径向流动整体固定相结构完整性的评价

整体色谱固定相结构完整性的评价,是研究整体填料的重要依据。常规的用于评价颗粒填料孔结构的技术,已不适用于评价大体积整体固定相。本实验利用前沿分析法,获得样品在色谱柱上的突破曲线（BTC）,由突破曲线的形状判定整体固定相结构的完整性。双S型突破曲线表明整体柱存在结构缺陷,并可由拐点的位置及曲率评价柱床的缺陷程度。山羊血清样品的快速高效分离,进一步证明了径向整体柱在生物T程领域的应用前景。     

关于N-弱鞅和弱鞅不等式的一个注记

$N$-弱鞅($N$-demimartingales)是由Christofides引进的.Christofides指出均值为零的负相协(negatively associated)随机变量序列的部分和序列是$N$-弱鞅. 然而, 相关文献中引理2.1的证明有错误, 这就影响了其文后的结果引理2.2、定理2.1等. 在这篇注记中,修正了相关文献中的引理2.1, 作为应用, 推广了鞅和下鞅的一些结果.     

区分动植物油的气相色谱-质谱分析

在实际办案中,经常需要对附着在不同载体上的油脂斑痕进行检验,嫌疑斑痕为何类何种油脂对案件的侦破有重大意义.各个领域的专家对动植物油的成分进行研究的目的各不相同,食品工业中偏重于动植物油的食用价值,医学中偏重研究油脂对身体的益处或危害,而司法鉴定领域,偏重于对常见油类进行定性分析,从而为侦查破案提供线索.     

Laplacian第一特征值整体曲率Pinching的一个结果

紧致流形上Laplacian的第一特征值的下界估计一直以来是人们非常感兴趣的问题之一.本文在整体曲率Pinching较小的条件之下考虑这个问题,得到了相应几何条件之下的Laplacian第一特征值的一个下界估计.     

一致L-Lipschitz的渐近拟伪压缩型映象迭代收敛的充要条件

设E是任意的实Banach空间,C是E的非空凸子集(C可以是E的无界子集),T:C→C是→致L-Lipschitz的渐近拟伪压缩型映象,在对参数的一些限制条件下,该文给出了带误差的修改的Ishikawa迭代序列强收敛于T的不动点的充要条件.     

相依误差下回归系数 LS 估计的收敛速度

其中 x(ij)(j=1,…,p,i=1,2,…)是已知常数,常称之为模型(1)的设计常数或设计点列,β_1,…,β_p,为未知的回归系数,y_i,e_i 分别为第 i 次量测时的量测值和量测随机误差。以下,我们记设计矩阵(x_(ij))(?)≤(?)≤n,(?)≤j p 为 X_n,Y_n=(y_1,…,y_n)′,β=(β_1,…,β_p)′.并假定对某N,X′_N X_N 非退化,那么当 n≥N 时,X′_n X_n 亦非退化,且回归系数β的基于前 n 次量测值 Y_(?)及设计矩阵 X_(?)的最小二乘估计(通常简记为 LS 估计) b_(?)=(b_(?)1, …,b_((?)p)'为     

SPECTRAL APPROXIMATION THEORY FOR MULTIGROUP NEUTRON TRANSPORT OPERATORS

In this paper, by using operator theory in Banach space, we mainly study spectral approximation theory for the case of an inhomogeneous, anisotropically scattering, and arbitrarily finite convex body with any cavity in an L~p context for generall p,1≤p<∞. We prove that solutions of the time-dependent multigroup systems converge, in a suitable sense, to the corresponding solution of the exact time-dependent transport equation; the eigenvalues and the corresponding eigenfunctions and generalized eigenfunctions of the exact transport operator are approximated respectively by the eigenvalues and the corresponding eigenfunctions and generalized eigenfunctions of the multigroup transport operotors; the dominant eigenvalues and the corresponding positive eigenfunctions of the multigroup transport operators (the existence is proved, too) accumulate to those of the exact transport operators; the orders of magnitude of the rate of convergence are given respectively. Other results are obtained to compare the dim     

Phase transition and thermal expansion property of Cr_(2-x)Zr_(0.5x)Mg_(0.5x)Mo_3O_(12) solid solution

Compounds with the formula Cr2-xZr0.5xMg0.5xMo3O12（x = 0.0, 0.3, 0.5, 0.9, 1.3, 1.5, 1.7, 1.9） are synthesized, and the effects of Zr4＋ and Mg2＋ co-incorporation on the phase transition, thermal expansion, and Raman mode are investigated. It is found that Cr2-xZr0.5xMg0.5xMo3O12 crystallize into monoclinic structures for x 〈 1.3 and orthorhombic structures for x _〉 1.5 at room temperature. The phase transition temperature from a monoclinic to an orthorhombic structure of Cr2Mo3O12 can be reduced by the partial substitution of （ZrMg）6＋ for Cr3＋. The overall linear thermal expansion coefficient decreases with the increase of the （ZrMg）6＋ content in an orthorhombic structure sample. The co-incorporation of Zr4＋ and Mg2＋ in the lattice results in the occurrence of new Raman modes and the hardening of the symmetric vibrational modes, which are attributed to the MoO4 tetrahedra sharing comers with ZrO6/MgO6 octahedra and to the strengthening of Mo-O bonds due to less electronegativities of Zr4＋ and Mg2＋ than Cr3＋, respectively.     

High Solubility of Hetero-Valence Ion （Cu^2＋） for Reducing Phase Transition and Thermal Expansion of ZrV1.6P0.4O7

Large thermal expansion at room temperature and high phase transition temperature of ZrV2O7 limit its practical applications and are reduced by the high solubility of hetero-valence ion （Cu^2＋） on the basis of an equal-valence substitution of P^5＋ for V^5＋. The temperature-dependent Raman spectra show that Zr0.9CU0.1V1.6P0.4O6.9 maintains a normal parent cubic structure till 173 K and transforms to a 3 × 3 × 3 cubic superstructure below 173K. Temperature dependent x-ray diffraction patterns of Zr0.9CU0.1V1.6P0.4O6.9 show near zero and negative thermal expansion. High solubility of lower valence Cu^2＋ relates to an equal-valence substitution of smaller pH for P^5＋, which extends the bond angle of V（P）-O-V in ZrV1.6P0.4O7 close to 180°. The change of microstructure is considered to be responsible for reduced phase transition temperature and thermal expansion.     

航空发动机尾气静电带电机理分析与试验研究

航空发动机工作时燃烧室内发生复杂的物理化学变化,生成大量带电粒子,导致发动机尾气静电带电;理论分析了发动机喷流尾气中带电粒子产生演化过程和带电影响因素,讨论对比了多种测试原理与传感器方案,确立了非接触式静电感应测试方案,研制了共轴喇叭状静电传感器和静电监测系统,开发了自动测试软件并对某型航空发动机进行了机载尾气静电带电试验研究,验证了测试平台的有效性,成功获得了大量喷流尾气静电信号;研究结果表明:航空发动机正常工作时喷流尾气中带电粒子总体显正极性,平均体电荷密度约为0.077 nC/m³,发动机等效充电电流为2.26 nA。