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排序方式: 共有155条查询结果,搜索用时 218 毫秒
21.
Agibert SA Moreira MB Ratusznei SM Rodrigues JA Zaiat M Foresti E 《Applied biochemistry and biotechnology》2007,136(2):193-206
The effect of temperature on the performance of an anaerobic sequencing biofilm batch reactor (ASBBR) with liquid-phase recirculation
was assessed. Assays were performed using a recirculation velocity of 0.20 cm/s, 8-h cycles, and an average treated synthetic
wastewater volume of 2 L/cycle with a concentration of 500 mg of Chemical Oxygen Demand (COD)/L. Operation temperatures were
15, 20, 25, 30, and 35°C. At 25, 30, and 35°C, organic matter removal efficiencies for filtered samples ranged from 81 to
83%. At lower temperatures, namely 15 and 20°C, removal efficiency decreased significantly to 61 and 65%, respectively. A
first-order model could be fitted to the experimental concentration profile values. The first-order kinetic parameter value
of this model varied from 0.46 to 0.81 h1 considering the lowest and highest temperature studied. Moreover, analysis of the removal profile values allowed fitting
of an Arrhenius-type equation with an activation energy of 5715 cal/mol. 相似文献
22.
Elena Gómez Noelia Calvar Ángeles Domínguez Eugénia A. Macedo 《The Journal of chemical thermodynamics》2010,42(11):1324-1329
In this paper, the ionic liquids 1,2-diethylpyridinium ethylsulfate, EEpyESO4; 1-methylpyridinium methylsulfate, MpyMSO4; 1,3-dimethylpyridinium methylsulfate, MMpyMSO4; and 2-ethyl-1-methylpyridinium methylsulfate, EMpyMSO4; were synthesized in our laboratory, and their experimental densities, speeds of sound, dynamic viscosities, and refractive indices were studied as a function of temperature at atmospheric pressure. Thermal expansion coefficient, molar volume, and molar refraction of these ionic liquids were calculated from the experimental density and refractive index values. 相似文献
23.
da Silva Bruno Fonseca da Silva Karolayne Esthefany Melo de Farias Emerson Emiliano Gualberto de França Elvis Joacir Martins Mônica Cristina Barroso de Oliveira Santos Mariana Luiza de Lourdes Lacerda Buril Maria da Silva Alves Gustavo Gabriel de Oliveira Silva Andrezza Karla de Lira Júnior Ednaldo Barbalho da Silva Nicácio Herique Pereira Eugênia C. 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(9):3671-3679
Journal of Radioanalytical and Nuclear Chemistry - This study aimed to evaluate the effects of the Rn-222 progeny on the lichen Cladonia verticillaris under controlled conditions. The results... 相似文献
24.
Daniela M. Nolasco Isabel C. P. Fortes Eugênia R. Valadares 《Biomedical chromatography : BMC》2020,34(11):e4931
Quantitative analysis of amino acids in blood and urine is primarily indicated for the diagnosis of amino acid disorders. The high-performance liquid chromatography (HPLC) technique is frequently used for this detection. The frequency of sample collection on filter paper has been increasing exponentially, and there are many advantages attributed to processing biological samples in this way. The aim of this study was to validate a quantitative analysis of amino acids by HPLC in blood and urine collected on filter paper and to establish reference values in the neonatal period. Dried blood and dried urine samples of respectively 58 and 45 healthy newborns (2–9 days) were collected. Pre-treatment and extraction of samples were done according to the literature. Separation and analysis of amino acids were carried out by HPLC with fluorescence detection. The developed method demonstrated excellent separation, linearity, limits of detection and quantification, repeatability and recovery. The reference values for 17 amino acids were defined in dried blood and urine samples of newborns. This work presents a simple, fast and effective method for the simultaneous analysis of 17 amino acids in blood and urine collected on filter paper in a single run. The reference values were established and validated. 相似文献
25.
Guanaes Lais Danciguer Guimarães Matheus Murmel Ducatti Diogo R. B. Duarte Maria Eugênia R. Barreira Sandra M. W. Noseda Miguel D. Gonçalves Alan Guilherme 《Chemistry of Heterocyclic Compounds》2021,57(12):1195-1203
Chemistry of Heterocyclic Compounds - In the present work, we have synthesized new molecular hybrids consisting of porphyrin ring system connected at the meso positions with phenyl groups and/or,... 相似文献
26.
27.
Alan G. Gonçalves Diogo R. B. Ducatti T. Bruce Grindley M. Eugênia R. Duarte Miguel D. Noseda 《Journal of the American Society for Mass Spectrometry》2010,21(8):1404-1416
We have prepared a number of isomeric red seaweed galactan-derivative sulfated oligosaccharides to determine whether there
were diagnostic differences among the isomeric mass spectra obtained using ESI CID MS/MS (triple quadrupole instrument). Fragmentation
of the single or multicharged molecular ions from di-, tetra-, and hexasaccharides indicated that the relative positioning
of the sulfate groups and type of monosaccharide unit affect the rate of cleavage of the glycosidic bonds. We also performed
a comparative [M-Na]− fragmentation study of positional isomers of sulfated disaccharides that present all four monosulfation possibilities on
the galactopyranosidic ring. In this case, negative-ion ESI CID MS/MS approach gave diagnostic product ions from cross-ring
cleavages along with the same main B1 ion (from sulfated Galp), at m/z 241, for all isomers. The isomeric disaccharides were also submitted to increased spray energy conditions inducing in-source
fragmentation; preformed B1 ions were then fragmented to give similar product ions as those found in [M-Na]− analysis. Evaluation of the relative abundances mainly for cross-ring fragment ions at m/z 138, 139, 151, 153 allowed clear distinction among the members of the disaccharide series. The different ratios for m/z 151/153 ions were consistent with the predominance of m/z 153 being related to the cases when the bond involved in the cleavage process links a sulfated carbon. A quadrupole ion trap
instrument (MSn analysis) was also utilized to compare the results obtained with the triple quadrupole instrument. 相似文献
28.
Calhelha RC Ferreira IC Peixoto D Abreu RM Vale-Silva LA Pinto E Lima RT Alvelos MI Vasconcelos MH Queiroz MJ 《Molecules (Basel, Switzerland)》2012,17(4):3834-3843
Three aminodi(hetero)arylamines were prepared via a palladium-catalyzed C-N Buchwald-Hartwig coupling of methyl 3-aminothieno[3,2-b]pyridine-2-carboxylate with different bromonitrobenzenes, followed by reduction of the nitro groups of the coupling products to the corresponding amino compounds. The aminodi(hetero)arylamines thus obtained were evaluated for their growth inhibitory effect on four human tumor cell lines MCF-7 (breast adenocarcinoma), A375-C5 (melanoma), NCI-H460 (non-small cell lung cancer) and HepG(2) (hepatocellular carcinoma). The toxicity to non-tumor cells was also evaluated using a porcine liver primary cell culture (PLP1), established by us. The aminodi(hetero)arylamine with the NH(2) group in the ortho position and an OMe group in the para position to the NH of the di(hetero)arylamine, is the most promising compound giving the lowest GI(50) values (1.30-1.63 μM) in all the tested human tumor cell lines, presenting no toxicity to PLP1 at those concentrations. The effect of this compound on the cell cycle and induction of apoptosis was analyzed in the NCI-H460 cell line. It was observed that it altered the cell cycle profile causing a decrease in the percentage of cells in the G0/G1 phase and an increase of the apoptosis levels. 相似文献
29.
1H NMR-based metabolomics approach for exploring urinary metabolome modifications after acute and chronic physical exercise 总被引:1,自引:0,他引:1
C. Enea F. Seguin J. Petitpas-Mulliez N. Boildieu N. Boisseau N. Delpech V. Diaz M. Eugène B. Dugué 《Analytical and bioanalytical chemistry》2010,396(3):1167-1176
Metabolomics is a comprehensive method for metabolite assessment that involves measuring the overall metabolic signature of
biological samples. We used this approach to investigate biochemical changes due to acute and chronic physical exercise. Twenty-two
women using identical oral contraceptives were segregated into an untrained (n = 10) or trained (n = 12) group depending on their physical training background. The subjects performed two exercises in a randomized order:
a prolonged exercise test (75% of their
\mathop V· \textO2 max \mathop V\limits^\cdot {{\text{O}}_{2\,\;\max }} until exhaustion) and a short-term, intensive exercise test (short-term, intensive exercise anaerobic test). Urine specimens
were collected before and 30 min after each test. The samples were analyzed by 1H NMR spectroscopy, and multivariate statistical techniques were utilized to process the data. Distinguishing characteristics
were observed only in the urine profiles of specimens collected before vs. 30 min after the short-term, intensive exercise
test. The metabolites responsible for such changes were creatinine, lactate, pyruvate, alanine, β-hydroxybutyrate, acetate,
and hypoxanthine. In both groups, the excretion of lactate, pyruvate, alanine, β-hydroxybutyrate, and hypoxanthine increased
similarly after the completion of the short-term, intensive exercise test (p < 0.03). However, acetate excretion increased to a lesser extent in trained than in untrained subjects (p < 0.05). In conclusion, metabolomics is a promising tool in order to gain insight into physiological status and to clarify
the changes induced by short-term, intense physical exercise. 相似文献
30.