大科学装置同步辐射光源在生命分析化学中的应用

大科学装置的建设和水平是一个国家科技发展程度的标志. 同步辐射装置是一种先进的多学科交叉的高端大科学研究设施, 作为独特的宽光谱高亮度光源, 同步辐射光源提供了其他光源所无法比拟的优势. 我国迄今已建成的最大的大科学装置—— 上海光源的建立和应用是新中国成立60年来的重大成就之一, 标志着我国在建设国际先进水平的大型科学实验装置方面具备了高水平的技术和集成与创新的能力, 已进入国际先进行列. 本文侧重介绍同步辐射光源在生命分析化学领域中的巨大作用, 并以上海光源为例介绍同步辐射光源装置的发展和应用状况, 旨在唤起和推动我国分析化学家的高度重视, 并充分利用我国这一先进的大型科学装置, 将生命分析化学的研究推进到一个崭新的、更高的层次.     

A gate enhanced power U-shaped MOSFET integrated with a Schottky rectifier

An accumulation gate enhanced power U-shaped metal-oxide-semiconductor field-effect-transistor(UMOSFET) integrated with a Schottky rectifier is proposed.In this device,a Schottky rectifier is integrated into each cell of the accumulation gate enhanced power UMOSFET.Specific on-resistances of 7.7 m.mm 2 and 6.5 m.mm 2 for the gate bias voltages of 5 V and 10 V are achieved,respectively,and the breakdown voltage is 61 V.The numerical simulation shows a 25% reduction in the reverse recovery time and about three orders of magnitude reduction in the leakage current as compared with the accumulation gate enhanced power UMOSFET.     

Effects of swift argon-ion irradiation on the proton-exchanged LiNbO₃ crystal

A proton-exchanged LiNbO3 crystal was subjected to 70-MeV argon-ion irradiation.The lattice damage was investigated by the Rutherford backscattering and channeling technique.It was found that the lattice disorder induced by the proton exchange process was partially recovered and the proton-exchanged layer was broadened.It indicated that the lithium ions underneath the initial proton-exchanged layer migrated to the surface during the swift argon-ion irradiation and supplemented the lack of lithium ions in the initial proton-exchanged layer.This effect was ascribed to the great electronic energy deposition and relaxation.The swift argon-ion irradiation induced an increase in extraordinary refractive index and formed another waveguide structure beneath the proton-exchanged waveguide.     

气相色谱法测定柑橘与土壤中氟啶虫胺腈的残留量

建立了柑橘和土壤中氟啶虫胺腈残留量的气相色谱测定方法.柑橘全果、果肉和土壤样品中的氟啶虫胺腈用乙腈提取,果皮样品用乙腈-水(4:1,V/V)混合溶剂提取,经中性氧化铝柱净化,浓缩后采用气相色谱-电子捕获检测器(GC-ECD)检测,结果表明,在添加浓度为0.05-1.0mg/kg时,氟啶虫胺腈在样品中的平均回收率为81.3％-101.2％,相对标准偏差为0.9％-4.9％.方法的检出限(LOD)为5.0× 10-11g,氟啶虫胺腈在全果、果肉、果皮和土壤中的最低检测浓度(LOQ)为0.05mg/kg.该方法杂质干扰少,准确性及灵敏度满足农药残留检测的基本要求,对检测硬件要求低,适用于柑橘和土壤中氟啶虫胺腈残留的分析.     

用羊八井ASγ实验数据寻找TeV能区的γ射线暴

γ射线暴的TeV能区辐射对研究其起源、辐射机制等是非常重要的.利用西藏羊八井ASγ实验三期阵列的重建数据,通过在给定的小天区和时间间隔内寻找较高显著性事例团的方法对TeV能区的γ射线暴进行了寻找,在计算过程中采用“等天顶角法”来估计背景.工作中采用了两种途径来寻找γ射线暴,一种是与卫星γ射线暴的符合寻找,另一种是全天区独立寻找.结果发现少量事例团对背景有明显超出,考虑试验次数后,其超出还不足以认定为γ射线暴.通过Monte Carlo模拟,给出了在95%置信水平下,到达大气顶部流强上限的估计值为3.32×10^-9—1.24×10^-7 cm^-2s^-1. 关键词： γ射线暴 TeV能区 ASγ实验 宇宙射线     

利用羊八井广延大气簇射阵列探测来自壳型超新星遗迹G40.5-0.5的TeV Gamma射线发射

利用羊八井广延大气簇射阵列从2000年10月到2001年9月的数据,对壳型超新星 遗迹G40.5-0.5可能的TeV gamma射线发射进行了探测. 用对扩展源的二维分析方法发现一个最高超出为4.4σ的天区,EGRET不明源GeV J1907+0557非常接近 这一最高超出天区的中心.     

钙钛矿型催化活性材料结构与性能的研究——La_(k—x)Sr_xCo_(0.75)Me_(0.25)O_(3—δ)体系

用多晶X射线衍射法研究了ABO_3型的[(La_(1-y)Sr_y)_(1-z)□_z][Co_(0.75)Me_(0.25)][○_(3-δ)□_δ]系列化合物的结构和晶格畸变。结构中A位为La~(3+)、Sr~(2+)和约14％的空位随机占有。不同价态的Co离子和Me~(4+)无序地分布于B位。○位为O~(2-)和空位随机占有。A位Sr~(2+)取代La~(3+)量增加,正二价的Co逐渐变为正三价,最后出现正四价。平均晶格畸率<ε_(110)~2>~(1/2),及对CO完全氧化反应的活性迅速增大。因此平均晶格畸变率<ε_(110)~2>~(1/2)可表征钙钛矿相A位的调变作用和与之相关的催化性能。     

ARGO实验探测γ暴的灵敏度研究

西藏羊八井ARGO实验是对广延大气簇射事例进行观测研究的"全覆盖式"地面宇宙线观测实验, 其主要目的之一就是探测E>10GeV的γ暴. 通过Monte Carlo模拟, 估算了ARGO实验探测10GeV γ暴所具有的灵敏度.     

Effects of swift argon-ion irradiation on the proton-exchanged LiNbO3 crystal

A proton-exchanged LiNbO3 crystal was subjected to 70-MeV argon-ion irradiation.The lattice damage was investigated by the Rutherford backscattering and channeling technique.It was found that the lattice disorder induced by the proton exchange process was partially recovered and the proton-exchanged layer was broadened.It indicated that the lithium ions underneath the initial proton-exchanged layer migrated to the surface during the swift argon-ion irradiation and supplemented the lack of lithium ions in the initial proton-exchanged layer.This effect was ascribed to the great electronic energy deposition and relaxation.The swift argon-ion irradiation induced an increase in extraordinary refractive index and formed another waveguide structure beneath the proton-exchanged waveguide.