耐尔蓝分光光度法间接测定铵

以耐尔蓝为显色剂，采用分光光度法进行铵的测定。选择了ＮａＯＨ碱解蒸馏分离氨的条件，探讨了表面活性剂ＯＰ，ＳＤＳ增敏增溶作用，分别测定了雨水，土壤，绿叶中铵含量，结果满意。     

稀土红色荧光粉SrZnO2∶Eu3+的发光性能

A series of novel luminescent materials, SrZnO₂∶M (M=Eu³⁺, or Eu³⁺ + Li⁺) have been synthesized by high-temperature solid-state reaction. The structure and luminescence properties of SrZnO₂∶Eu³⁺ phosphor were studied through XRD, photoluminescence and Raman spectroscopy. The excitation spectra show a broad intense band and a number of small peaks corresponding to the inner 4f-shell excitations of Eu³⁺ (the strongest one is at 395 nm for ⁷F₀-⁵L₆). After SrZnO₂∶Eu³⁺ phosphor was co-doped with Li⁺ ions, its charge transfer band extended to longer wavelengths. This resulted in increase of luminescent quantum efficiency of the sample. SrZnO₂∶Eu³⁺,Li⁺ phosphor can be efficiently excited by longer UV. From the fluorescence spectrum of SrZnO₂∶Eu³⁺ phosphor, apart from transition emissions of ⁵D₀→ ⁷F_J (J=0～4), the transition emissions from ⁵D₁ → ⁷F_J (J=0～2) have been observed. For the SrZnO₂∶Eu³⁺ phosphor, under excitation of UV, the dominant emission is at about 612 nm, due to the ⁵D₀→ ⁷F₂ hypersensitive transition. The incorporation of Li⁺ ions greatly enhanced the luminescence intensity and made emission peak from ⁵D₀ → ⁷F₂ transition red-shifted.     

计算机透析成像技术在岩土工程中的应用

系统综述了计算机透析成像技术（CT）的基本原理及其在岩土工程中的应用现状,包括CT的图像重建理论、CT图像分析的进展、岩土材料损伤的探测方法、岩土材料结构变化的动态监测、岩土材料本构模型的建立等方面。     

超临界水的分子动力学模拟

采用分子动力学(MD)模拟的方法对超临界条件下水的结构及扩散性质进行了研究.模拟结果表明超临界条件下水分子之间的氢键作用明显减弱,分子极性大大降低.扩散性质与常温下相比,其大小约上升了两个数量级.     

土的工程力学性质的颗粒流模拟

基于颗粒流理论,引入不同的颗粒接触连接本构模型,分别建立了砂土和粘性土的颗粒流模型．通过颗粒流数值模型试验,对砂土和粘性土的室内平面应变试验及其剪切带形成和发展进行了数值模拟,分别对比了不同围压下颗粒流试样与室内试验的应力应变关系曲线,基本再现了砂土和粘性土试样应力．应变关系．通过砂土和粘性土PFC试样剪切带模拟表明,当围压较小时试样内部颗粒位移量小而且分布范围较广,当围压增大时,试样内部颗粒位移量也增大,而且发生较大位移颗粒的分布范围趋于集中,同时随着围压的增大试样内部形成明显的剪切带．无论砂土还是粘性土的PFC试样,随着围压的增加剪切带的形状趋于集中,而且剪切带宽度在减小．在围压很小时,试样内形成大的破坏区域,在围压较大时出现明显的线破坏区．这些规律基本与室内试验结果相似。     

THE CRITICAL DYNAMICS OF THE KINETIC ISING MODELS ON THE SYSTEMS WITH Rmin> 2

We perform the exact TDRG transformations on the kinetic Ising model of the braced ladder whose R_min is 5. Within our knowledge, this is the only example that the exact TDRG transformations have been performed on a system with R_min >2. We show that under Achiam's linear response theory there must be important excitations of the multi-spin operators in the kinetic Ising models of the systems with R_min > 2, the dynamic critical behaviours of the systems are greatly affected by these excitations. Moreover, we get the conclusion that for the kinetic Ising models of the systems with R_min=∞ exact TDRG calculationa are impossible. The complete new and interesting results are given.     

基于Labview实现二频机抖激光陀螺角随机游走系数的计算

国军标法和Allan方差法是目前用于计算二频机抖激光陀螺角随机游走系数最常用的两种方法,基于Labview对两种方法分别编程并予以实现,计算结果表明两种方法计算出来的结果几乎相等,具有等价性;但在数据处理的过程中发现用国军标法得到的拟合系数有时为负,针对这一现象通过理论分析发现目前数据处理方法的不完善是导致国军标法拟合系数有时为负的根本原因,对现有方法提出改进并基于Labview编程实现,实验结果表明：改进后的数据处理方法不仅解决了国军标法拟合系数有时为负这一问题,而且拟合误差降低了近一个数量级。     

粉煤灰作为排水垫层筑坝的动力分析

淮南某电厂灰坝设计拟采用粉煤灰作为坝基排水垫层筑坝以节约资金。为研究其可行性,在已有的大量静力和动力特性试验研究基础上,对该灰坝在地震荷载作用下的动力反应进行研究。研究中以Biot波动方程为基础,考虑水土动力耦合作用和土体和非线性性质,引入地震孔隙水压力和残余变形项,把动力分析与动力渗流、液化发展及骨架变形加以综合考虑。研究表明,7°地震烈度条件下用本文配制的粉煤灰代替砂作为排水垫层筑坝是可行的。     

H2S/N2混合物在碳纳米管中吸附分离的分子模拟

采用巨正则Monte Carlo(GCMC)方法讨论了不同温度、压力及管径下,碳纳米管对H2S/N2混合物(主体相体积比为1∶99)的吸附分离选择性.结果表明,随着碳纳米管管径的增大,H2S的吸附选择性先增加后减小;而(11,0)碳纳米管(管径为0.86 nm)对H2S的选择性最高,这种选择性与管径的关系是由几何效应和能量效应共同决定的.针对(11,0)碳纳米管讨论了温度和压力对H2S吸附量和选择性的影响.模拟结果表明,随着温度上升,H2S的吸附量和选择性都呈先增加后减小的趋势;随着压力增加,H2S的吸附量和选择性都有所下降.本文模拟结果可为含硫气体混合物的吸附分离提供一定参考.     

Four-State Modulation in Middle of a Quantum Channel for Continuous-Variable Quantum Key Distribution Protocol with Noiseless Linear Amplifier

We characterize a modified continuous-variable quantum key distribution(CV-QKD)protocol with four states in the middle of a quantum channel.In this protocol,two noiseless linear amplifiers(NLAs) are inserted before each detector of the two parts,Alice and Bob,with the purpose of increasing the secret key rate and the maximum transmission distance.We present the performance anal.ysis of the new four-state CV-QKD protocol over a Gaussian lossy and noisy channel.The simulation results show that the NLAs with a reasonable gain g can effectively enhance the secret key rate as well as the maximum transmission distance,which is generally satisfied in practice.