锂离子电池正极材料LiMn2-xCrxO4电化学性能的研究

针对尖晶石型LiMn2O4锂离子电池正极材料的容量衰减,提出了相应的抑制方法,所合成的LiMn2-xCrxO4(0相似文献   

应用红外光谱法快速测定粉煤灰中硫酸盐

用直接燃烧-红外吸收光谱法测定粉煤灰中硫酸盐。在1300℃，加WO3作助熔剂，直接燃烧试样释出SO2，然后用红外吸收光谱法测定。结果准确，操作快速。分析一份试样的时间由原来重量法的8～9h缩短至现方法的4min。     

EFFECTS OF COMPATIBILIZERS ON THE MECHANICAL PROPERTIES OF LOW DENSITY POLYETHYLENE/LIGNIN BLENDS

Low density polyethylene(LDPE)/lignin blends were prepared using melt blending.Two kinds of compatibilizers, ethylene-vinylacetate(EVA) which is softer than LDPE and polyethylene grafted with maleic anhydride(PE-g-MA) which is harder than LDPE were used to improve the interfacial adhesion.Scanning electron microscope(SEM) was used to investigate the dispersion of lignin in LDPE matrix.The results showed that both of the compatibilizers could improve the interaction between the low density polyethylene an...     

等离子体处理碳纳米管的研究现状及展望

采用等离子体处理技术对碳纳米管进行表面处理是一项新兴的技术,本文对在碳纳米管处理过程中,等离子体处理工艺参数的选择,以及处理前后表面结构变化、形貌变化、场发射效应等进行了综述,并对等离子体处理技术在碳纳米管表面修饰中的应用前景进行了展望。     

煤矿泥岩流变模型辨识及支护方法的确定

结合高家梁煤矿斜井泥岩的流变变形特征, 对泥岩进行分析建模, 设计有效的泥岩斜井支护措施. 通过对泥岩进行蠕变加卸载试验, 采用统一流变力学模型理论建立了能表现泥岩流变特性的弹性--黏性--黏弹性--黏弹塑性模型, 并确定了流变模型参数. 结合泥岩试验测得的泥岩力学特性和现场观测资料, 设计采用锚喷网联合支护方法, 并采用大型有限元软件ADINA进行数值模拟分析, 该支护方法能有效控制泥岩变形, 采用的锚喷网支护方法合理可靠.     

Size Distribution and Anisotropy of the MinorPhase Droplets in Polypropylene/Ethylene-OcteneCopolymer Blends: Effects of Shear andComponent Miscibility简

In this work, polypropylene （PP）/octene-ethylene copolymer （POE） blends were injection-molded using the so- called dynamic packing injection technique, which imposed oscillatory shear on the gradually cooling melt during the packing solidification stage. In this way, the effect of shear on the size distribution and anisotropy of the minor phase droplets could be investigated. Besides, by using two kinds of POE with different octene contents, the effect of component miscibility was also studied. The results show that the droplet size is mainly determined by composition and miscibility, and droplet anisotropy is mainly determined by droplet size and shear. Most importantly, under the same processing condition, droplet anisotropy increases with droplet size, and there seems a linear fit between them, disregarding the miscibility factor. These results may provide guidance for preparing polymer blends with desired properties by tailoring their phase morphologies.     

Extended Self Similarity of Passive Scalar in Rayleigh-Bénard Convection Flow Based on Wavelet Transform

Wavetet transform was used to analyze the scaling law of temperature data utilize the method of extended self similarity, presented first by Benzi et al. , to study the scaling exponent of temperature data. The obtained results show that the inertial range is much wider than that one determined directly from the conventional structure function, and find the obtained scaling exponent agrees well with the one obtained from the temperature data in an experiment of wind tunnel. The second one was that, by extending the formula which was proposed by A. Arneodo et al. for extracting the scaling exponentζ(q) of velocity data to temperature data, a newly defined formula which is also based on wavelet transform, and can determine the scaling exponentζ(q) of temperature data was proposed.The obtained results demonstrate that by using the method which is named as WTMM ( wavelet transform maximum modulus )ζ(q) correctly can be extracted.     

多功能椭偏测厚仪

研究成功一台变入射角反射式消光法多功能智能椭偏测厚仪。实验表明 :仪器的测厚准确度为± 0 1nm ;椭偏参数Ψ和Δ的测量重复性精度分别为± 0 1°和± 0 3° ,适用于纳米级薄膜厚度和折射率的测量     

高强超韧高密度聚乙烯/聚丙烯共混物性能与微相分离结构的研究

在常规注射过程中 ,难以获得超高性能的共混体系注射制件 ,已有的研究表明 ,采用高剪切注射 ,可以抬高共混体系的最低临界相容温度曲线 (LCST)的位置 ,增加相容性 .当熔体进入模具后 ,冷却的同时相容性下降 ,开始相分离 ,相分离程度发展到某一程度即可获得高性能的制件 .对于高密度聚乙烯 (HDPE)、聚丙烯 (PP)两组分均为结晶型聚合物的共混体系 ,由于其相形态与结晶形态相互制约、竞争 ,微相分离程度难以控制 ,因此对其液 液相形态与结晶过程的控制是获得共混物最终形态与性能的关键 .采用振动保压注射成型技术不仅对HDPE、PP各自力学性能有明显的自增强作用 ,而且对HDPE/PP共混体系的力学性能也有十分明显的改善 .DSC、WAXD、SEM结果表明共混体系拉伸强度的提高主要取决于试样中串晶数量和大分子链的定向程度 ,而冲击强度则主要取决于两组分微观的相分离程度 .研究结果表明 ,HDPE/PP含量为 92 / 8的试样拉伸强度为 97 1MPa,80 / 2 0试样的缺口冲击强度为 4 5 5kJ/m2 ,较静态试样分别提高 4 3倍和 9 5倍 .采用振动填充注射技术针对某一组分可以获得高强度、高韧性的共混制件 .     

茂金属聚乙烯的支化非均匀性与结晶形态

以美国Exxon公司生产的茂金属短支链聚乙烯 (SCBPE)为研究对象 ,用DSC热分级方法研究了不同支链含量聚乙烯的支化非均匀性 ,并用TEM表征茂金属聚乙烯在不同条件下熔体结晶的形态 .SCBPE经逐步结晶分级后 ,其DSC熔融曲线出现多峰 ,表明茂金属SCBPE仍具有很大的非均匀性 .支链含量愈高 ,熔点愈低 ,非均匀性增加 .SCBPE的晶体形态随平均支链含量的增加片晶厚度减小 ,片晶尺寸分布增加 ;含量较低时 ,SCBPE在不同温度下均生成球晶结构 .随结晶温度的降低支链含量较多的分子也能参与结晶 ,故生成的片晶厚度减小 .从相分离的熔体中结晶 ,大尺度的片晶集聚体间的分离和小尺度的片晶之间相分离同时存在 .