Simple corona -algebras

Let be a non-unital and -unital simple -algebra. We show that if is simple, then is purely infinite. We also show that is simple if and only if has a continuous scale provided that is not isomorphic to the compact operators.

     

极低反射率光控高温超导开关的研究

提出了一种能够实现极低反射率的光控高温超导开关的新结构-微带直线结构,并提出实现此结构的新方法-辐照均匀法。理论分析、仿真数据和可行性验证实验都表明,光控高温超导开关采用辐照均匀法和微带直线结构,可以有效地扩大超导开关光辐照通断点的受辐射面积;因光束光强分布更加均匀,使通断控制性能更高;微带直线结构使得特性阻抗变化完全消失,具有极低的反射率;利用光学元件能够有效控制激光光束直径的特点,使微带线宽指标设计更加灵活,光控超导开关的适应面更广。     

Lifting Automorphisms

Let A be a unital nuclear separable C*-algebra which satisfies the Universal Coefficient Theorem and E be a unital essential extension of the form:

Pd(Hmp)2(PBn3)2的合成、晶体结构及其二聚机理

膦巯混合配位钯化合物Pd（Hmp）_2（（PBu_3~n）_2）（1）含有四方平面构型的二价钯，PdS和Pd-P的键长分别为2．338（1）和2．336（1），在过量的邻巯基苯酚存在下生成．如果是膦过量，则生成以核配合物Pd_2（Hmp）（PBu_3~n）_2Cl_2[1]．文中讨论了（1）和（2）的生成机理和Pd（Hmp）_2（PM_（e3））_2的量化计算结果．     

锰基催化剂催化燃烧VOCs

锰基催化剂作为一种催化活性高、稳定性强、价格低廉的非贵金属类材料,在催化燃烧VOCs领域显示出了广阔的应用前景。然而,该材料存在表面电子传递能力弱,比表面积低等缺点须通过掺杂改性等方式得到优化。本文分别对单一锰氧化物、贵金属掺杂、负载以及钙钛矿型的锰基催化剂近年来从制备方法、催化剂的化学组分、形貌结构等方面提高催化剂活性的最新研究进展进行综述,并对锰基催化剂整体化、工业化的发展提出展望。     

An approximate universal coefficient theorem

An approximate Universal Coefficient Theorem (AUCT) for certain -algebras is established. We present a proof that Kirchberg-Phillips's classification theorem for separable nuclear purely infinite simple -algebras is valid for -algebras satisfying the AUCT instead of the UCT. It is proved that two versions of AUCT are in fact the same. We also show that -algebras that are locally approximated by -algebras satisfying the AUCT satisfy the AUCT. As an application, we prove that certain simple -algebras which are locally type I are in fact isomorphic to simple AH-algebras. As another application, we show that a sequence of residually finite-dimensional -algebras which are asymptotically nuclear and which asymptotically satisfies the AUCT can be embedded into the same simple AF-algebra.

     

Reaction of sulfur-containing structural units of transition metals

Two tri-n-butylphosphme-participated ( PBu3n) nickel (Ⅱ) complexes of 2-mercaptophenol(H2mp),i.e,Ni2Ru(mp)3(Hmp)(PBu3n)3 3 exhibiting a curved heterotrinuclear metal skeleton and its mononuclear "synthon",[HNEt3] [Ni(mp) (Hmp) (PBu3n)] 1 were synthesized and characterized by X-crystallography and 1H NMR,FAB-MS and cyclic valtammogram measurements.The nickel(Ⅱ) center in 1 has a square-planar geometry For 3,the ruthenium(Ⅲ) atom is in a distorted octahedral environment and the two mckel(Ⅱ) atoms exhibit square-planar and rare triangle-planar geometries,respectively.The Ni (1)-Ru-Ni(2 ) arrangement is severely asymmetric with the distances 0.254 and 0.394 nm,respectively,for Ni(1)-Ru and Ni(2)-Ru.The structural regularities of relevant complexes are summarized in relation to the structural as well as spectra data.     

双齿膦参与的非均三脚架配位银化合物的合成、结构与表征

近年来,由于在发光材料及一些生物酶的模拟方面有着重要的价值,研究三脚 架有机配体与金属离子自组装形成的配合物引起了人们的极大兴趣。有许多稀土及 银的配合物被报道。从结构的角度来看,非均三脚架配体的三个支架可以有不同类 型的翻转,加上所其带基团的多样性,使其可具有较均三脚架配体更丰富多变的配 位方式,为具有新颖结构的功能材料的设计提供了新思路。     

1,2-苯基异噁唑为氮源的铜催化苯乙烯不对称硼胺化

报道了一种以手性亚砜膦配体/铜络合物为催化剂的苯乙烯不对称硼胺化反应.该方法以联硼酸频哪醇酯（B₂pin₂）为硼源,以商业可得的1,2-苯基异噁唑为亲电氮源,合成了一类β-氨基硼酸酯类化合物,目标产物可以方便地转化为β-硼酯伯胺化合物,为结构多样的手性氨基化合物合成提供了一条技术途径.     

Type I -algebras of real rank zero

We show that a separable -algebra of type I has real rank zero if and only if where is a modified dimension. We also show that a separable -algebra of type I has real rank zero if and only if it is an AF-algebra.