多肢墙的线性方程解

本文去掉了R.Rossman方法中连梁连续化这一基本假定,给出了一种更符合实际的解法,该方法可以直接处理多肢墙,进而解决了R.Rossman方法中弯矩分配系数的确定问题。     

一种基于场景轮廓特征的三维地形重建方法

为了提升双目视觉系统三维重建的准确性和实时性,提出了一种基于区域分割和匹配的方法。针对实际场景中存在大面积灰度相近区域的现象以及稠密三维重建存在实时性差的问题,采用分水岭算法提取区域轮廓进行三维重建;针对轮廓边缘的误匹配问题,建立区域匹配和边缘点匹配的双重约束条件进行优化匹配;根据平行轴双目立体视觉模型进行三维重建。结果表明:采用轮廓特征进行匹配因其匹配点数大为减少,匹配用时提高了90%;由于采用了双重匹配策略,匹配和重建的准确性得到了保证。     

基于非同步替代光谱定标的地表下垫面影响分析

对760nm附近的氧气吸收带,选用植被、枯萎植被、人工地物、沙地和雪地五种典型地表类型,基于模拟数据进行非同步替代光谱定标方法的误差分析,比较不同地表类型得到的光谱定标准确度,为高光谱成像仪的非同步替代光谱定标提供定标图像选择策略.结果表明:运用两种光谱匹配方法——光谱角度匹配和欧氏距离法得到的定标误差基本一致;730~800nm的地表反射率曲线标准差在0.05nm以内时,定标误差集中在±0.5nm范围内;人工地物类型中个别地物如橄榄绿光泽涂料和植被大面积覆盖的图像数据不适合用于非同步替代光谱定标.     

实用型三谱段太阳模拟器的设计与研制

本文设计并研制了一种实用型三谱段太阳模拟器,其光谱匹配可同时调整3个谱段(300~700 nm,700~900 nm,900~1 700 nm)范围的能量,修正后可满足三结砷化镓太阳电池的测试使用要求。本文重点阐述了三谱段太阳模拟器滤光片的设计和氙灯光谱的修正及测试,介绍了太阳模拟器的光机结构。实验表明:三谱段太阳模拟器的光谱匹配满足三结砷化镓太阳电池各子电池的响应电流值。在有效辐照面150 mm×150 mm上,平均辐照度可以达到2个太阳常数(2 730 W/m²),辐照不均匀度达到±1.77%,辐照不稳定度达到±0.83%,为太阳电池自动分拣系统提供了可靠稳定的平台。     

Synthesis of high molecular weight polyisobutylene via cationic polymerization at elevated temperatures

A novel simple but effective initiating system of H2O/AlCl3 /veratrole (VE) has been developed to synthesize high molecular weight polyisobutylene (PIB) at elevated temperatures via cationic polymerization of isobutylene (IB) in solvent mixture of hexane/methylene dichloride (n-Hex/CH2Cl2 = 2/1, V/V). VE played very important roles in decreasing cationicity of the growing chain ends, suppressing side reactions of chain transfer and termination during polymerization, leading to production of high molecular weight PIBs. PIBs with high yields, having very high weight-average molecular weight (Mw ) of 1117000 and 370000 g/mol could be synthesized with H2O/AlCl3 /VE initiating system at VE concentration of 5.4 mmol/L at 80 and 60℃ respectively. Molecular weight of PIB increased remarkably with increasing VE concentration. The reaction order with respect to VE concentration was determined to be 3.52 via FTIR spectroscopy in combination with a diamond tipped attenuated total reflectance (ATR) immersion probe. The negative reaction order of VE was consistent with its retarding effect on IB polymerization by interacting with the propagating species. Molecular weight of PIB decreased with increasing polymerization temperature. The activation energy for polymerization degree (EDP ) could be determined to be around 23 kJ/mol when VE concentration was 5.4 mmol/L or 6.4 mmol/L.     

Synthesis, properties and electropolymerization of starshaped oligothiophenes with hexakis(fluoren-2-yl)benzene as core

Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.     

Correlation of SiO x layer thickness and properties of BOPP/SiO x composite films with spin coating process parameters

The effects of the spin coating process parameters on the thickness of the SiOx layer of the BOPP/SiOx composite film were investigated. When the concentration of tetraethoxysilane (TEOS) increased from 12.5 vol% to 55% vol%, the SiOx thickness increased from about 80 nm to 470 nm. In the sol time range of 1.5 h to 5 h the SiOx layer thickness reached a maximum at about 4 h and the change of the thickness roughly matched the change of the silica colloidal sphere sizes in sol. When the spin-coating speed of the dispensing stage increased from 450 r/min to 500 r/min, the SiOx layer thickness drastically decreased from about 1.67 μm to 400 nm. While the spin-coating speed of the thinning and drying stage went up to 1200 r/min, the SiOx layer thickness was in the range of 330 nm to 390 nm. It was also found that the SiOx layer thickness was almost increased linearly from about 500 nm to 1.02 μm with the ratio of the commercial silica colloidal to the TEOS from 0.2 to 1.0. The water contact angles decreased to about 23.0° for the BOPP/Si-Sol composite film with 1.67 μm SiOx layer and about 4.0° for the BOPP/mixing Si-Sol composite film with 1.02 μm SiOx layer. Compared to BOPP, the light transparency of the BOPP/Si-Sol composite films decreased by about 5.5% with the SiOx layer from about 80 nm to 1.67 μm and by 7.0% for the BOPP/mixing Si-Sol composite film with the SiOx layer from about 350 nm to 1.02 μm respectively.     

Systhesis of double-hydrophilic core-shell type multiarm star copolymer polyethylenimine-block-poly(2-hydroxyethyl methacrylate

Multiarm star block copolymers hyperbranched polyethylenimine-b-poly(2-hydroxyethyl methacrylate) (HPEI-b-PHEMA) with average 28 PHEMA arms have been prepared by atom transfer radical polymerization (ATRP) of HEMA in a mixed solvent of methanol and water using a core-first strategy. The hyperbranched macroinitiator employed was prepared on the basis of well-defined hyperbranched polyethylenimine with Mw/Mn of 1.04 by amidation with 2-bromo-isobutyryl bromide. The polymerization condition was optimized to prepare star copolymers with narrow dispersity, and the variables included the volume ratio of methanol to water, the molar ratio of initiating site to CuCl and the molar ratio of [CuCl]:[CuBr2]. Under the optimized polymerization condition, the lowest Mw/Mn value of the obtained star copolymers was around 1.3. Kinetic analysis showed that an induction period existed in the polymerization of HEMA. After this induction period, a linear dependence of ln([M]0/[M]t) on time was observed. The obtained HPEI-b-PHEMA could adsorb hydrophilic molecules. The comparison with the star copolymer with hydrophobic core and hydrophilic PHEMA shell verified that both the hydrophilic core and shell could host the hydrophilic guests, but the amidated HPEI core was more effective than the PHEMA shell.     

Synthesis, characterization and ion transport properties of hot-pressed solid polymer electrolytes (1−x) PEO:x KI

Synthesis and ion transport properties of hot-pressed solid polymer electrolytes (SPEs), (1-x) PEO: x KI, where x is the content of KI in wt%, are reported. A hot-press technique has been used for the formation of the polymeric membranes in place of the usual solution cast method. The composition (80PEO:20KI) was identified as the highest conducting polymer electrolyte on the basis of compositional dependent conductivity studies of PEO:KI films. A conductivity enhancement of more than two orders of magnitude from that of the pure PEO was achieved. Materials characterization and ion transport mechanism were explained by using various experimental techniques.     

Improving the properties of HDPE based separators for lithium ion batteries by blending block with copolymer PE-b-PEG

To improve the performances of HDPE-based separators, polyether chains were incorporated into HDPE membranes by blending with poly(ethylene-block-ethylene glycol) (PE-b-PEG) via thermally induced phase separation (TIPS) process. By measuring the composition, morphology, crystallinity, ion conductivity, etc, the influence of PE-b-PEG on structures and properties of the blend separator were investigated. It was found that the incorporated PEG chains yielded higher surface energy for HDPE separator and improved affinity to liquid electrolyte. Thus, the stability of liquid electrolyte trapped in separator was increased while the interfacial resistance between separator and electrode was reduced effectively. The ionic conductivity of liquid electrolyte soaked separator could reach 1.28 × 10-3 S.cm-1 at 25℃, and the electrochemical stability window was up to 4.5 V (versus Li + /Li). These results revealed that blending PE-b-PEG into porous HDPE membranes could efficiently improve the performances of PE separators for lithium batteries.