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71.
Experiments for the determination of mono-, di and tri-butyltin (MBT, DBT and TBT) by hydride generation/gas chromatography/atomic absorption spectrometry in various matrices (sediment, suspended matter, mussel, algae and water) have revealed that poor butyltin recoveries are obtained in sediments displaying high sulphur and hydrocarbon contents; very poor recoveries were also observed for TBT in sediments with high chlorophyll pigment contents as well as in algal samples. It was however not clear whether the hydride generatin was inhibited by these infering compounds, as was previously assumed in the case of hydrocarbons, or whether interferences affected the atomization rate. Further studies were performed to solve this problem in order to validate this method in the case of analyses of, for example, oil-contaminated sediment and algae. This paper presents the results obtained. It is concluded here that the poor recoveries were due to an inhibition of hydride generation rather than to interference at the atomization stage. 相似文献
72.
73.
S. Chen H. Büttner 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,29(1):15-18
We generalize the Shastry-Sutherland model to three dimensions. By representing the model as a sum of the semidefinite positive
projection operators, we exactly prove that the model has exact dimer ground state. Several schemes for constructing the three-dimensional
Shastry-Sutherland model are proposed.
Received 20 February 2002 / Received in final form 27 May 2002 Published online 17 September 2002 相似文献
74.
75.
Duan-zhi ZHANG School of Mathematical Sciences Peking University Beijing China 《中国科学A辑(英文版)》2007,50(6):761-772
In this paper, we study the Maslov-type index theory for linear Hamiltonian systems with brake orbits boundary value conditions and its applications to the existence of multiple brake orbits of nonlinear Hamiltonian systems. 相似文献
76.
REN QingBao ZHU WeiTing HONG Bo & ZHANG YuHeng Department of Physics Lishui University Lishui China National High Magnetic Field Laboratory University of Science Technology of China Hefei China 《中国科学G辑(英文版)》2007,(3)
Magnetic properties of Nd_(0.5)Sr_(0.5)Mn_(1-x)(Ga_x, Ti_x)O_3 system (0.04≤x≤0.4) were inves- tigated through magnetization and electron spin resonance (ESR) measurements. It was observed that a small amount of Ti substitution for Mn will destroy the charge-ordering (CO) phase completely and induce the cluster-spin-glass phase in the system, which displays a procedure of collapse of CO and of an enhancement of spin ordering (SO) phase. In contrast, the Ga substitution for Mn induces a melt- ing of CO phase in the system. It was observed that with substitution the CO phase is suppressed gradually and the remanent CO phase is retained all the while, and withal, there is a co-existence of AFM CO phase and FM SO at low temperature. In addition, an abrupt rise of magnetization was observed in M-T curves. We attributed this abnormal phenomenon to a transition from canted AFM SO to FM SO in CO region. 相似文献
77.
Emrys A. Jones Nicholas P. Lockyer John C. Vickerman 《International journal of mass spectrometry》2007,260(2-3):146
Recent developments in desorption/ionisation mass spectrometry techniques have made their application to biological analysis a realistic and successful proposition. Developments in primary ion source technology, mainly through the advent of polyatomic ion beams, have meant that the technique of secondary ion mass spectrometry (SIMS) can now access the depths of information required to allow biological imaging to be a viable option.Here the role of the primary ion C60+ is assessed with regard to molecular imaging of lipids and pharmaceuticals within tissue sections. High secondary ion yields and low surface damage accumulation are demonstrated on both model and real biological samples, indicating the high secondary ion efficiency afforded to the analyst by this primary ion when compared to other cluster ion beams used in imaging. The newly developed 40 keV C60+ ion source allows the beam to be focused such that high resolution imaging is demonstrated on a tissue sample, and the greater yields allow the molecular signal from the drug raclopride to be imaged within tissue section following in vivo dosing.The localisation shown for this drug alludes to issues regarding the chemical environment affecting the ionisation probability of the molecule; the importance of this effect is demonstrated with model systems and the possibility of using laser post-ionisation as a method for reducing this consequence of bio-sample complexity is demonstrated and discussed. 相似文献
78.
79.
M. Dubé C. Daneault V. Vuorinen M. Alava M. Rost 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,56(1):15-26
We investigate the structure and dynamics of the interface between
two immiscible liquids in a three-dimensional disordered porous
medium. We apply a phase-field model that includes explicitly
disorder and discuss both spontaneous and forced imbibition.
The structure of the interface is dominated by a length scale
ξ× which arises from liquid conservation. We further show
that disorder in the capillary and permeability act on different
length scales and give rise to different scalings and
structures of the interface properties. We conclude with a
range of applications. 相似文献
80.