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纯氧化硅气凝胶孔隙率高,易碎且对红外光谱具有较强的选择透过性,高温隔热性能差。加入纤维和遮光剂可以改善材料力学性能和隔热性能,然而纤维的加入会增加气凝胶的固相导热、降低辐射传热,但总的作用是降低气凝胶的隔热性能;加入遮光剂抑制辐射传热的同时会增加固相导热,综合影响效果不仅随着遮光剂的种类、含量和大小的影响,还会随着使用温度变化。本文采用基于瞬态平面法的Hot Disk热常数分析仪在较大的温度范围内测试氧化硅气凝胶添加不同含量的Si02增强纤维和中空球、添加不同粒径和含量的SiC遮光剂对氧化硅纳米多孔材料等效导热系数的影响规律,并对比了添加SiC、ZrO_2和TiO_2遮光剂的遮光效果。 相似文献
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采用多GPU并行的格子Boltzmann方法(lattice Boltzmann method, LBM)对充分发展的槽道湍流进行了直接数值模拟.GPU(graphic processing unit)的数据并行单指令多线程(single-instruction multiple-thread, SIMT)特征与LBM完美的并行性相匹配,使得LBM求解器在GPU上运行获得了极高的性能,亦使得大规模DNS(direct numerical simulation)在桌面级计算机上进行成为可能.采用8个GPU,网格数目达到6.7×107,全场网格尺寸Δ+=1.41.模拟3×106个时间步长,用时仅24 h.另外,直接模拟结果无论是在平均流速或湍流统计量上均与Moser等的结果吻合得很好,这也证实了二阶精度的格子Boltzmann法直接模拟湍流的能力与有效性 相似文献
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过渡金属纯簇和混合簇的密度泛函研究:Nb4,Co4和Nb2Co2 总被引:2,自引:0,他引:2
用密度泛函方法对过渡金属双原子Nb2,Co2和NbCo的电子态进行研究,得到三者的基态分别为3∑g-,5∑g+和3△.并以此为基础,讨论四核簇Nb4,Co4和No2Co2的成键情况,发现稳定的单金属簇Nb4具有高对称性的密堆结构,稳定的Co4具有低对称性的变形封闭结构,两者都是典型的金属键;而Nb2Co2在封闭式结构中是一般的金属键,在线形结构中有强弱交替的定域键,Nb原子易相互靠近成键,Co原子趋于远离不成键.三种团簇的多重度以Nb4<Nb2Co2<Co4顺序依次升高. 相似文献
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Bismuth-containing semiconductor material is a hot topic in photocatalysts because of its effective absorption under the visible light. In this paper, we expect to explore a new bismuth-based photocatalyst by studying the subsolidus phase relations of the Bi2O3-Fe2O3-La2O3 system. The X-ray diffraction data shows that in this ternary system the ternary compound does not exist, while seven binary compounds (including one solid solution series Bi1-xLaxO1.5 with 0.167 〈 x 〈 0.339) are obtained and eight compatibility triangles are determined. 相似文献
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首先定义一致凸Banach空间某非空紧子集上的一种新的映射—(L-α)一致李普希兹渐近非扩张映射,在该子集上构造关于(L-α)一致李普希兹渐近非扩张映射的三步迭代序列,然后来讨论三步迭代序列的收敛性。 相似文献
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To elucidate the nature of low-lying triplet states and the effect of ligand modifications on the excited-state properties of functional cationic iridium complexes,the solventdependent excited-state dynamics of two phosphorescent cationic iridium (III) complexes,namely[Ir (dph-oxd)2(bpy)]PF6(1) and[Ir (dph-oxd)2(pzpy)]PF6(2),were investigated by femtosecond and nanosecond transient absorption spectroscopy.Upon photoexcitation to the metal-to-ligand charge-transfer (MLCT) states,the excited-state dynamics shows a rapid process (τ=0.7-3 ps) for the formation of solvent stabilized 3MLCT states,which significantly depends on the solvent polarity for both 1 and 2.Sequentially,a relatively slow process assigned to the vibrational cooling/geometrical relaxation and a long-lived phosphorescent emissive state is identified.Due to the different excited-state electronic structures regulated by ancillary ligands,the solvation-induced stabilization of the 3MLCT state in 1 is faster than that in 2.The present results provide a better sight of excited-state relaxation dynamics of ligand-related iridium (III) complexes and solvation effects on triplet manifolds. 相似文献