利用偏振全息记录可重复擦写的偶氮相位光栅

利用偏振全息技术在偶氮苯侧链聚合物薄膜上进行了记录全息相位光栅的研究.从理论和实验两方面分析了不同的偏振全息模式、偶氮高分子聚合物材料和全息曝光时间对相位光栅生成的影响.通过实验比较,确定了最佳的实验条件,在形成折射率相位光栅的同时,最大限度的避免了由于大分子运动而导致的表面起伏对相位光栅的破坏,并在此基础上,记录了可重复擦写的全息相位光栅.这种全息光栅制作比较方便,光栅系数可以方便的调整,在室温下非常稳定并且能用圆偏振光完全擦除后重复写入.     

聚合物光纤放大器

聚合物光纤是一种新型的信号传输介质。本文综述了聚合物光纤放大器的研究现状，着重对有机染料和稀土掺杂的聚合物光纤的特性进行了深入的讨论。     

Polarized Emission of an Eu^3＋ Doped Azo-Polymer Waveguide

We investigate the polarized emission behaviour of an Eu^3 doped azo-polymer waveguide. Affected by the azobenzene groups in the photoinduced orientation process by the 532nm linearly polarized laser, the ligands were realigned orderly perpendicular to the direction of the orientation direction. This leads to the polarized absorption and emission of the waveguide in the orientation direction. By an m-line apparatus based on the prism coupling technique, two guided propagation modes were observed in the waveguide, and the refractive index at 650hm in TE polarizations is 1. 7505.     

Fluorescence Enhancement of a Polymer Planar Waveguide Doped with Rhodamine B and Ag Nanoparticles

Planar polymer multi-model waveguides doped with Ag nano-particles and rhodamine B are fabricated and investigated by the spectroscopy analysis method as well as the M-line method. Experimental results shown that fluorescence enhancement occurs when excited by a wide band wavelength with Ag nano-particle concentration at a certain level. The maximum enhancement factor in our experiment is obtained to be about 3.8 when excited by 350 nm. Our study may have potential applications in polymers optical elements, such as polymer waveguide lasers and amplifiers.     

Enhanced Three-Photon Absorption by Symmetric Twisted Intramolecular Charge Transfer

We report on a novel organic chromophore with symmetric twisted intramolecular charge transfer (TICT) state on excitation. The properties of nonlinear transmission induced by three-photon absorption (3 PA) are demonstrated pumped with nanosecond laser pulse. Large 3PA cross sections as high as the order of 10^-74 cm^6s^2 have been obtained for nanosecond and picosecond laser pulses at 1064 nm from intensity-dependent transmission measurements. Similar two emissive behaviours from one-photon and three-photon excited fluorescence spectra indicate that the linear and nonlinear fluorescences share the same TICT relaxation process from the excited states. The intensity dependence of upconversion fluorescence on the incident intensity obeys the cubic law that characterizes the three-photon absorption.     

Eu3+掺杂的PMMA-络合物体系的发光特性

研究了聚甲基丙烯酸甲脂PMMA-Eu(DBM)3(phen)和PMMA-辛酸铕体系的发光特性。已有的结果表明，聚甲基丙烯酸甲脂PMMA—Eu(DBM)3(phen)体系具有较高的色纯度，Eu^3 的主发射峰几乎只有613nm(Eu^3 的^5D0→^7F2)被观测到，其发射强度比PMMA-辛酸盐体系的高一个量级，是潜在的高效稀土红光材料。     

Rhodamine 6G-doped polymer optical fiber amplifiers

Rhodamine 6G-doped step-index polymer optical fiber is fabricated.The characteristics of the am-plification of rhodamine 6G-doped step-index polymer optical fiber amplifier have been studied.Thehigh-gain optical amplification with a tunable wavelength range from 585 to 613 nm is obtained in a step-index polymer optical fiber doped with rhodamine 6G at 10-ppm level,which can be used for broadband amplifiers and tunable lasers.     

烯类单体自由基聚合的二个计算机模拟练习

本文介绍了一个高分子化学计算机辅助教学（ＣＡＩ）软件，该软件针对自由基聚合动力学和自由基共聚合的教学重点设计了相应的模拟软件。通过该软件可以让使用者深化对基本概念的理解，并对动手实验有一定的指导作用。     

Effect of Ag Nanoparticles on Optical Properties of R6G Doped PMMA Films

The composite PMMA films containing Ag nanoparticles and rhodamine 6G are prepared. We investigate the fluorescence properties and nonlinear optical properties of R6G/PMMA films influenced by Ag nanoparticles. The fluorescence enhancement factor is about 3.3. The corresponding nonlinear refractive index is measured to be -2.423 ×10^-8 esu using the Z-scan technique, which is much enhanced compared with the R6G/PMMA film. The results indicate that these enhancements are attributed to surface plasmon resonance of Ag nanoparticles.     

侧链型偶氮聚合物液晶在不同波长激发条件下的光致取向

合成了聚甲基丙烯酸 (6 [4 (4 氰基偶氮苯 )苯氧基 ]己酯 ) (Poly(6 [4 (4 cyanophenylazo)phenoxy]hexylmethacrylate) (PM6ABCN) ) ,采用溶液挥发法在玻璃载片上成膜 ,研究了薄膜样品在Tg 温度以下的光致取向 .用波长分别为 36 6、40 0和 436nm的偏振光照射 ,发现PM6ABCN薄膜的光致取向过程不仅依赖于光的强度 ,还依赖所使用的偏振光的波长 .在低于Tg 的温度下 ,用波长为 40 0nm ,功率为 2 0mW cm2 的光照射 10 0s可以使样品的取向达到饱和 ,而用 36 6nm的光导致的取向程度要小于 40 0nm和 436nm的光 ,因为 36 6nm的光会在稳态时产生更多数目的cis异构体