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981.
利用辉光放电技术采用等离子体质谱诊断的方法研究了不同工作 压强下H2/C4H8混合气体等离子体中 主要正离子成分及其能量的变化规律, 并分析了压强对H2/C4H8混合气体的离解机理以及主要正离子形成过程的影响. 结果表明: 随着工作压强的增加, 碳氢碎片离子的浓度和能量均逐渐减小. 当工作压强为5 Pa时, H2/C4H8混合气体等离子体中C3H5+相对浓度最大; 压强为10 Pa时, C3H3+相对浓度最大; 压强为15, 20 Pa时, C2H5+相对浓度最大; 压强为25 Pa时, C4H9+相对浓度最大. 对H2/C4H8等离子体中的主要组分及其能量分布所进行的定性分析, 将为H2/C4H8混合气体辉光放电聚合物涂层的工艺参数优化提供参考技术基础.
关键词:
辉光放电技术
等离子体质谱诊断
工作压强 相似文献
982.
983.
采用放电电流为100~300 A、持续时间为13 s的单脉冲电源,设计了两种同轴电极结构作为放电阳极,分别为筒状电极、喷嘴状电极。利用MAXWELL 3D电场仿真软件对两种电极结构下的电场分布进行了仿真分析,并采用探针法对放电生成的等离子体的参数进行了测量,分析讨论了同轴电极结构对真空放电等离子体生成特性的影响。选取喷嘴状电极结构作为阳极,分别测量了采用铅、铝、铜三种材质的阴极时生成的等离子体的扩散速度及能量。实验与仿真结果表明:当阳极为喷嘴状电极时阴极尖端的电场强度较大,测得放电电流较大,击穿电压较低,等离子体密度也较大;采用铝材质阴极时生成的等离子体扩散速度最快,采用铅材质阴极时生成的等离子体的离子动能最大。 相似文献
984.
薄膜量热计是进行Z箍缩辐射总能量测量的主要手段之一,准确可信的总能量参数对Z箍缩研究具有重要意义。对薄膜量热计装置进行技术改进,采用脉冲恒流源代替脉冲恒压源驱动镍薄膜量热计,撤除了回路中的串接电阻,可直接测量薄膜探测器的电阻变化,从而有效提高了辐射总能量测量的精度,拓宽了该设备的适用范围,使其可对目前强光一号加速器Z箍缩实验中所有典型负载进行测量。改进后平面型铝丝阵负载实验中总能量测量的相对不确定度由49.0%降低为19.6%。与闪烁探测系统功率测量结果积分值进行了对比,二者比值在0.87~1.04之间。 相似文献
985.
986.
The plasma region under investigation is separated from the discharge region by a mesh grid. Plasma potential and electron number densities and electron temperatures under bi‐Maxwellian approximation for electron distribution function of the multi‐dipole argon plasma are measured. The cold electrons in the diffusion region are produced by local ionization. The hot electrons are the ionizing electrons behaving as Maxwellian. The electron trapping process in the discharge region is produced by potential well due to positive plasma potential with respect to the anode and by a repulsive grid. The dependence of ratios of the density of the hot to the cold electrons NE (=Neh/Nec) and hot to cold electron temperature T(=Teh/Tec) in the diffusion region on the depth of the potential well has been investigated. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
987.
Abstract This review article describes some existing microplasma sources and their applications in analytical chemistry. These microplasmas mainly include direct current glow discharge (DC), microhollow-cathode discharge (MHCD) or microstructure electrode (MSE), dielectric barrier discharge (DBD), capacitively coupled microplasmas (CCμPs), miniature inductively coupled plasmas (mICPs), and microwave-induced plasmas (MIPs). The historical development and recent advances in these microplasma techniques are presented. Fundamental properties of the microplasmas, the unique features of the reduced size and volume, as well as the advantageous device structures for chemical analysis are discussed in detail, with the emphasis toward detection of gaseous samples. The analytical figures of merit obtained using these microplasmas as molecular/elemental-selective detectors for emission spectrometry and as ionization sources for mass spectrometry are also given in this review article. 相似文献
988.
《应用光谱学评论》2013,48(1):71-99
Abstract High performance liquid chromatography (HPLC) has often been employed in the separation and speciation of metal containing compounds. One of the most sensitive devices used for detecting those compounds after the separation is the inductively coupled plasma (ICP). The similar flow rates for these two techniques render the coupling of the devices trivial, usually involving only a short length of capillary tubing. Upon entering the plasma, species are typically determined either via atomic emission spectrometry or mass spectrometry. HPLC-ICP devices have been employed less frequently for the determination of non-metals. This review will describe the applications of HPLC-ICP techniques to the determination of compounds containing carbon, sulfur, phosphorus, and the halogens. The instrumentation used for each application will be described, and the performance of the systems will be summarized. 相似文献
989.
N. H. Cheung 《应用光谱学评论》2013,48(3):235-250
Abstract Two all‐optical analytical techniques are reviewed. Both are capable of highly sensitive multi‐element analysis. One is by means of resonance‐enhanced plasma spectroscopy. It minimizes the continuum background associated with laser‐induced plasmas. Relative to laser‐induced breakdown spectroscopy, the signal‐to‐noise ratio is improved by orders of magnitude, thus allowing the quantitation of sodium and potassium at the single blood cell level. The other technique utilizes laser‐excited atomic fluorescence. It has been traditionally handicapped by its one wavelength–one transition specificity. We showed, however, that numerous elements could be induced to fluoresce at a single excitation wavelength of 193 nm provided that the analytes were imbedded in dense plumes, such as those produced by pulsed laser ablation. This method eliminates the continuum plasma background and sub‐ppb sensitivity was demonstrated in the analysis of aqueous lead colloids. 相似文献
990.
N. S. Mokgalaka 《应用光谱学评论》2013,48(2):131-150
Abstract The application of laser ablation inductively plasma mass spectrometry (LA‐ICP‐MS) to the determination of major, minor, and trace elements as well as isotope‐ratio measurements offers superior technology for direct solid sampling in analytical chemistry. The advantages of LA‐ICP‐MS include direct analysis of solids; no chemical dissolution is necessary, reduced risk of contamination, analysis of small sample mass, and determination of spatial distributions of elemental compositions. This review aims to summarize recent research to apply LA‐ICP‐MS, primarily in the field of environmental chemistry. Experimental systems, fractionation, calibration procedures, figures of merit, and new applications are discussed. Selected applications highlighting LA‐ICP‐MS are presented. 相似文献