含改性松香的丁二醇二缩水甘油醚固化反应动力学研究

设计了含改性松香无苯环的环氧固化体系和无松香的对照体系,分别是无松香体系Ⅰ：丁二醇二缩水甘油醚（BDGE）和甲基六氢苯酐（MeHHPA）;无规体系Ⅱ：丙烯酸松香（AR）、BDGE和MeHHPA;有规体系Ⅲ：丙烯酸松香基环氧树脂（ARE,由AR和BDGE预聚而来）和MeHHPA。对三体系的固化反应应用动态示差扫描量热仪（DSC）进行了研究,利用KAS法求得不同转化率下的表观活化能,通过整个反应过程反应活化能的变化,得到了三体系反应的内在机理,结果发现松香基的引入及引入顺序都对固化反应产生影响。     

毛细管电泳氨类手性药物对映体拆分机理研究

手性药物及其对映体在药理上可表现出较大的差异,对它们进行研究将具有重要的理论意义和实用价值[1,2].毛细管区带电泳因其分离效率高、药品和试剂用量少、方法简单而成为目前手性拆分鉴定的重要方法之一[3].     

pH-Sensitive Wettability Induced by Topologicaland Chemical Transition on the Self AssembledSurface of Block Copolymer简

pH-sensitive wettability of polystyrene-b-poly（4-vinylpyridine） （PS-b-P4VP） self assembled films, exhibiting superoleophobicity under water and hydrophilicity at low pH value, and oleophobicity under water and hydrophobicity at neutral condition, has been realized. The wettability properties resulted from the surface topological and chemical transition, which were confirmed by in situ AFM measurements under water at different pH. At low pH, P4VP chains, which were confined in the hexagonal-packed nanodomains, got protonated into a swollen state, while at high pH, P4VP chains were deprotonated into a collapsed state. The reversible protonation/deprotonation procedure on the molecular scale leads to surface topological and chemical transition, thereby pH-sensitive wettability.     

罗斯滤片法测量激光打靶X射线辐射通量

利用一套罗斯滤片系统测量激光轰击固体金属Ti平面靶产生的X射线辐射通量,系统包括两个相同的X射线探测器及相应滤膜。罗斯滤片法的优点在于利用相邻核素对X射线相似的阻止率,可滤出一个窄的能带并去除高能部分的干扰,获得了Ti平面靶K壳层X光辐射产额。实验结果表明:硬X射线能段在4.5~4.9keV之间的K壳特征辐射占优,连续谱所占份额较低(与晶体谱仪一致);随着激光能量的增加,特征辐射增加;激光强度接近2×1015 W/cm2时,能量转换效率出现峰值。     

基于小波域三状态HMT模型的含噪图像增强

针对含噪图像增强问题,提出一种基于小波域三状态隐马尔可夫树模型的方法,采用三状态的高斯混合模型逼近小波系数的分布,不需要设定精确的阈值,依据期望最大算法训练得到的每个系数所属状态的后验概率,将系数区分为噪声系数、弱边缘系数和强边缘系数,然后通过抑制噪声系数,增强细节特征系数来达到对含噪图像增强的目的,并引入循环平移策略避免人工失真.通过对含噪的标准图像和人脑核磁共振图像进行仿真实验,并与几种经典的图像增强方法作视觉上的对比和定量分析.实验结果表明,本文所提出的方法具有很好的鲁棒性,在突出了图像中更多的细节信息的同时,可以有效抑制噪声.     

Electron Dynamics of Atoms in Parallel Electric and Magnetic Fields

Through an analysis of the nearest neighbor level fields, we investigate the evolution of the electron spacing statistics for atoms in parallel electric and magnetic dynamics as electric field strength increases. In the ＇inter-l mixing＇ predominant region, the electron shows complex dynamics while in the ＇inter-n mixing＇ predominant region, its dynamics behaves in a relatively stable way and the characteristic quantity ξ shows a slight oscillation. Comparing the dynamics for hydrogen and barium, we find that the core effect makes the main contribution to the chaotic behavior in non-hydrogen atoms.     

应用混频超声检测微小缺陷

高端飞行器的可靠性往往受限于其发动机内部盘、板等构的结构强度和使用寿命,因此对这类部件的无损检测在制造业上具有巨大需求。超声检测作为一种应用广泛、高效、环保的检测方法,常常被应用于这类构件的检测中。但是,大厚度盘、板类构件内的微小缺陷反射能力弱,常规超声脉冲反射法无法进行有效检测。为实现大厚度盘、板类构件内部微小缺陷的识别和定位,采用共线异侧纵波混频法,通过和差频信号特征识别微小缺陷;研究缺陷埋深变化对混频效果的影响,通过测量和差频信号幅值变化,实现微小缺陷的深度定位。结果表明：该方法可有效识别7075铝合金中埋深80mm的φ0.2mm横孔微缺陷,且可实现微小缺陷的深度定位。     

Temporal response of laminated graded-bandgap GaAs-based photocathode with distributed Bragg reflection structure: Model and simulation

To describe the dynamic response characteristics of the laminated graded-bandgap GaAs-based photocathode with distributed Bragg reflection structure, a general theoretical temporal response model is deduced by combining the unsteady continuity equation and numerical calculation method. Through the model, the contribution of the distribution Bragg reflection structure and graded-bandgap emission layer to the temporal response are investigated. Meanwhile, the relationships between the temporal response characteristics of the laminated GaAs-based photocathode and different structural parameters are also analyzed, including average electron decay time, emission layer thickness, and incident light wavelength. It is found that the introduction of distribution Bragg reflection (DBR) layer solves the discrepancy between the absorption capability of the emission layer and the temporal response. Moreover, the distributed Bragg reflection layer can improve the time response by optimizing the initial photoelectron distribution. The improvement effect of the DBR layer on the temporal response is enhanced with the emission layer thickness decreasing or the incident light wavelength increasing. These results explain the effect of the DBR layer of the photocathode on the dynamic characteristics, which can offer a new insight into the dynamic research of GaAs-based photocathode.     

高校代数教学的一些实践与思考

科技发展的现状要求我们必须用现代的代数学武装年青人,然而我国高校的代数教学却存在着诸多问题.基于已有的开设代数教学的实践与体会,主张在代数教学中应关注后续课程的教学改革和建设,并重新审视学生的培养目标,更多关注优秀学生的培养.     

匹配最大根小于等于2的图的匹配等价

给出了十六个匹配等价桥,证明了两个匹配最大根小于等于2的图匹配等价当且仅当它们之间可以由这十六个匹配等价桥进行等价转换,完整地刻画了这些图的补图的匹配等价图类,找到了这些图和它们的补图中的所有匹配唯一图．