激光沉积超导薄膜过程中出射粒子速度的飞行时间谱分析

采用飞行时间谱技术,测量了准分子激光烧蚀沉积高温超导薄膜过程中,由靶面出射粒子的飞行速度。研究了粒子速度与充氧压及其激光能量密度的关系。讨论了高能粒子在薄膜原位低温外延生长中的作用。     

约束系统量子化中Dirac方法与Faddeev-Jackiw方法的等价性

对约束系统量子化中Dirac方法和 Faddeev-Jackiw方法进行了讨论，并对它们的运动方程、正则量子化的等价性进行证明.找出了两种方法中约束的对应关系. 关键词： Faddeev-Jackiw方法 Dirac方法 约束系统 正则量子化     

Ab initio study on structure and phase transition of A- and B-type rare-earth sesquioxides Ln2O3 (Ln=La-Lu, Y, and Sc) based on density function theory

Ab initio energetic calculations based on the density functional theory (DFT) and projector augmented wave (PAW) pseudo-potentials method were performanced to determine the crystal structural parameters and phase transition data of the polymorphic rare-earth sesquioxides Ln₂O₃ (where Ln=La-Lu, Y, and Sc) with A-type (hexagonal) and B-type (monoclinic) configurations at ground state. The calculated results agree well with the limited experimental data and the critically assessed results. A set of systematic and self-consistent crystal structural parameters, energies and pressures of the phase transition were established for the whole series of the A- and B-type rare-earth sesquioxides Ln₂O₃. With the increase of the atomic number, the ionic radii of rare-earth elements Ln and the volumes of the sesquioxides Ln₂O₃ reflect the so-called “lanthanide contraction”. With the increase of the Ln³⁺-cation radius, the bulk modulus of Ln₂O₃ decreases and the polymorphic structures show a degenerative tendency.     

Synthesis of grafted poly(p‐phenyleneethynylene) with energy donor–acceptor architecture via atom transfer radical polymerization: Towards nonaggregating and hole‐facilitating light‐emitting material

In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007     

关于李萨如图形讨论的小结

对《大学物理》和其它一些刊物上多年来关于李萨如图形的讨论作了归纳和分析。     

AN ESTIMATE ON THE DISTRIBUTION AND MOMENTS OF THE LAST EXIT TIME OF AN ELLIPTIC DIFFUSION PROCESS

Let LB be the last exit time from a compact set B of an elliptic diffusion process X. A moderate estimate for the distribution of LB is obtained, and the sufficient and necessary condition for Ex(LBk)<∞is proved.     

A census of semisymmetric cubic graphs on up to 768 vertices

A list is given of all semisymmetric (edge- but not vertex-transitive) connected finite cubic graphs of order up to 768. This list was determined by the authors using Goldschmidt's classification of finite primitive amalgams of index (3,3), and a computer algorithm for finding all normal subgroups of up to a given index in a finitely-presented group. The list includes several previously undiscovered graphs. For each graph in the list, a significant amount of information is provided, including its girth and diameter, the order of its automorphism group, the order and structure of a minimal edge-transitive group of automorphisms, its Goldschmidt type, stabiliser partitions, and other details about its quotients and covers. A summary of all known infinite families of semisymmetric cubic graphs is also given, together with explicit rules for their construction, and members of the list are identified with these. The special case of those graphs having K_1,3 as a normal quotient is investigated in detail. Supported in part by N.Z. Marsden Fund (grant no. UOA 124) and N.Z. Centres of Research Excellence Fund (grant no. UOA 201) Supported in part by “Ministrstvo za šolstvo, znanost in šport Slovenije”, research program no. 101-506. Supported in part by research projects no. Z1-4186-0101 and no. Z1-3124-0101. The fourth author would like to thank the University of Auckland for hospitality during his visit there in 2003.     

Farkas-type results for fractional programming problems

Considering a constrained fractional programming problem, within the present paper we present some necessary and sufficient conditions, which ensure that the optimal objective value of the considered problem is greater than or equal to a given real constant. The desired results are obtained using the Fenchel–Lagrange duality approach applied to an optimization problem with convex or difference of convex (DC) objective functions and finitely many convex constraints. These are obtained from the initial fractional programming problem using an idea due to Dinkelbach. We also show that our general results encompass as special cases some recently obtained Farkas-type results.