能还原氯金酸,导致610 nm处共振散射峰的强度降低.三聚氰胺的浓度在5.0×10 -6～4.0×10-5 mol·L-1范围内...     

Hysteresis behavior and nonequilibrium phase transition in a one-dimensional evolutionary game model

We investigate a simple evolutionary game model in one dimension. It is found that the system exhibits a discontinuous phase transition from a defection state to a cooperation state when the b payoff of a defector exploiting a cooperator is small. Furthermore, if b is large enough, then the system exhibits two continuous phase transitions between two absorbing states and a coexistence state of cooperation and defection, respectively. The tri-critical point is roughly estimated. Moreover, it is found that the critical behavior of the continuous phase transition with an absorbing state is in the directed percolation universality class.     

Synchronization of Local Oscillations in a Spatial Rock-Scissors-Paper Game Model

We study a spatial rock-scissors-paper model in a square lattice and a quenched small-world network. The system exhibits a global oscillation in the quenched small-world network, but the oscillation disappears in the square lattice. We find that there is a local oscillation in the square lattice the same as in the quenched small-world 1 network. We define σ = 1/N ∑i（di-〈di〉^2 （where di is the density of a kind of species and （di） is the average value） as the variance of the oscillation amplitude in a certain local patch. It is found that σ decays in a power law with an increase of the local patch size R in the square lattice σ ∝ R^-σ, but it remains constant with an increase of the patch size in the quenched small-world network. We can speculate that in the square lattice, superposition between the local oscillations in different patches leads to global stabilization, while in the quenched small-world network, long-range interactions can synchronize the local oscillations, and their coherence results in the global oscillation.     

电力市场实用稳定性的判定条件

首次把实用稳定性的理论用于电力市场稳定性的研究中.结合Alvarado提出的电力市场动态模型,利用微分代数方程与特征值技术,从理论上研究电力市场的实用稳定性,并且给出了判断电力市场实用稳定、一致实用稳定和实用渐近稳定性的充分条件.利用这些实用稳定性条件,对于Alvarado给出的数值算例,可方便地利用初始数据判断电力市场模型的实用稳定性,并通过实例提供了假设模型中某个参数在电力市场变化中起主要作用,如何控制电力市场模型实用稳定性的方法.最后利用Maple软件包给出了参数变化引起模型实用稳定和不稳定的图形演示.