Spin-dependent transport induced by magnetization in zigzag graphene nanoribbons coupled to one-dimensional leads

We study spin transport in a zigzag graphene nanoribbon sample with two ferromagnetic strips deposited on the two sides of the ribbon.A tight-binding Hamiltonian was adopted to describe the sample connected to two onedimensional leads.Our theoretical study shows that the resonance peaks of conductance for the spin-up and spin-down electrons are separated for the parallel configuration of the ferromagnetic strips,while they are not separated for the case of antiparallel configuration.This means that giant magnetoresistance can be produced at particular energies by altering the configurations of the ferromagnetic strips,and the device can be designed as a spin filter.     

垃圾填埋渗滤液溶解性有机物组分的光谱学特性研究

选取3个不同填埋年限的渗滤液样品,以Leenheer的分组方法为基础,采用XAD-8树脂将渗滤液中的溶解性有机物(DOM)按极性和电荷特性分为结构较为均一的不同组分,用荧光光谱和紫外光谱对其中3个组分进行分析。荧光光谱分析表明,填埋初期,疏水酸性组分(HOA)、疏水中性组分(HON)和亲水性组分(HIM)均以类蛋白物质为主,随着填埋年限增加,其分子复杂化程度增强;其中HOA组分分子量最大、复杂程度最高,同时芳烃化合物的含量也最高,HON居中,HIM组分最小。紫外光谱分析表明,HOA和HON组分芳香环上的取代基均以羰基、羧基、羟基为主;而HIM组分则以脂肪链为主,同时芳香烃化合物含量较低。研究结果表明,随着填埋年限的增加,三种组分的复杂化程度均呈上升趋势。     

一类加强不等式的推广

本文给出了 n个正数 x1 ,x2 ,… ,xn 的如下不等式 :∏nk=1( xαk+x-αk )≥ ( Aαn( x) +A-αn ( x) ) n ,每个 xk≤ xα,∏nk=1( xαk+x-αk )≤ ( Aαn( x) +A-αn ( x) ) n ,每个 xk≥ e.其中 α>0 ,xα=[4α2 +1 +2 α]12α ,常数 e=2 .71 81 82 81 8… ,An( x) =1n∑nk=1xk.     

SBA－15的二氧化钛改性及其光催化降解对氯苯酚

在“后合成”法在介孔二氧化硅SBA－15的孔壁表面键接了二氧化钛,并对其 结构进行了表征。改性后的SBA－15保持了规则的介孔结构,并在孔壁表面形成了 类似于锐钛型二氧化钛的Ti-O-Ti网络结构。光催化降解对氯苯酚的结果表明,经 过两次二氧化钛键接的样品表现出较高的光催化效率。但是由于对酚、醌等中间产 物的强烈吸附以及孔道中反应物质的扩散速度慢,使得其光催化活性略低于纯的锐 钛型二氧化钛。     

具有分布时滞的双曲型微分方程边值问题解的振动性

本文研究偏微分方程……的振动性．给出了方程(1)振动的—些充分条件．     

具有分布时滞的双曲型微分方程边值问题解的振动性

本文研究偏微方程δ／δｔ（ａ（ｔ）δ／δｕ（ｘ,ｔ）＋ｍ（ｔ）δｕ（ｘ,ｔ）／δｔ＋ｃ１（ｘ,ｔ,ｕ（ｘ,ｔ）＋ｃ２（ｘ,ｔ,ｕ,ｔ－τ））＝∫＾ｔａ∑＾ｔｊ＝１（ｔ,ζ）△ｕ（ｘ,ｈｊ（ｔ,ζ）ｄσ（ζ）＋ｆ（ｘ,ｔ）的振动性,给出了方程（１）振动的一些充分条件。     

一个随机过程的小扰动的平均越出时间估计

考虑Ｒ＾ｄ（ｄ≥１）上随机过程｛Ｘ（ｔ）｝的小扰动｛Ｘ＾ε（Ｔ）｝,其中｛Ｘ（ｔ）｝和｛Ｘ＾ε（ｔ）｝分别满足随机微分方程ｄＸ（ｔ）＝ｂ（Ｘ（ｔ）,Ｚ（ｔ）ｄｔ和ｄＸ＾ε（ｔ）＝ｂ（Ｘ＾ε（Ｔ）,Ｚ（ｔ）ｄｔ＋εｄＢ（ｔ）,这里｛Ｚ（ｔ）｝是一个有限状态马氏过程,应用大偏差方法,给出了当扰动趋于零时,｛Ｘ＾ε（ｔ）｝是平均越出时间的渐近估计。     

Fabrication and Magnetic Properties of Co-Doped TiO2 Powders Studied by Nuclear Magnetic Resonance

Co0.04 Ti0.96O2 powders are fabricated by sol-gel method. The structure and magnetic properties are investigated under different annealing conditions systematically with emphasis on the influence of oxygen pressure. Pure anatase structure was acquired for all the samples annealed at 450℃ for one hour. The samples annealed in air exhibit evident room-temperature ferromagnetism (RTFM) with a small magnetic moment of 0.029μB per Co atom and coercivity Hc of 26 Oe, while the samples annealed in vacuum have strong RTFM with a larger magnetic moment of 1.18μB per Co atom and Hc of 430 Oe. The zero-field spin echo nuclear magnetic resonance spectrum of ^59Co is obtained to prove the existence of Co dusters in the latter samples, implying that the Co dusters are responsible for the strong RTFM in the samples annealed in vacuum. No Co cluster could be observed using both XPS and NMR techniques in the samples annealed in air, implying that the RTFM found in these sample sis intrinsic.     

长链单不饱和脂肪醇乙酸酯的红外和拉曼光谱研究

本文研究了鳞翅目昆虫性外激素——长链单不饱和脂肪醇乙酸脂系列化合物的红外和拉曼光谱。对主要谱带进行了归属。探讨了十一种系列化合物在室温液态和低温固态的光谱差异,得到了某些特征带与链结构的关系。结合其它物理性质,它们可用于估计同系物的双键位置和链长。     

毛细管电泳法测定四味土木香散中氧化苦参碱的含量

毛细管电泳法测定四味土木香散中氧化苦参碱的含量.苦参碱的线性范围为:25-150μg/mL相关系数为0.9998;线性方程为y=0.742268x-3.4708.RSD(n=5)为0.45%;平均回收率为99.76%.该法简便、快速、结果准确、重现性好.