离子-电子非平衡机制降低中心热斑点火条件

提出通过离子-电子非平衡物理模型来降低惯性约束聚变中心热斑点火的聚变点火条件。在该物理模型中,强调离子比电子具备更高的温度,从而使得热斑的热核聚变反应增强,轫致辐射和电子热传导造成的能量漏失相对降低。通过对中心热斑的自加热分析和热斑燃烧动力学分析,发现相对于平衡聚变点火模型,非平衡模型可以显著扩大聚变点火区在热斑面密度和热斑温度空间的范围。同时采用LARED-S程序的数值模拟,研究了通过尖峰脉冲波形、二次冲击物理机制强化中心热斑聚变点火的非平衡性。     

CuCl2-KCl-LaCl3/γ-Al2O3对乙烷氧氯化反应的催化性能

 以γ-Al2O3为载体,采用常规浸渍法制备了负载型CuCl2-KCl-LaCl3三组分催化剂,并研究了其对乙烷氧氯化反应的催化性能. 结果表明,该催化体系中乙烷的转化率较稳定,但随着反应时间的延长,氯乙烯的选择性和收率明显下降. XRD,N2吸附,TGA/DTA和XPS测试结果表明,随着反应的进行,催化剂中的活性物种Cu2+逐渐被还原成Cu+,并且积炭的产生使催化剂的比表面积和孔容积减小. 活性物种Cu2+的减少及比表面积的降低是催化剂失活的主要原因.     

航天探测器CO2两相主动热控系统试验及分析

本文设计了一种以机械泵驱动的CO2两相散热系统,用于高热流密度航天探测器的高精度温度控制.分别对其稳态特性包括散热热流密度、流动阻力特性和动态性能包括启动特性、控温特性试验研究发现:机械泵CO2两相控温系统控温精度不低于1.5℃,启动性能和控温实时性能良好.     

翠绿亚胺聚合物高压下芳环扭角和能隙的缩减

利用改进的Ginder-Epstein模型计算了翠绿亚胺聚合物在参数V4,0取值于1.8～35.8 eV的自洽变分基态,并通过芳环扭角的变化来估算聚合物压强,给出了V4,0,芳环扭角及能隙与理论压强之间的最小二乘拟合.结果表明随此参数的增大,芳环扭角和能隙都缩减而理论压强升高.当理论压强由零压增至3.0 GPa左右时,能隙先快后慢从2.0 eV减小至最小值0.87 eV.这理论与该聚合物的高压电导测试结果一致.     

Graphene oxide for diode-pumped Tm:YLF passively Q-switched laser at 2 μm

A diode-pumped Tm:YLF passively Q-switched laser at 2 μm was first demonstrated by using graphene oxide(GO) as a saturable absorber(SA).In this letter,continuous-wave(CW) laser and pulse laser performances were studied meticulously and systematically.It reasonably showed the dependence of the pulse duration,pulse energy,and pulse repetition rate on the absorbed power.A maximum repetition rate of 38.33 kHz and a single pulse energy of 9.89 μJ were obtained.     

等离子体浸没注入超低能注入掺杂研究

A plasma immersion ion implantation(PIII) system based on inductively coupled plasma(ICP) technology was designed. The PIII system had a cylindrical chamber, and a radio frequency(RF) power was used to sustain discharge and a pulsed voltage source was provided to bias the wafer. The RF power was coupled into chamber by a non-coplanar two-turn circular structure coil. A Langmuir probe was connected to the PIII system to diagnose the plasma parameters. The probe diagnosis indicated that plasma ion density of the system achieves 10¹⁷m^-3, the uniformity of the ion density along radial direction achieves 3.53%. Boron (B) and phosphorus (P) doping experiments were performed on the system. Results from second ion mass spectrum (SIMS) tests showed that the measured injection depth is about 10nm and the shallowest is 8.6 nm (at 10¹⁸cm^-3), the peak ion concentration is below the surface of the wafer, and the ion dose reaches above10¹⁵cm^-2 and the abrupt 2.5 nm/decade.     

Highly efficient polymer phosphorescent light-emitting devices based on a new polyfluorene derivative as host

Several highly efficient iridium-complex polymer light-emitting devices (PLEDs) are fabricated,with a newly synthesized blue conjugated polymer,poly[(9,9-bis(4-(2-ethylhexyloxy)phenyl)-fluorene)-co-(3,7-dibenziothiene-S,S-dioxide15)] (PPF-3,7SO15),chosen as host.High luminous efficiencies of 7.4 cd·A 1 and 27.4 cd·A 1 are achieved in red and green PLEDs,respectively,by optimizing the doping concentrations of red phosphorescent dye iridium bis(1-phenylisoquinoline) (acetylacetonate) (Ir(piq)) and green phosphorescent dye iridium tris(2-(4-tolyl)pyridinato-N,C 2) (Ir(mppy) 3).Furthermore,highly efficient white PLEDs (WPLEDs) with the Commission Internationale de l’Eclairage (CIE) coordinates of (0.35,0.38) are successfully produced by carefully controlling the doping concentration of the irid-ium complex.The obtained WPLEDs show maximal efficiencies of 14.4 cd·A 1 and 10.1 lm·W 1,which are comparable to those of incandescent bulbs.Moreover,the electroluminescent spectrum of the white device with an initial luminance of about 1000 cd·m 2 is stable,subject to constant applied current stress,indicating that good device stability can be obtained in this system.     

强上转换发光的LiLu_(1-x)Yb_xF_4∶Tm@LiGdF_4核壳纳米晶的制备

利用高温热分解法制备了LiLuF_4∶Yb,Tm@LiGdF_4核壳纳米晶。在980nm激光激发下,与未包覆的样品相比,LiLuF_4∶Yb,Tm@LiGdF_4核壳纳米晶的发光增强了15倍左右,这主要是因为通过惰性壳层的包覆可以有效抑制表面猝灭效应。另外,随着核中Yb~(3+)离子的摩尔分数从20%增加到100%,上转换发光强度逐渐增大,最大增加了12.4倍左右。这主要是由于增加Yb~(3+)离子的浓度可以增加纳米粒子对激发光的吸收和提高Yb~(3+)到Tm~(3+)的能量传递速率。所制备的LiYbF_4∶2%Tm@LiGdF_4核壳纳米晶的发光效率高达4%。     

超热电子在稠密等离子体中输运的混合粒子模拟方法

相对论激光等离子体相互作用以及所产生的带电粒子束在高密度等离子体中的输运行为非常重要.该物理问题的数值模拟研究仍面临技术挑战.本文介绍一种粒子/流体混合模拟方法.该方法中超热电子采用动力学方法描述,背景冷的稠密等离子体采用简化的流体方程描述,适合于超热电子密度远小于背景电子密度,超热电子能量远大于背景电子温度.我们的三维并行混合模拟程序HEETS的模拟结果表明：背景材料的电离和电阻率模型至关重要,将严重影响高能电子输运过程的模拟.     

Tunable Nd,La:SrF_2 laser and passively Q-switched operation based on gold nanobipyramids saturable absorber

A novel Nd, La:SrF_2 disordered crystal is prepared, and its continuous-wave wavelength tuning operation is performed for the first time. Employing a surface plasmon resonance(SPR) based gold nanobipyramids(G-NBPs) saturable absorber,we obtain a compact diode-pumped passively Q-switched Nd, La:SrF_2 laser. The stable Q-switched pulse operates with the shortest pulse duration of 1.15 μs and the maximum repetition rate of 41 k Hz. The corresponding single pulse energy is 2.24 μJ. The results indicate that G-NBPs could be a promising saturable absorber applied to the diode-pumped solid state lasers(DPSSLs).