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Co-K-Mo/γ-Al2O3催化剂的合成低碳醇性能及其结构研究 总被引:10,自引:0,他引:10
氧化态K-MoO3/γ-Al2O3催化剂中添加Co(NO3)2后在空气中四个不同温度下焙烧再硫化,制得Co-K-MoO3/γAl2O3催化剂,对其CO加氢合成低碳醇的催化反应性能进行了评价,运用XRD,LRS及EXAFS等手段对催化剂及其氧化态前躯体的结构进行了表征,活性测试结果表明加Co后于500-650℃焙烧制得的催化剂活性较高,且使C2+醇比例增加,结构分析结果显示加Co后350℃焙烧时,C 相似文献
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利用X射线光电子能谱和程序升温脱附谱研究了NO在清洁和预吸附氧的Cu(111)表面上的吸附和反应.通过改变NO的暴露量和退火温度,在Cu(111)表面可以制备出不同种类的化学吸附氧物种,其O 1s的结合能分别位于531.0 eV (O531)和529.7 eV (O529).表面O531物种的存在对NO的不同吸附状态有着显著影响,同时使得大部分NO吸附分子(NO(a))在加热过程中发生分解并以N2O和N2形式脱附; 而表面O529物种对NO(a)的解离脱附有着明显的抑制作用.相对于O531物种来说,O529物种对NO吸附表现出更强的位阻效应.上述结果表明,NO在Cu(111) 表面的吸附和分解行为与预吸附氧物种的种类和覆盖度密切相关. 相似文献
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Pd/C catalysts were prepared by deposited Pd nanoparticles (NPs) on different carbon supports including activated carbon (AC), graphite oxide (GO), and reduced graphite oxide (rGO) using sol-immobilization method. Through transmission electron microscopy, powder X-ray di raction, and X-ray photoelectron spectroscopy, the role of the carbon supports for the catalytic performances of Pd/C catalysts was examined in selective hydrogenation of acetylene. The results indicate that Pd/AC exhibited higher activity and selectivity than Pd/GO and Pd/rGO in the gas phase selective hydrogenation of acetylene. Thermal and chemical treatment of AC supports also have some effect on the catalytic performance of Pd/AC catalysts. The differences in the activity and selectivity of various Pd/C catalysts were partly attributed to the metal-support interaction. 相似文献