表面解吸常压化学电离质谱快速鉴别樟木制品

采用自行研制的表面解吸常压化学电离质谱(SDAPCI-MS),在无需样品预处理的情况下,对樟木制品及普通木材进行检测,在正离子模式及m/z 90～400范围内获得其化学指纹图谱,并通过主成分分析(PCA)方法对所获指纹谱图信息进行分析,进而对不同样品进行鉴别。结果表明,SDAPCI-MS能够对樟木表面多种特征化学成分(樟脑,香叶醇等)进行解吸电离,快速获得樟木的化学指纹谱图,并能够对目标组分做多级串联质谱鉴定。结合PCA方法,可对不同品质、不同种类的木材样品进行区分。结果表明,本方法灵敏度高,分析速度快(单个样品分析时间小于3 min),可望应用于珍贵木材快速无损分析及品质鉴定。     

小腿前外侧岛状皮瓣的研究进展

回顾国内外小腿前外侧岛状皮瓣的研究成果,总结了小腿前外侧岛状皮瓣的应用解剖学基础和临床应用,讨论了目前报道的小腿前外侧岛状皮瓣修复小腿下段皮肤缺损的优缺点,并对优化该皮瓣在临床上的应用提出了展望.     

Revisiting Chiral Extrapolation by Studying a Lattice Quark Propagator

The quark propagator in the Landau gauge is studied on the lattice, including the quenched and the unquenched results. No obvious unquenched effects are found by comparing the quenched quark propagator with the dynamical one. For the quenched and unquenched configurations, the results with different quark masses have been computed. For the quark mass function, a nonlinear chiral extrapolating behavior is found in the infrared region for both the quenched and dynamical results.     

磁稳定床反应器(英文)

介绍了磁稳定床反应器在国际上的首次工业应用,它集成了浆态床、固定床、移动床和流化床等反应器的优点. 通过调整线圈间距、在反应器内设置磁隔栅构件,实现了均匀磁场的放大; 绘制出磁稳定床反应器链式操作相图. 将非晶态Ni优异的加氢性能和磁性与磁稳定床反应器反应过程强化性能相结合,实现了在己内酰胺加氢精制过程的工业应用,并建成5套20～40万吨/年工业装置. 磁性催化剂与磁稳定床反应器相结合,强化了甲烷化、乙炔选择性加氢和烯烃叠合等反应过程,形成了新技术生长点.     

Probing the QCD phase structure with higher order baryon numbersusceptibilities within the NJL model

Conserved charge fluctuations can be used to probe the phase structure of strongly interacting nuclear matter in relativistic heavy-ion collisions. To obtain the characteristic signatures of the conserved charge fluctuations for the quantum chromodynamics(QCD) phase transition, we study the susceptibilities of dense quark matter up to eighth order in detail, using an effective QCD-based model. We studied two cases, one with the QCD critical end point(CEP) and one without owing to an additional vector interaction term. The higher order susceptibilities display rich structures near the CEP and show sign changes as well as large fluctuations. These can provide us information about the presence and location of the CEP. Furthermore, we find that the case without the CEP also shows a similar sign change pattern, but with a relatively smaller magnitude compared with the case with the CEP. Finally, we conclude that higher order susceptibilities of conserved charge can be used to probe the QCD phase structures in heavyion collisions.     

短孔道Pt/W-s-SBA-15催化剂的合成及甘油催化氢解制1,3-丙二醇性能的研究

合成了孔道平行于短轴方向的W原位掺杂的介孔SBA-15分子筛(W-s-SBA-15), 以其为载体制备了Pt/W-s-SBA-15催化剂, 考察了催化剂中Pt、W负载量变化对甘油氢解制1,3-丙二醇(1,3-PDO)性能的影响. 采用多种手段对催化剂的形貌、活性组分Pt和W的存在状态、催化剂的酸性等性质进行了系统的表征. 催化剂评价结果表明, 随着Pt、W负载量的增加, 甘油的总转化率和液相转化率(CTL)提高, 而1,3-PDO选择性呈先升高后降低的火山型变化趋势. 在Pt负载量为4.0 wt%、W/Si物质的量比为1/480的4Pt/W-s-SBA-15(1/480)催化剂上, 在433 K、H₂压力4.0 MPa、反应时间24 h的条件下, 甘油氢解制1,3-PDO的得率可达49.0%. 根据表征结果, 我们发现在Pt/W-s-SBA-15催化剂上的甘油转化率与Pt活性比表面积直接相关, 而小的Pt粒径、Pt与单分散WO₄之间密切的协同作用, 则有助于提高1,3-PDO的选择性.     

Gain-assisted indented plasmonic waveguide for low-threshold nanolaser applications

A subwavelength plasmonic indented waveguide with an active InGaAsP core is proposed.The characteristics of the gap plasmon mode and gain required for lossless propagation are investigated and analyzed by the finite element method.We numerically calculate the normalized mode areas and percentages of energy confined in InGaAsP and metal for plasmonic nanolaser applications.It is shown that the indentation of the sidewalls has an optimal value for which the lasing threshold gain is minimal.The structure could enable low-threshold subwavelength lasing and applications for optoelectronic integrated circuits.     

Effects of reagent's rotational and vibrational excitations on reaction O(3P) + H2 H2(ν = 0, 3, j = 0, 3; 5; 7; 9; 12; 15) → OH + H

To investigate the effect of reagent's rotational and vibrational excitations on the stereo-dynamics of reaction product, the title reaction is theoretically simulated using the quasi-classical trajectory (QCT) method on the ³A" and ³A′ potential energy surfaces (PESs). The reaction cross section is considered as the only scalar property in this work at four different collision energies. Furthermore the vector properties including two polarization-dependent differential cross sections (PDDCSs), the angular distributions of product' rotational momentum are discussed at one fixed collision energy. Effects of reagents' rotational excitation on the reaction do exist regularly.     

基于物理水平基准的组合式高程测量方法

针对空间坐标点相对于测量基准的高程测量准确性问题,提出一种基于物理水平基准的组合式高程测量方法。利用激光三角测量原理及其测量光路的几何特性,搭建了物理水平基准的高程测量系统,在朗伯散射光场中,分析了倾角变化对激光光能质心偏移量的影响,建立了相应的误差修正模型,利用倾角传感器实现了高程测量的倾角误差补偿,自主研制了标定平台对本文提出的高程测量系统进行标定验证试验。结果表明：本文提出的组合式高程测量方法能够在500 mm测量量程下将重复性测量误差控制在±20μm的波动范围内,相较于单一激光位移传感器测量方式,其组合式高程测量误差波动量大幅度降低,能够适应空间坐标点在任意姿态下的精准测量,有效改善激光位移传感器在高程测量领域的性能,使其测量结果更为真实有效。     

HDPE-g-GMA增容PC/UHMWPE共混体系的形态结构和动态流变性能

HDPE-g-GMA增容PC/UHMWPE共混体系的形态结构和动态流变性能;聚碳酸酯; 超高分子量聚乙烯; 共混物; 增容; 动态流变