| Enhanced Three-Photon Absorption by Symmetric Twisted Intramolecular Charge Transfer |
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| 作者姓名： | 郭福全 杨军 张其锦 明海 |
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| 作者单位： | [1]StructureResearchLaboratory,UniversityofScienceandTechnologyofChina,Hefei230026 [2]DepartmentofPhysics,UniversityofScienceandTechnologyofChina,Hefei230026 [3]DepartmentofPolymerScienceandEngineering,UniversityofScienceandTechnologyofChina,Hefei230026 |
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| 摘 要： | We report on a novel organic chromophore with symmetric twisted intramolecular charge transfer (TICT) state on excitation. The properties of nonlinear transmission induced by three-photon absorption (3 PA) are demonstrated pumped with nanosecond laser pulse. Large 3PA cross sections as high as the order of 10^-74 cm^6s^2 have been obtained for nanosecond and picosecond laser pulses at 1064 nm from intensity-dependent transmission measurements. Similar two emissive behaviours from one-photon and three-photon excited fluorescence spectra indicate that the linear and nonlinear fluorescences share the same TICT relaxation process from the excited states. The intensity dependence of upconversion fluorescence on the incident intensity obeys the cubic law that characterizes the three-photon absorption.
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| 关 键 词： | 三-光子吸收增益 对称扭曲 分子内电荷转移 激发态 |
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