磁性离子交换树脂连续化运行条件的研究

本文针对现行离子交换操作过程和离子交换树脂的不足,研制出一种新磁性离子交换树脂,并对其应用于连续化子离子交换过程的运行条件进行了较详细的研究,结果表明,磁性离子交换树脂应用于连续化操作过程,可增大操作流速或提高工作效率。     

Imine Reduction with Me2S-BH3

Although there exists a variety of different catalysts for hydroboration of organic substrates such as aldehydes, ketones, imines, nitriles etc., recent evidence suggests that tetra-coordinate borohydride species, formed by activation, redistribution, or decomposition of boron reagents, are the true hydride donors. We then proposed that Me₂S-BH₃ could also act as a hydride donor for the reduction of various imines, as similar compounds have been observed to reduce carbonyl substrates. This boron reagent was shown to be an effective and chemoselective hydroboration reagent for a wide variety of imines.     

基于电磁仿真的粗糙面上二维目标参数反演

针对海洋(或陆地)环境中目标电磁逆散射问题开展研究,建立了粗糙面上简单导体目标的电磁散射模型,通过精确的电磁散射建模得到散射回波数据,包括空间分布采样和频率采样,再分别应用BP神经网络(BPNN)和支持向量机(SVM)两种方法反演粗糙面上二维导体目标的特征几何尺寸.在粗糙面上圆柱几何参数反演以及海上舰船尺寸反演过程中需要考虑粗糙面的随机性,因此对散射数据进行了多次统计,实现了随机粗糙面上方目标的特征参数重构.     

Tb~(3+)在YAG中的发光及Tb~(3+)与Tm~(3 +)间的能量传递

采用溶胶 -凝胶方法合成了系列化合物 (Y1 -x- yTbxTmy) 3Al5O1 2 ,研究了Tb3+在该化合物中的发光及其浓度对发光性质的影响 ,以及Tb3+与Tm3+间的能量传递现象。     

高纯金属的快速分析-强激光溅射电离飞行时间质谱法

随着现代材料行业的发展,高纯金属纯度分析日趋重要。本研究建立了一种基于强激光溅射电离飞行时间质谱（LAI-TOFMS）检测高纯金属纯度新方法。为消除高价离子和多原子离子等干扰峰的影响,在离子源内引入了氦气。通过分析高纯阴极铜的系列标准样品,建立了其中16种痕量元素的固体直接定量分析方法,在4个动态范围内（10-7 – 10-3 μg/g）的线性相关度优于0.97,检出限低至0.1 μg/g。该方法几乎无需样品处理、分析时间短、操作简便、灵敏度高、谱峰干扰小,可用于高纯金属材料纯度及其痕量杂质的快速分析。     

SmP5O14晶体中的辐射跃迁

本文根据Judd-0felt理论,计算了SmP₅O₁₄晶体中Sm³⁺离子的振子强度和参数Ω_λ实验值和计算值符合较好。同时计算了⁴G₅/2→⁶H_J跃迁的约化矩阵元和辐射跃迁几率。     

Abnormal dynamics in cascading model with gravitational effect

Nonlinear Dynamics - In actual networks, the distance between nodes has an effect on load flow. Nodes closer to a node are more attractive, as if there is some kind of gravity between the nodes....     

A New Isomer and Other Metabolites Isolated from Alternaria alternata

Chemistry of Natural Compounds - The marine derived fungus Alternaria alternata (Fr.) Keissl. was isolated from branch samples of Beibu Gulf, Qinzhou, Guangxi, China and identified by 16s rDNA....     

Packing and properties of composite phase change energy storage materials based on SiC nanowires and Na2SO4·10H2O

Journal of Thermal Analysis and Calorimetry - SiC nanowires were prepared by sol–gel sintering at high temperature, then shaped and encapsulated Na2SO4·10H2O-based composite phase change...