排序方式: 共有28条查询结果,搜索用时 218 毫秒
11.
梁建华 《应用数学和力学(英文版)》1983,4(5):765-777
In this paper, by using Chien Wei-zang — Latta's composite expansion method[5], we have obtained the first-order asymptotic solution to a system of equations for a nonlinear diffusion process, thus simplifying
and improving the previous work[4] considerably. Moreover, a kind of complete analytical solution has been given for a special case, and the periodic solution
at the bifurcation point has been discussed, the related results being in agreement with the experiments. 相似文献
12.
One reaction-diffusion equation φtx+εφtφxx-φxxx=γ(φx) has been presented in the study of Morphogenesis. In this paper, reasonable de-finite conditions of the equation are proposed and the asymptotic form of its solution is obtained by using perturbation method. So the existence of solution of this probiem is solved. 相似文献
13.
14.
<正> 目前,国内高等工科院校工科学生的工程数学课共有六块,其中包括复交函数、积分变换、数理方程、线性代数、概率论与数理统计以及计算方法。而每一块也都有一本相应的教材。其中除了积分变换为18学时以外,其它各块的学时大约为36或者再多一点。我们把前 相似文献
15.
We report a detailed ab initio study of the trapping behavior of interstitial helium atoms (IHAs) in hcp Ti. The tetrahedral interstitial site for one He is confirmed to be the most stable IHA configuration, but the most favorable interstitial site comprises two adjacent octahedral sites for two helium atoms. The octahedral IHA can trap another IHA regardless of the site where it is initially located, whereas the tetrahedral IHA cannot. Hybridization among the different states is responsible for the stable order, which has significant implications for He clustering and bubble nucleation that can affect material performance in future fusion reactors. These results provide the basis for the development of improved atomistic models. 相似文献
16.
Zirconium(Zr) thin films deposited on Si(100) by pulsed laser deposition(PLD) at different pulse repetition rates are investigated. The deposited Zr films exhibit a polycrystalline structure, and the X-ray diffraction(XRD) patterns of the films show the α Zr phase. Due to the morphology variation of the target and the laser–plasma interaction, the deposition rate significantly decreases from 0.0431 /pulse at 2 Hz to 0.0189 /pulse at 20 Hz. The presence of droplets on the surface of the deposited film, which is one of the main disadvantages of the PLD, is observed at various pulse repetition rates. Statistical results show that the dimension and the density of the droplets increase with an increasing pulse repetition rate. We find that the source of droplets is the liquid layer formed under the target surface. The dense nanoparticles covered on the film surface are observed through atomic force microscopy(AFM). The root mean square(RMS) roughness caused by valleys and islands on the film surface initially increases and then decreases with the increasing pulse repetition rate.The results of our investigation will be useful to optimize the synthesis conditions of the Zr films. 相似文献
17.
克拉霉素(Clarithromycin)是第二代十四元大环内酯抗生素, 其合成是保护技术应用和区域选择性研究的一次集中体现[1,2].目前, 美国雅培实验室和日本大正公司是以2′,4″-O-双(三甲基硅)红霉素A 9-O-(1-异丙氧环己基)肟(1)作为区域选择性前体制备的[1,3]; 而中国和印度制药企业多采用2′,4″-O-双(三甲基硅)红霉素A 9-O-(1-甲氧基-1-甲基乙基)肟(2)作为关键中间体[4,5].后者的主要杂质为6,11-O-双甲基红霉素A[6].对大环内酯的区域选择性进行了大量的研究后, 发现2′,4″-O-双(三甲基硅)红霉素A 9-O-(1-甲氧基环己基)肟(3)的区域选择性远低于空间结构差异不大的化合物1[7], 却与空间结构差异较大的化合物2一样, 易生成大量的6,11-O-双甲基化产物. 相似文献
18.
19.
20.
反相高效液相色谱分析克拉霉素合成工艺中区域选择性甲基化的关键中间体 总被引:2,自引:0,他引:2
采用反相高效液相色谱法对克拉霉素合成工艺中关键中间体E-2′,4″-双(三甲基硅)-红霉素A-9-(1-异丙氧环己基)肟、Z-2′,4″-双(三甲基硅)-红霉素A-9-(1-异丙氧环己基)肟和E-2′,4″-双(三甲基硅)-6-甲基红霉素A-9-(1-异丙氧环己基)肟、Z-2′,4″-双(三甲基硅)- 6-甲基红霉素A-9-(1-异丙氧环己基)肟及其相关的6种工艺杂质进行了分离、定性和定量分析。色谱柱为DIKMA公司的Inertsil ODS-3(150 mm×4.6 mm i.d., 5 μm);流动相 相似文献