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研究了ZnO或K2O助剂对Cu/SiO2-Al2O3上丙三醇和苯胺气相催化合成3-甲基吲哚反应的促进作用,采用X射线衍射、透射电子显微镜、H2程序升温还原、NH3程序升温脱附以及热重-差热分析等技术对催化剂进行了表征.结果表明,适量ZnO或K2O的加入可明显提高催化剂的活性、选择性和稳定性,其中以ZnO的促进作用更强.ZnO不仅能增强活性组分Cu与SiO2-Al2O3载体之间的相互作用、提高Cu在载体表面的分散度,而且可有效抑制反应过程中Cu粒子的烧结;而K2O的加入却降低了Cu分散度,但也对反应过程中Cu粒子的烧结有所抑制.ZnO或K2O的加入均不同程度地增加了Cu/SiO2-Al2O3催化剂的弱酸中心数量,从而促进3-甲基吲哚的生成. 相似文献
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Single-to-Multiple Channel Wavelength Conversions and Tuning of Picosecond Pulses in Quasi-Phase-Matched Waveguides 下载免费PDF全文
We report the single-to-multiple channel wavelength conversions of 1.57-ps pulses based on cascaded secondharmonic generation and difference frequency generation in quasi-phase-matched periodically poled lithium hiebate waveguides. For single-to-single channel wavelength conversion, no external cavity laser is required with use of a fibre ring laser. The conversion efficiency is about -21.44 dB. The converted idler wavelength can be tuned from 1526.4nm to 1537.5nm as the lasing pump wavelength is varied from 1566.1 nm to 1555.0nm. By employing several input pumps, tunable single-to-dual and single-to-triple channel wavelength conversions are experimentally demonstrated. 相似文献
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在ADS散裂靶系统的优化设计中,蒙特卡罗方法结合可靠的散裂反应理论模型进行中子学计算具有重要的作用。本工作利用Geant4程序中的INCLXX模型、BIC模型以及BERT模型和FLUKA程序分别模拟了597 MeV和1 500 MeV质子轰击薄铅靶不同出射角度的中子双微分截面,500,1 500 MeV质子轰击厚铅靶不同出射角度的中子双微分产额,以及400,600,800,1 000和1 200 MeV质子轰击厚钨靶在反角方向(175 °)的中子双微分产额,并与实验数据进行比较。研究表明,对于薄铅靶,Geant4程序的INCLXX模型和FLUKA程序模拟结果与实验符合得更好。能量在10~40 MeV范围内,BIC模型模拟结果明显高于实验数据,而BERT模型模拟结果略微低于实验数据。对于厚铅靶,在40 MeV左右所有的模拟结果都低于实验数据。对于厚钨靶,Geant4程序的BIC模型和FLUKA程序与实验数据符合得较好,INCLXX模型在能量高于60 MeV时模拟结果低于实验数据,BERT模型与实验数据差异较大。总体来看,Geant4程序的INCLXX模型和FLUKA程序进行ADS散裂靶相关的中子学的计算是合理和可靠的。The reliable Monte Carlo simulation codes coupled with nuclear reaction models play an important role in the neutronic calculation for the design and optimization of the ADS spallation target. In this work, the double differential cross sections at different angles produced from a thin lead target bombarded with 597 and 1 500 MeV protons, the neutron energy spectra at different angles produced from a thick lead target bombarded with 500 and 1 500 MeV protons, and the neutron energy spectra in the backward direction(175°) produced from a thick tungsten target bombarded with 400, 600, 800, 1 000 and 1 200 MeV protons are calculated with the Geant4 code coupled INCLXX, BIC and BERT models and the FLUKA code. The calculations are compared with the available experimental data. The results show that, for the thin lead target, the calculations with the Geant4 coupled INCLXX model and FLUKA code well reproduce the experimental results. In a energy range from 10 to 40 MeV, BIC model obviously overestimates the experimental results, and BERT model slightly underestimates the experimental results. For the thick lead target, all of the calculations underestimate the experimental results around 40MeV. For the thick tungsten target, the Geant4 coupled BIC model and FLUKA code well reproduce the experimental results. INCLXX model underestimates the experimental results above 60 MeV. BERT model bad reproduces the experimental results. Overall, the neutronic calculations with the Geant4 code coupled INCLXX model and FLUKA code for the ADS spallation target is reasonable and reliable. 相似文献
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铁、钴或镍助剂促进的 Ag/SiO2 催化剂上气相催化合成 3-甲基吲哚 总被引:1,自引:0,他引:1
将铁、钴或镍促进的 Ag/SiO2 催化剂用于苯胺和 1,2-丙二醇气相催化合成 3-甲基吲哚的反应中, 并采用 X 射线衍射、H2-程序升温还原和热重分析等技术对催化剂进行了表征. 结果表明, 铁或镍助剂的加入有助于提高 Ag/SiO2 催化剂的选择性. 其中, 铁的加入能增强活性组分银与载体间相互作用, 大大促进了银在载体表面上的分散, 使催化剂的初活性显著提高. 而钴或镍的加入虽然能略微减少反应过程中 Ag/SiO2 催化剂表面的积炭, 但加剧了银在反应过程中的烧结, 导致催化剂稳定性下降. 相似文献
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