外载荷作用下水泥砂浆复合材料中的弹性波波速分析

为研究水泥基复合材料中弹性波频散特性,应用主频分别为50kHz、300kHz和1MHz三种声波探头,对钢纤维体积含量分别为0.5%、1.0%和3.0%的三种钢纤维增强水泥砂浆试件进行了单轴压缩下的弹性波测试实验。结果表明:在加载初始阶段,P波波速随着载荷增大而明显增大,但这种增大趋势逐渐减弱,并达到一个较稳定的值。随着钢纤维体积含量增加,波速有增大趋势。S波具有类似趋势,但其增幅比P波小得多。三种材料均表现出一定的频散效应。为消除材料在初始加载过程的非线性特性影响,采用了相对波速的方法,并讨论了相对波速的频散效应。结合多组份未胶结模型和Hashin-Shtrikman上限模型,应用一种无量纲理论模型,对比分析了弹性波波速频散规律。     

Spectroscopic properties of Yb~(3+)-doped TeO_2–BaO–BaF_2–Nb_2O_5-based oxyfluoride tellurite glasses

A series of oxyfluoride glasses with the compositions of 75 mol% TeO2, 10 mol% Nb2O5,(15 mol%-x) BaO, x BaF2(x = 0 mol%, 5 mol%, 10 mol%, 15 mol%) doped with Yb2O3 were prepared by the melt-quenching method. Their emission cross-sections, fluorescence lifetimes, and gain properties were investigated by using the absorption spectra and the fluorescence decay curves. The results show that by substituting BaF2 for BaO, the emission cross-section decreases from 1.37 pm2 to 1.21 pm2, and the fluorescence lifetime increases from 0.71 ms to 0.96 ms. These properties indicate that this oxyfluoride tellurite glass may have potential uses as the Yb2O3-doped gain medium in a solid laser.     

紫外氟磷玻璃的高能激光损伤研究进展

激光驱动惯性约束聚变(ICF),因有望解决全球能源危机问题而备受瞩目。然而,熔石英作为ICF装置终端光学组件中一类重要的功能性紫外元件,其高能激光诱导损伤问题成为限制ICF装置输出能量向更高更强方向发展的关键因素。因此,ICF装置负载能力继续提升对新型高抗强激光损伤紫外元件提出重大应用需求。综述了中国科学院西安光学精密机械研究所研制的紫外氟磷玻璃在高能紫外激光损伤方面的研究现状,并分析了现存的实际问题,最后对高抗损伤紫外氟磷玻璃的发展方向进行了展望。     

Effect of N2 Plasma Annealing of Properties of Fluoring Doped Silicon Dioxide Films with Low Dielectric Constant for Ultra—Large—Scale Integrated Circuits

The influence of N2 plasma annealing on the properties of fluorine doped silicon oxide (SiOF) films is investigated.The stability of the Dielectric constant of SiOF film is remarkably improved by the N2 plasma annealing.After enduring a moisture absorption test for six hours in a chamber with 60% humidity at 50℃,the dielectric constant variation of the annealed SiOF films is only 1.5%,while the variation for those SiOF films without annealing is 15.5%.Fourier transform infrared spectroscopic results show that the absorption peaks of Si-OH and H-OH of SiOF films are reduced after the N2 plasma annealing because the annealing can wipe off some unstable Si-F2 bonds in SiOF films.These Unstable Si-F2 bonds are suitable to react with water,resulting in the degradation of SiOF film properties.Therefore,the N2 plasma annealing meliorates the properties of SiOF films with low dielectric constant.     

正方形排列棒束元件中压力对临界热流密度影响的实验研究

一、前言 近三十年来,各国对临界热流密度(CHF)进行了一系列的研究,企图推导出理论关系式来计算反应堆燃料组件的CHF值。但是至今仍未取得满意的结果。目前用于反应堆热工设计的CHF关系式仍然是一些经验关系式。为了得到特定结构压水堆燃料组     

高温下轻质泡沫铝动态力学性能实验

对传统的分离式Hopkinson压杆装置加以改进,设计了一种长杆直接撞击Hopkinson杆的实验方案,检测出低波阻抗材料在高温动态加载下的应力均匀性。对轻质泡沫铝材料的实验表明,在同一撞击速度下,温度越高,试件两端的应力均匀性越差,增加温度与提高撞击速度均会导致泡沫铝材料冲击端与支撑端的应力不均匀性。根据高温下应力均匀性的实验结果,确定高温下试件均匀变形对应的冲击速度,再通过传统的分离式Hopkinson压杆实验得出泡沫铝在高温动态下的力学性能。     

级联三能级系统中极化拍频的不对称特性

在泵浦光为窄带或宽带的情形下,我们对级联三能级系统中极化拍频的不对称特性进行了研究,发现这种不对称特性是由于光学元件色散所导致的零延时的漂移引起的.     

纳米碳酸锌的制备和热分解动力学参数的测定

Nanosized zinc carbonate was prepared in the droplet of nano-reactor based on microemusion. The influences of the concentration of the surfactant and reactant on the diameter of nanoparticles were studied and the kinetic pa-rameters of thermal decomposition reaction were determined. It can be shown from experimental results， the di-ameter of the droplet in the microemulsion which have dissolved reactant zinc nitrate and sal volatile is between 4.9nm and 7.7nm， 6.2nm and 12.4nm， respectively. Nanosized zinc carbonate prepared by the method of mi-croemusion has shown good dispersion， narrow distribution and light agglomeration. The particle size of nanosized zinc carbonate is between 5nm and 40nm， and its kinetic parameters of thermal decomposition reaction-activation energy E and reaction order n are 110kJ·mol^-1 and 0.9， respectively.     

基于极化拍频激光绝对频率与原子能级差的测量方法研究

研究级联三能级系统中的极化拍频技术哪现其对能级差的测量精度决定于学跃迁的均匀增宽,在符合拍频条件下,两独立光源拍频的频差可以超出激光线宽,激光绝对频率的测量精度可达到与激光线宽同一量级。     

SiO_2气凝胶负载磷钨酸催化四氢呋喃聚合反应的研究

采用等体积浸渍法制备了SiO2气凝胶负载磷钨酸(HPW)催化剂,利用BET、XRD、NH3-TPD、FT-IR、Py-IR对催化剂结构及表面性质进行了表征.将催化剂应用于四氢呋喃(THF)聚合反应,考察了HPW负载量、聚合时间、聚合温度等条件的影响.结果表明:在负载量50%,反应温度50℃、反应时间4 h条件下,反应收率达53%,聚合物数均分子量2000左右,可用作纺织、化工等领域的生产原料.