杯芳烃对铁的配位及其超分子化学研究进展

介绍了近年来杯芳烃对铁的配位及其超分子化学的研究进展,讨论了杯芳烃对铁的配位结构及其超分子作用机理.并对"杯芳烃-铁"配位及其超分子化学的研究动向作了展望.     

富勒烯C60、C70的超分子化学

介绍了富勒烯Ｃ６０、Ｃ７０与环糊精、冠醚、杯芳烃等主体形成超分子的进展和一些潜在的应用前景。     

High extraction ability of 1,3-dialkynyl calixarene towards mercury（Ⅱ） ion

The reaction of 1,3-dipropyn-2-yloxycalix[4]arene with mercury(II)acetate could give mercury-containing alkynyl calixarenepolymer.The extraction behavior of 1,3-dipropyn-2-yl-oxycalix[4]arene towards mercury(II)ion was examined.When the moleratio of Hg~(2 )/calixarene was 1:1,the extractive percent can reach to 99.1%,and the extraction capacity was up to 431 mg/g.It couldalso decrease the Hg~(2 )concentration from 5 to 0.85 mg/L,which was only 17%of the national standard of effluent and satisfied thenational standard of drinking water.The extraction process included chemical reaction.     

超分子自组装合成杯[4]芳烃黄原酸镍(Ⅱ)配合物

利用二维和三维的大环及笼状主体分子与金属离子直接进行自组装反应合成新型有机无机杂化分子是当前超分子领域的研究热点之一。这类分子不仅具有新奇的光、电、磁等特性，而且还可作为新型的主体分子在客体识别、催化、吸附与分离等方面有广阔的应用前景。杯芳烃是有机超分子领域广受     

Synthesis of a Tweezer—like Bis（Phenylthiapropoxy）calix[4]—arene as a Cation／π Enhanced Sensor for Ion—Selective Electrodes

Two novel 25,27-dihydroxy-26,28-bis(3-phenylthiapropxy)-calix[4]arene(3) and 25,27-dihydroxy-26,28-bis(3-phenylthiapropoxy)-5,11,17,23-tetra-tert-butylcalix[4] arene (4) were synthesized for the evaluation of their ion-selectivity in ion-selective electrodes(ISEs).ISEs based on 3 and 4 as neutral ionophores were prepared,and their selectivity coefficients for Ag^ (lg KAg,M^pot)were investigated against other alkali metal,alkaline-earth metal,aluminum,thallium(Ⅰ）,Lead and some transition metal ions using the separate solution method (SSM).These ISEs showed excellent Ag^ seletivity over most of the interfering cations examined,except for Hg^2 and Fe^2 having relative smaller interference(lg KAg,M^pot≤-2.1).     

羧基苯偶氮基杯[6]芳烃衍生物的合成及表征

近几年,随着对主客体化学研究的深入,杯芳烃的功能化修饰成为该领域的研究热点[1-6]。本文以邻、间、对氨基苯甲酸和杯[6]芳烃为原料,经重氮化 偶联反应合成了新型有色邻、间、对羧基苯偶氮基杯[6]芳烃,产物的结构经IR,1HNMR和元素分析表征;并研究了它们生色原理和光谱性能。结果表明它们是一类新型指示剂和具有新型配位空腔的主体分子。合成路线如下:图1　邻、间、对羧基苯偶氮基杯[6]芳烃的合成Fig.1　Fig1:Synthesisofp (o,m,p carboxylbenzeneazo)calix[6]arenes1　实验部分1 1　仪器与试剂Nicolet 460型傅里叶红外光谱仪(KBr…     

Synthesis and Characterization of Thiacalix[ 4 ] arene Derivatives with Polymerisable Groups

Introduction Calixarenes are versatile host molecules for molecular recognition and supram olecular assembly be-cause its functional groups can be readily introduced in-to the phenolic OH or the para position to realize a wide variety of functions[1-5].     

AAS法测定土壤中铜的新型进样装置

研制了一种新的进样装置，装置既可常规进样又可以脉冲进样，可用于土壤中铜元素的测定。并对两种进样的方法的分析性能进行了对比。     

杯芳烃的分子设计(Ⅵ)--一种新的杯[4]磺胺衍生物的合成及晶体结构

杯芳烃是由酚单体通过亚甲基在羟基邻位桥连而成的环状低聚物, 它具有可调的杯状疏水空腔, 结构柔性较大, 构象可变, 并对中性分子和有机、无机离子具有选择性配位能力. 因此, 在其上下缘进行化学修饰所得到的杯芳烃衍生物可广泛应用于萃取分离、离子选择性电极、色谱分析、功能材料、催化及模拟酶等研究领域[1～4].     

基于杯芳烃的阳离子荧光分子传感器的研究进展

按照荧光团的种类, 综述了基于杯芳烃的荧光分子传感器对阳离子选择性荧光传感性能的研究进展.