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121.
Daniel Grinberg Sabrina Siddique Minh‐Quyen Le Richard Liang Jean‐Fabien Capsal Pierre‐Jean Cottinet 《Journal of Polymer Science.Polymer Physics》2019,57(2):109-115
Additive manufacturing (AM), otherwise known as three‐dimensional (3D) printing, is driving major innovations in many areas, such as engineering, manufacturing, art, education, and medicine. Although a considerable amount of progress has been made in this field, additional research work is required to overcome various remaining challenges. Recently, one of the actively researched areas lies in the AM of smart materials and structures. Electroactive materials incorporated in 3D printing have given birth to 4D printing, where 3D printed structures can perform as actuating and/or sensing systems, making it possible to deliver electrical signals under external mechanical stimuli and vice versa. In this paper, we present a lightweight, low cost piezoelectric material based on the dispersion of inorganic ferroelectric submicron particles in a polymer matrix. We report on how the proposed material is compatible with the AM process. Finally, we discuss its potential applications for healthcare, especially in smart implants prostheses. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 109–115 相似文献
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为了准确有效监测工业烟囱排放,基于SO2及碳黑颗粒物的光学特性,设计并研制出一套双通道紫外成像遥感监测系统.该成像系统的两个光谱通道的中心波长分别定于310 nm和330 nm,利用两个通道的光学厚度之差反演SO2浓度图像,颗粒物浓度图像由330 nm通道获取,根据浓度图像结合光流法获取烟羽运动速度,进而计算得出SO2和碳黑颗粒物的排放速率.结果表明,该工业烟囱的SO2及碳黑颗粒物排放速率分别为72.48±3.16 kg/h和6.33±1.18 kg/h.实验采用紫外相机同时对工业烟囱排放的SO2及碳黑颗粒物进行监测,实验表明双通道紫外成像遥感监测兼具高时间分辨率与高空间分辨率,测量结果准确直观,在工业废气污染、船舶尾气污染以及火山喷发污染排放遥感监测中具有非常明显的技术优势及巨大的应用前景. 相似文献
124.
土地利用信息是国土资源管理的基础和重要依据,随着高分辨率遥感图像数据的日益增多,迫切需要快速准确的土地利用分类方法。目前应用较广的面向对象的分类方法对空间特征的利用尚不够充分,在特征选择上存在一定的局限性。为此,提出一种基于多尺度学习与深度卷积神经网络(deep convolutional neural network,DCNN)的多尺度神经网络(multi-scale neural network,MSNet)模型,基于残差网络构建了100层编码网络,通过并行输入实现输入图像的多尺度学习,利用膨胀卷积实现特征图像的多尺度学习,设计了一种端到端的分类网络。以浙江省0.5 m分辨率的光学航空遥感图像为数据源进行了实验,总体分类精度达91.97%,并将其与传统全卷积网络(fully convolutional networks,FCN)方法和基于支持向量机(support vector machine,SVM)的面向对象方法进行了对比,结果表明,本文所提方法分类精度更高,分类结果整体性更强。 相似文献
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Bing-Chang Tan Qian Wang Long-Long Jiang Ying Song Prof. Xin-Tao Wu Prof. Tian-Lu Sheng 《欧洲无机化学杂志》2023,26(12):e202300003
To investigate the effect of ligand remote (>10 Å) substituents on the bridging metal center on the metal-to-metal charge transfer (MMCT) properties in cyanidometa-bridged complexes, a series of new cyanidometal-bridged complexes and their one-electron and two-electron oxidation products have been synthesized and well characterized (namely, trans-[Cp(dppe)Fe−NC−(L)Ru(PPh3)−CN−Fe(dppe)Cp][PF6]n (n=2, 3, 4) (L=dmptpy, 1[PF6]n ; L=meoptpy, 2[PF6]n ; L=t-Buptpy, 3[PF6]n ) (Cp=1,3-cyclopentadiene, dppe=1,2-bis(diphenylphosphino)ethane, PPh3=triphenylphosphine, dmptpy=4′-(4-dimethylaminophenyl)-2,2′,6′,2′′-terpyridine, meoptpy=4′-(4-methoxyphenyl)-2,2′,6′,2′′-terpyridine, t-Buptpy=4′-(4-tertbutylphenyl)-2,2′,6′,2′′-terpyridine)). The investigations suggest that the cyanido-stretching (νCN) vibration energy for the complexes is unsensitive to the electron-donating ability change of the remote substituents of the cyanidometal bridging auxiliary ligand from tertbutyl, methoxy to dimethylamino group. However, the MMCT energies of the one- and two-electron oxidation complexes are still sensitive to the remote substituents of the ligand on the bridging metal center, and decreases with the increase of the electron-donating ability of the remote substituents from tertbutyl, methoxy to dimethylamino group. All one-electron and two-electron oxidation products belong to Class II mixed valence compounds according to the classification of Robin and Day. 相似文献
127.
Xiaoyu Chen Pengyu He Siqi Xia Lixin Cui Prof. Dr. Guofu Zhong Prof. Dr. Limin Yang 《Chemical record (New York, N.Y.)》2023,23(7):e202200279
Over the recent decades, due to the special electronic characteristics and diverse reactivities, N-heterocyclic carbene (NHC) has received significant interest in organocatalyzed reactions. The formation of Breslow intermediates by NHC can convert into acyl anion equivalent, enolates, homoenolate, acyl azolium, and vinyl enolate etc., and the cycloaddition reactions of these species has attracted lots of attention. In this review, we focus on the summry of the development of NHC-activation of carbonyl carbon (or imine carbon) in situ, α-, β-, γ-, and beyond, and the cycloaddition reaction of these species. 相似文献
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129.
Keiko Ohkura Hidekazu Nishizawa Takashi Obi Akira Hasegawa Masahiro Yamaguchi Nagaaki Ohyama 《Optical Review》2000,7(3):193-198
In the analysis of a medical image database aimed at formulating useful knowledge for image diagnosis requires an unsupervised image processing technique without preconceived knowledge. In this paper, we propose a method for unsupervised image segmentation, which is suitable for finding the features contained in an image. A small region around each pixel is considered as a pattern vector, and the set of pattern vectors acquired from the whole image is classified using the hierarchical clustering technique. In hierarchical clustering, the classification of pattern vectors is divided into two clusters at each node according to the statistical criterion based on the entropy in thermodynamics. Results of the test image generated by the Markov random field (MRF) model and real medical images photomicrographs of a colon tumor are shown. 相似文献
130.
In this paper, the exponential asymptotic solution (E.A.S.) of differential equation is discussed. Firstly, E.A.S. of the second-order differential equation is studied and the orthogonal conditions of the uniformly valid E.A.S. are found out. Next, E.A.S. in matched asymptotic method is discussed. Finally, some examples are given. 相似文献