硅表面聚苯乙烯自组装超薄膜的制备及摩擦磨损性能研究

研究了苯乙烯 -乙烯基三乙氧基硅烷共聚物在羟基化基片上的自组装行为及聚合物超薄膜的摩擦磨损性能 .结果表明 ,自组装聚合物薄膜的厚度和均匀程度取决于聚合物成膜溶液的浓度 .与空白基底相比 ,自组装膜修饰的基底在低载荷下同钢对摩时的摩擦系数更低 ,耐磨寿命更长 .因此 ,自组装聚合物薄膜可以作为低载荷下硅基材料的减摩抗磨防护层     

置换通风的数值模拟

首先介绍了用于数值模拟置换通风室内空气分布的N点风口模型、新零方程湍流模型，以简化和加快实际工程中对置换通风的模拟计算。然后利用这些模型对某办公室置换通风的室内温度场和速度场进行了模拟，并和实验数据进行对比。结果表明，计算所得速度和温度分布与实测值吻合得很好，所用的风口模型和湍流模型能将置换通风的温度分层特性和速度场合理地模拟出来，可用于指导和优化置换通风气流组织设计。     

有限元方法在爆炸动力学中的应用

从动量和能量守恒方程出发，结合爆炸动力学的特点，建立适于模拟爆炸动力学过程的有限元方法，并对两个问题进行了模拟计算。计算结果与实验结果符合表明，通过选择合适的物质模型，有限元方法对爆炸动力学问题的模拟是可行的。     

Direct Observation of High-Temperature Superconductivity in One-Unit-Cell FeSe Films

We prepared one-unit-ceil （1-UC） thick FeSe films on insulating SrTiOa substrates with non-superconducting FeTe protection layers by molecular beam epitaxy for ex situ studies. By direct transport and magnetic measurements, we provide definitive evidence for high temperature superconductivity in the 1-UC FeSe films with an onset Tc above 40 K and an extremely large critical current density fie Jc-1.7× 106 A/cm2 at 2K, which are much higher than Tc-8K and Jc-104 A/cm^2 for bulk FeSe, respectively. Our work may pave the way to enhancing and tailoring superconductivity by interface engineering.     

Electronic and magnetic properties of BiFeO_3 with intrinsic defects:First-principles prediction

The electronic structure, magnetism, and dielectric functions of BiFeO3 with intrinsic vacancies, including Bi-, Fe-, and O-vacancies （denoted as VFe, VBi, and Vo, respectively） are investigated using the first-principles density functional theory plus U calculations. It is revealed that the structural distortions associated with those vacancies impose significant influences on the total density of state and magnetic behaviors. The existence of VBi favors the excitation of the O2p state into the band gap at 0.4 eV, while the O2p and Fe3d orbitals are co-excited into the band gap around 0.45 eV in VFe- Consequently, a giant net magnetic moment of 1.96 P-B is generated in VFe, and a relatively small moment of 0.13 P-B is induced in VBi, whereas Vo seems magnetically inactive. The giant magnetic moment generated in VFe originates from the suppression of the spatially modulated antiferromagnetic spin structure. Furthermore, VFe and VBi have strong influences on dielectric function, and induce some strong peaks to occur in the lower energy level. In contrast, VO has a small effect.     

疏水基含量和微嵌段长度对缔合聚合物溶液弹性的影响

研究了疏水基含量和微嵌段长度对缔合聚合物,聚(丙烯酰胺-丙烯酸钠-十六烷基二甲基烯丙基氯化铵)[P(AM-NaAA-C16DMAAC)],弹性行为的影响规律。研究结果表明,对于结构类似且具有相近零剪切粘度的缔合聚合物,疏水基含量越高,聚合物分子链间形成稠密网络结构的疏水缔合能力越强,其第一法向应力差N1越大,N1出现拐点处对应剪切速率越小,缔合聚合物溶液弹性越好;并且缔合聚合物溶液的弹性随着疏水微嵌段长度的增加先增加后降低,存在最佳微嵌段长度。因此,可以通过调整分子结构有效改变缔合聚合物溶液的弹性行为。     

可移动半无限垂直圆柱体温度交变振荡时对MHD自由对流的影响

不可压缩粘性流体,流过可移动、温度交变振荡的半无限垂直圆柱体时,对MHD自由对流影响的数值解进行了研究.应用Crank-Nicolson型的隐式有限差分方法,求解无量纲、不稳定、非线性、耦合的偏微分控制方程.在不同参数下研究速度、温度和浓度分布的变化,还分析了局部及平均的表面摩擦力、Nusselt数和Sherwood数,并以图形形式给出.所得结果与其他文献的结果比较,有着很好的一致性.     

Solitary Wave Solutions of Triple Sine-Gordon Equation

Through a mapping relation between the triple sine-Gordon and Ф5 model, we discuss the equation in detail. A series of solitary wave solutions for the triple sine-Gordon equation is obtained by the existing ones of the Ф5 model. Some detailed solitary wave solutions are given for some special coefficients which have significance in physics.     

WHITEHEAD GROUPS OF MODULE EXTENSIONS

When R satisfies (strong unit) 1-stable range and M is a R-R-bimodule, theauthors calculate that K1(R ∞ M) ≌ U(R ∞ M)/L(R ∞ M). As applications, the authors also calculate some Whitehead groups for exchange rings with artinian primitive factors.Key words Whitehead group, module extension, (strong unit) 1-stable range     

建筑涂料用苯丙乳液的研制

本文采用自由基乳液聚合方法，通过苯乙烯，丙烯酸丁酯和丙烯酸三元共聚反应，合成了建筑涂料用的苯丙乳液。通过大量的实验确定了反应配方及加料方式，并详细讨论了各组分及反应条件对聚合反应和产品性能的影响。