2-(Ⅳ,Ⅳ-二羧甲基)-氨甲基4-氯酚铜(Ⅱ)的合成、结构与催化降解聚丙烯酰胺性能研究

合成了2-(N,N-二羧甲基)氨甲基4-氯酚,进而在水溶液中合成了其铜(Ⅱ)配合物,通过X-射线单晶衍射法测定了晶体结构.配合物中心Cu(Ⅱ)为五配位四方锥结构,在该配合物的晶体结构中存在两种构象异构体,相互问隔通过分子问氢键连接,延伸为一维链状结构.催化性能研究表明该配合物对H<,2>O<,2>的氧化降解聚丙烯酰胺有...     

2-(N,N-二羧甲基)-氨甲基-4-氯酚铜(Ⅱ)的合成、结构与催化降解聚丙烯酰胺性能研究

合成了2-(N,N-二羧甲基)氨甲基4-氯酚,进而在水溶液中合成了其铜(Ⅱ)配合物,通过X-射线单晶衍射法测定了晶体结构.配合物中心Cu(Ⅱ)为五配位四方锥结构,在该配合物的晶体结构中存在两种构象异构体,相互问隔通过分子问氢键连接,延伸为一维链状结构.催化性能研究表明该配合物对H<,2>O<,2>的氧化降解聚丙烯酰胺有一定的催化作用,可以使分子量由6.1×10<'6>降低至1.66×10<'5>.     

SU(3) spin-orbit coupled fermions in an optical lattice

We propose a scheme to realize the SU(3)spin-orbit coupled three-component fermions in an one-dimensional optical lattice.The topological properties of the single-particle Hamiltonian are studied by calculating the Berry phase,winding number and edge state.We also investigate the effects of the interaction on the ground-state topology of the system,and characterize the interaction-induced topological phase transitions,using a state-of-the-art density-matrix renormalization-group numerical method.Finally,we show the typical features of the emerging quantum phases,and map out the many-body phase diagram between the interaction and the Zeeman field.Our results establish a way for exploring novel quantum physics induced by the SOC with SU(N)symmetry.     

Topological phases and type-II edge state in two-leg-coupled Su-Schrieffer-Heeger chains

Topological quantum states have attracted great attention both theoretically and experimentally.Here,we show that the momentum-space lattice allows us to couple two Su-Schrieffer-Heeger(SSH)chains with opposite dimerizations and staggered interleg hoppings.The coupled SSH chain is a four-band model which has sublattice symmetry similar to the SSH4.Interestingly,the topological edge states occupy two sublattices at the same time,which can be regarded as a one-dimension analogue of the type-II corner state.The analytical expressions of the edge states are also obtained by solving the eigenequations.Finally,we provide a possible experimental scheme to detect the topological winding number and corresponding edge states.     

Hard-core Hall tube in superconducting circuits

The Hall tube as a minimum model to simulate the integer quantum Hall effect is essential for exploring topological physics, while it has not been constructed in the recent developing successfully experiments on superconducting circuits. In this work, we propose a feasible experiment scheme using three legs superconducting circuits with transmon qubits to realize a Hall tube. Then we first investigate its topological properties. Since the time-reversal, particle-hole, and chiral symmetries are all broken for the system, the Hall tube belongs to the A class of the Altland-Zirnbauer classification. We obtain the corresponding topological phase transition both numerically and analytically. Since the chirality is a key character of the quantum Hall effect, we secondly investigate the chiral physics in the Hall tube. We find the topological protected chiral edge currents and discuss its robustness. Finally, we give the possible experimental observations of the topological state and topological protected chiral edge currents.     

Legendre transformations and the thermodynamic geometry of 5D black holes

This paper studies the thermodynamic properties of the 5D black hole in Einstein-Gauss-Bonnet gravity from the viewpoint of geometrothermodynamics. It is found that the Legendre invariant metrics of the 5D black holes in Einstein-Yang-Mills-Gauss-Bonnet theory and Einstein-Maxwell-Gauss-Bonnet theory reproduce the behavior of the thermodynamic interaction and phase transition structure of the corresponding black hole configurations correctly. It is shown that they are both curved and that the curvature scalar provides information about the phase transition point.     

ICF激光驱动器间接驱动兼顾直接驱动打靶角度的优化设计

为了增加ICF激光驱动器的灵活性,使其可满足多种聚变点火方式,激光驱动器激光打靶角度的优化设计应以间接驱动为主,同时兼顾直接驱动。以神光Ⅲ主机装置为例,基于已有的间接驱动激光打靶角度设计,用球谐模和三维辐照场方法,完成了兼顾直接驱动打靶角度的优化,结果表明优化设计的打靶角度可实现小于1%的球靶表面辐照均匀性。同时分析了激光参数对辐照性能的影响,并获得了满足直接驱动要求的陡边小焦斑设计。     

关于21世纪数学类学生综合能力培养的思考

针对21世纪以来科学和技术的迅猛发展及社会对数学类学生提出的要求,对大学数学类学生综合能力培养的必要性进行了全面论述,详细分析了数学类学生综合能力培养存在的问题,提出了相应解决措施．     

初始位置布局不平衡的疏散行人流仿真研究

行人初始位置布局不平衡的多安全出口疏散过程, 是行人疏散流仿真研究的热点. 利用行人流动态参数仿真模型, 在实际距离和假想距离"极大极小"路径选择机理的基础上, 改进假想距离的计算方法及其拥堵计算区域, 实现疏散过程的动态平衡; 提出行人位置布局的不平衡系数, 以描述疏散空间内行人初始位置布局的不平衡性. 从行人初始位置随机和固定布局的角度, 仿真研究正常疏散环境下行人布局的不平衡性对疏散时间的影响, 并将仿真结果与原始模型做对比分析. 研究表明, 模型能有效地实现行人流疏散过程的动态平衡, 行人疏散时间受行人位置或安全出口布局的影响较小, 而与安全出口总宽度、 行人的初始数量以及拥堵感知系数有关.     

0.2 nm带宽滤光片的制备以及退火温度对其形貌和性能的影响

近红外波长为1.064 μm的激光是激光测距、自由空间光通信和空间光学遥感等应用中的主要激光光源之一.窄带滤光片是抑制背景光干扰的关键元件之一,目前大部分滤光片的半峰全宽为几纳米.本文研制了中心波长为(1064±0.05) nm、半峰全宽为0.19 nm、峰值透过率可达70.2％的带通滤光片,并考察了不同温度(100,200,300℃)退火处理后滤光片的表面形貌和光谱特性的变化.实验结果表明:滤光片的表面光滑,受退火温度的影响很小;滤光片的透射光谱随着退火温度的升高向长波方向移动,在100℃退火处理3h的滤光片的光谱漂移量为0.03 nm,说明该滤光片可在温控条件有限的空间光学系统中使用.