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The outstanding hard-magnetic properties are reported of Sm_3Fe_{28.1-x}Co_xMo_{0.9} compounds with x=12, 14, 16. In this alloy system, only a small amount of Mo is needed to stabilize the 3:29 structure so that the magnetic properties are not seriously affected by the presence of this nonmagnetic element. Substitution of Co for Fe leads to a significant increase of the magnetic anisotropy, and for x≥14 the easy magnetization direction changes from easy plane to the easy axis. In this alloy system, the compound Sm_3Fe_{12.1}Co_{16}Mo_{0.9} is a very promising candidate for permanent magnet applications. Its room temperature saturation magnetization (μ_0M_s=1.5 T) and anisotropy field (B_{an}=6.5 T) are comparable to the values for Nd_2Fe_{14}B (μ_0M_s=1.6 T and B_{an}=7 T). However, the Curie temperature of Sm_3Fe_{12.1}Co_{16}Mo_{0.9} is 1020 K, which is appreciably higher than that for Nd_2Fe_{14}B (T_C=588 K). 相似文献
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对R404A/R23/R14三级复叠制冷系统进行模拟,研究了三级复叠制冷循环中间温度的选取对系统制冷系数的影响,比较了R404A/R23/R14与R404A/R23在重叠温区的制冷系数以及不同制冷剂对三级复叠系统制冷系数的影响。结果表明:R404A/R23/R14复叠式制冷循环存在最佳中间温度,最佳温度下的压缩机压比大致相等;在重叠温区内,R404A/R23的制冷系数高于R404A/R23/R14;R404A/R508B/R14、R404A/R508A/R14更适用于做三级复叠制冷系统的制冷剂。 相似文献
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利用Chen-Mbius晶格反演获得的原子间相互作用势,对NaZn13型Fe基金属间化合物进行原子级模拟研究.计算结果表明,Si原子和Co原子均优先占据96i晶位,Si原子和Co原子替代Fe原子后晶体平均结合能降低.随着Co含量的增加,LaFe13-x-yCoySix和NdFe13-x-yCoySix的晶格参数逐渐降低.声子态密度中,稀土原子主要激发低频模,Si原子主要激发高频模.LaFe11.5-yCoySi1.5化合物的德拜温度随Co含量的增加而增高.
关键词:
晶格反演
原子间相互作用势
热力学性质
磁致冷材料 相似文献
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冷藏运输车内气体流场的数值模拟及分析 总被引:2,自引:0,他引:2
利用计算流体力学(ANSYS)软件,建立了冷藏运输模拟试验台的物理模型,对冷藏运输车内流场进行了数值模拟研究。主要研究内容包括:(1)不同送风速度对冷藏运输车内流场分布的影响;(2)不同时间内库内流场变化情况。冷藏运输模拟试验台采用前端送风,两侧回风口的送风方式。风机吹出的冷气能够在库体内形成大的回流,从而降低库体温度并且使库体内温度分布的均匀。不同送风速度影响车体内速度场的分布,而当送风速度较大时,库内的温度会在短期内均匀。但是过大的送风速度会风干冷藏车内的食品。 相似文献
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建立了NH_3/CO_2和R507/CO_2复叠式制冷系统热力学模型,并改变冷凝蒸发器换热温差、低温级蒸发温度和高温级冷凝温度来研究两种系统的性能。结果表明,冷凝蒸发器换热温差对R507/CO_2复叠式制冷系统效率影响更大,相同工况下,R507/CO_2复叠式制冷系统的COP略低于NH_3/CO_2复叠式制冷系统,但R507/CO_2复叠式制冷系统随低温级蒸发温度升高的增长速率较大,随高温级冷凝温度增长而降低的速率较小,且R507制冷剂比NH_3制冷剂更加安全,可以通过降低冷凝蒸发器换热温差,提高低温级蒸发温度,降低高温级冷凝温度的方法来提高复叠式制冷系统COP。 相似文献
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Construction of embedded-atom-method interatomic potentials for alkaline metals (Li,Na,and K) by lattice inversion 下载免费PDF全文
The lattice-inversion embedded-atom-method interatomic potential developed previously by us is extended to alkaline metals including Li,Na,and K.It is found that considering interatomic interactions between neighboring atoms of an appropriate distance is a matter of great significance in constructing accurate embedded-atom-method interatomic potentials,especially for the prediction of surface energy.The lattice-inversion embedded-atom-method interatomic potentials for Li,Na,and K are successfully constructed by taking the fourth-neighbor atoms into consideration.These angular-independent potentials markedly promote the accuracy of predicted surface energies,which agree well with experimental results.In addition,the predicted structural stability,elastic constants,formation and migration energies of vacancy,and activation energy of vacancy diffusion are in good agreement with available experimental data and first-principles calculations,and the equilibrium condition is satisfied. 相似文献
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利用低温风洞实验室研究了过冷度、过热度、蒸发温度、迎面风速对冷库蒸发器性能的影响。结果表明:当环境温度为0℃和-18℃时,过冷度从1℃增加到6℃,制冷量近乎呈线性增长,平均每过冷1℃制冷量分别增加了2.63%、2.72%;过热度从0℃增加到5℃,制冷量随过热度的增大而逐渐减小,平均每过热1℃制冷量分别减小了0.99%、0.38%;迎面风速从3.8 m/s增加到5.8 m/s,制冷量随迎面风速的增大而逐渐增大,平均每增加0.5 m/s的风速制冷量分别增大了1.01%、0.57%。蒸发温度从-29℃增加到-25℃,制冷量近乎呈线性增长,平均每增加1℃蒸发温度制冷量增加了4.6%。 相似文献
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Systematic approaches are presented to extract the interfacial potentials from the ab initio adhesive energy of the interface system by using the Chen–M ¨obius inversion method. We focus on the interface structure of the metal(111)/Zn O(0001)in this work. The interfacial potentials of Ag–Zn and Ag–O are obtained. These potentials can be used to solve some problems about Ag/Zn O interfacial structure. Three metastable interfacial structures are investigated in order to check these potentials. Using the interfacial potentials we study the procedure of interface fracture in the Ag/Zn O(0001) interface and discuss the change of the energy, stress, and atomic structures in tensile process. The result indicates that the exact misfit dislocation reduces the total energy and softens the fracture process. Meanwhile, the formation and mobility of the vacancy near the interface are observed. 相似文献