具有可逆热致变色有机-无机杂化铜化合物的合成及表征

在浓盐酸水溶液中，碘化N，N-二甲基-1，5-二氮杂环[3.2.1]辛烷（[3.2.1-Me₂dabco]I₂）和碘化1-氨基-1，4-二氮杂环[2.2.2]辛烷（[2.2.2-NH₂dabco]I）与氯化铜反应得到2种有机-无机杂化铜化合物[3.2.1-Me₂dabco][CuCl₄]（1）和[2.2.2-NH₂dabco][CuCl₄]（2）。X射线单晶结构衍射证实化合物1和2中的无机阴离子是[CuCl₄]^2-四面体。化合物1和2表现出可逆的热致变色现象，随着温度升高，它们的颜色从黄色变为红色，这应该是由[CuCl₄]^2-四面体的变形引起的。     

Synthesis and Structural Characterization of two Novel Copper(I) Complexes with Oxygen Donor

Two novel copper(I) complexes with Cu‐O bonds, [Cu₂L₂(PPh₃)₂](BF₄)₂ ( 1 ) and [Cu(L)(dppeo)](BF₄) ( 2 ) ( L = 6‐(4‐diethylmethylphosphonatephenyl)‐2,2′‐bipyridine, dppeo = bis(diphenylphosphino)ethane monoxide), have been prepared and their structures characterized. In the binuclear complex 1 , the ligand L serves as tridentate donor with the N, N′ and O as coordination atoms, and the two Cu^I atoms are bridged through both P = O donor atoms in different ligand L with a triphenylphosphine molecule as auxiliary ligand. While in mononuclear complex 2 , both ligands L and dppeo behave as bidentate with N^∧N from L and P^∧O from dppeo chelating to Cu^I atom.     

Immobilization of carboxyl-modified multiwalled carbon nanotubes in chitosan-based composite membranes for U(VI) sorption

Journal of Radioanalytical and Nuclear Chemistry - The carboxyl-modified multiwalled carbon nanotubes were immobilized in chitosan-based composite membranes (CS-CNTs) which were used as efficient...     

Sparse non-negative matrix factorizations for ultrasound factor analysis

Factor analysis is a powerful tool used for the analysis of dynamic studies. One of the major drawbacks of Factor Analysis of Dynamic Structures (FADS) is that the solution is not mathematically unique when only non-negativity constraints are used to determine factors and factor coefficients. In this paper, we introduce a novel method to correct FADS solutions by constructing and minimizing a new objective function. The method is improved from non-negative matrix factorizations (NMFs) algorithm by adding a sparse constraint that penalizes multiple components in the images of the factor coefficients. The technique is tested on computer simulations, and a patient ultrasound liver study. The results show that the method works well in comparison to the truth in computer simulations and to region of interest (ROI) measurements in the experimental studies.     

Investigation of capacitance storage and cyclic voltammetry for the electrochemical oxidation of phenol on iridium and lead oxide electrodes

Journal of Solid State Electrochemistry - The capacitance storage and cyclic voltammetry (CV) of electrochemical oxidation of phenol were investigated using IrO2–Ta2O5/Ti and β-PbO2/Ti...     

Click Chemistry on Polymer Support: Synthesis of 1-Vinyl- and 1-Allyl-1,2,3-triazoles via Selenium Linker

Polystyrene-supported 2-azidoethyl phenyl selenide and 3-azidopropyl phenyl selenide reagents have been developed and applied to the traceless solid-phase organic synthesis of 1-vinyl- and 1-allyl-1,2,3-triazoles by CuI-mediated azide–alkyne cycloadditions and subsequent cleavage from the polymer support through oxidation–elimination reaction with 30% hydrogen peroxide. The advantages of this method include straightforward operation, good yield and purity of the products, and good stability and lack of odor for the reagents.     

Analysis of F-53B,Gen-X,ADONA, and emerging fluoroalkylether substances in environmental and biomonitoring samples: A review

The persistent, bioaccumulative, and toxic properties of certain per- and polyfluoroalkyl substances (PFAS) raise concerns for environmental and human health. This has led to the gradual phase-out from production and commerce of some legacy PFAS. Fluoroalkylether compounds (ether-PFAS) are among the fluorinated alternative chemicals that are beginning to be reported in impacted and background environments. Extensive monitoring activities were conducted since 2015–2019 to bridge knowledge gaps on the environmental fate and effects of ether-PFAS including F-53B (6:2 chlorinated polyfluoroalkyl ether sulfonate [6:2 Cl-PFAES] and 8:2 Cl-PFAES), Gen-X (hexafluoropropylene oxide dimer acid [HFPO-DA]), and ADONA (dodecafluoro-3H-4,8-dioxanonanoate). In recent years, advances in nontarget screening using high-resolution mass spectrometry have revealed the identities of other infrequently monitored ether-PFAS. In this critical review, we provide an up-to-date inventory of the structures of ether-PFAS discovered in the recent literature. Their environmental occurrence, fate, and effects are discussed on a comparative perspective with some legacy PFAS such as perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS). Information on the methods employed for the quantitative and semi-quantitative analysis of ether-PFAS is also provided, including sample preparation and mass spectrometry analysis, analytical performance, and limitations. In particular, the compiled database of MS/MS fragment ions (n = 111) can be useful in spectrum interpretation of novel ether-PFAS. The concluding remarks open on possible research avenues and the challenges that remain to be addressed.     

Multiple bifurcation trees of period-1 motions to chaos in a periodically forced,time-delayed,hardening Duffing oscillator

In this paper, bifurcation trees of periodic motions in a periodically forced, time-delayed, hardening Duffing oscillator are analytically predicted by a semi-analytical method. Such a semi-analytical method is based on the differential equation discretization of the time-delayed, nonlinear dynamical system. Bifurcation trees for the stable and unstable solutions of periodic motions to chaos in such a time-delayed, Duffing oscillator are achieved analytically. From the finite discrete Fourier series, harmonic frequency-amplitude curves for stable and unstable solutions of period-1 to period-4 motions are developed for a better understanding of quantity levels, singularity and catastrophes of harmonic amplitudes in the frequency domain. From the analytical prediction, numerical results of periodic motions in the time-delayed, hardening Duffing oscillator are completed. Through the numerical illustrations, the complexity and asymmetry of period-1 motions to chaos in nonlinear dynamical systems are strongly dependent on the distributions and quantity levels of harmonic amplitudes. With the quantity level increases of specific harmonic amplitudes, effects of the corresponding harmonics on the periodic motions become strong, and the certain complexity and asymmetry of periodic motion and chaos can be identified through harmonic amplitudes with higher quantity levels.     

Spin Squeezing and Quantum Fisher Information in the Lipkin-Meshkov-Glick Model

We investigate spin squeezing and quantum Fisher information in the Lipkin-Meshkov-Glick model. Approximate analytical expressions and the numerical analysis of spin squeezing and quantum Fisher information are derived. Spin squeezing and quantum Fisher information depend on the strength of the external transverse magnetic field and the anisotropic parameter